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11.
The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.  相似文献   
12.
The transformation of Rome during the Late Antiquity and the Early Middle Ages has been investigated by archaeologists and historians. Social and political changes are the main aspects which led to a progressive modification of the urban framework; abandonment, spoliation and transformation of buildings are quite diffused as documented by the archaeological literature. The consequence of these practices is a higher vulnerability of the buildings which, from the seismological point of view, played a main role in increasing the effects of seismic shaking. A number of earthquakes have struck Rome during the period of investigation (fifth to ninth century A.D.), known from historical sources: 443, 484–508, 618, 801, 847; in some cases (443, 484–508, 801) damage has been documented. In contrast, the archaeological sources characterise collapse layers and evidence of destruction at different sites with changing and not always conclusive chronological constraints. Consequently, collapse and destruction have been alternatively attributed to the above-mentioned earthquakes. Through a geoarchaeological and stratigraphic analysis of potentially coseismic collapse units, we want (1) to describe the archaeoseismic evidence derived from recent excavations and from the available literature (e.g. Piazza Madonna di Loreto, Piazza Venezia, Palazzo Valentini Crypta Balbi, Colosseo, Basilica Hilariana, Basilica di Santa Petronilla, Santa Maria Antiqua,…); (2) to discuss the chronological problems and the uncertainty of attribution of the collapse units to known historical earthquakes; (3) to discuss the earthquake damage exaggeration due to erroneous attribution of seismic origin to the evidence of destruction derived from archaeological data. Finally, we will infer the role that earthquakes may have had on the development of the urban landscape in the fifth to ninth century A.D.  相似文献   
13.
The Maldives was severely hit by massive coral bleaching and subsequent mortality in 1998. The results of reef monitoring in the following years have supported contrasting views about their recovery potential, partly because of the scarcity of information on the situation before 1998. Quantitative data on coral assemblages collected in 1993 in the Rasfari region (North Malé Atoll) may provide a base-line for the evaluation of the present status of the Maldivian reefs. Five years before the 1998 mortality, most coral communities appeared to be similar, in terms of both coral cover and growth-form composition, to those described in 1958 and 1964, notwithstanding increased human pressure and local events such as minor bleaching episodes in 1987 and crown-of-thorns starfish (COTS) attacks in 1989. Three lessons can be learnt from these results to help to understand the present situation, some ten years after the 1998 mass mortality. First, Maldivian reefs proved in the past to be capable of maintaining flourishing coral life despite various disturbances. Second, four years had been sufficient for complete reef recovery after a (minor) bleaching event. Third, recovery after both COTS attack and bleaching follows a predictable path suggesting that the presence of a three-dimensional community structure, which should reduce post settlement mortality of coral recruits, is essential for rapid coral recovery. As coral recruitment remains high and large tabular Acropora colonies are now reappearing, it is expected that Maldivian reefs should return to their original condition within the next few years.  相似文献   
14.
This study addresses the influence of landslide dams on surface water drainage and groundwater flow. In the study area of Scanno Lake and Sagittario River (Central Italy), a limestone rockslide‐avalanche formed a lake, which has an outlet that is occasionally active, showing infiltration into the rockslide dam. Several springs are present at the lake's base and are partly fed by seepage through the rockslide debris. Piezometric surveys, discharge measurements, pumping tests and chemical analyses are tools used to build a conceptual model of the groundwater flow and to evaluate the flow through the rockslide debris. Seasonal water isotopic signatures validate the assumed model, showing a mixing of infiltration recharge and groundwater seepage throughout the rockslide debris. Various recharge areas have been found for springs, pointing out those directly fed by the rockslide debris aquifer. Hypotheses about seasonal groundwater mixing between the regional carbonate aquifer and the rockslide debris aquifer are supported by isotope results. Seasonal changes in groundwater table level due to recharge and surface losses from seasonal outlet have been correlated with isotopic groundwater composition from the rockslide debris aquifer and the downstream springs; this relationship highlights the role of the rockslide dam body on the hydrodynamics of the studied area. Relationships between surface waters and groundwater in the area have been completely understood on the basis of water isotopic fingerprinting, finally obtaining a complete evaluation of groundwater renewable resources and its regimen. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
15.
The most common way to prevent biofouling of immersed surfaces is to coat the exposed surfaces with a paint containing a biocide acting on marine organisms by diffusion into the surrounding water. However diffusion of toxins into the marine environment causes pollution and serious economic problems. This paper outlines the anti-microfouling properties of some insolubilized quaternary ammonium salts (grafted onto a vinyl copolymer by means of a covalent non-hydrolyzable bond). After immersion times in sea-water up to 4 months, the microbial cover was limited to bacterial forms, without microalgae or cyanobacteria as observed on the untreated, or tin-salt painted surfaces. Bacteria are mostly on unicell forms and numerous areas appear free of any microorganisms. As microbiofouling is an obligate step to macrofouling, this unleachable antifouling treatment could result in a prolonged protection.  相似文献   
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Roccamonfina, part of the Roman Potassic Volcanic Province, is an example of a composite volcano with a complex history of caldera development. The main caldera truncates a cone constructed predominantly of this caldera may have been associated with one of the ignimbritic eruptions of the Brown Leucitic Tuff (BLT) around 385 000 yr BP. The Campagnola Tuff, the youngest ignimbrite of the BLT, however, drapes the caldera margin and must postdate at least the initial stages of collapse. During the subsequent history of the caldera there were several major explosive eruptions. The largest of these was that of the Galluccio Tuff at about 300 000 yr BP. It is likely that there was further collapse within the main caldera associated with these eruptions. It is of note that despite these subsequent major explosive eruptions later collapse occurred within the confines of the main caldera. Between eruptions caldera lakes developed producing numerous lacustrine beds within the caldera fill. Extensive phases of phreatomagmatic activity generated thick sequences of pyroclastic surge and fall deposits. Activity within the main caldera ended with the growth of a large complex of basaltic trachyandestite lava domes around 150 000 yr BP. Early in the history of Roccamonfina sector collapse on the northern flank of the volcano formed the northern caldera. One of the youngest major events on Roccamonfina occurred at the head of this northern caldera with explosive activity producing the Conca Ignimbrite and associated caldera. There is no evidence that there was any linkage in the plumbing systems that fed eruptions in the main and northern calderas.  相似文献   
19.
This study corroborates the hypothesis that nitrogen-fixing cyanobacteria have probably occurred as an important component of the phytoplankton community in the Baltic Sea at least since brackish water conditions were initiated 8,50014C yr BP. Pigment analyses indicate that extensive occurrences started prior to a sharp increase in nutrient levels dated to 7,10014C yr BP. The cyanobacteria could have functioned as a natural trigger for eutrophication in the Baltic Sea by importing nitrogen. This is also verified by a contemporaneous drop in the δ15N values from 4‰ to around 2‰. We further conclude that the spreading of cyanobacteria was probably caused by a decrease in nitrogen∶phosphorus (N∶P) in the water mass that resulted from the intrusion of oceanic water with high P levels. The fractionation of P in sediments indicated that iron-bound P was efficiently sequestered under anoxic conditions that occurred as a consequence of the establishment of a stable stratification caused by the marine intrusion. This pool only showed minor variations around 3 μmol g−1 at the freshwater-brackish water transition. All P pools except the CaCO3 fraction showed a distinct increase around 9,30014C yr BP prior to the transition. We interpreted this increase as a change in preservation of organic matter or in the source of the sediment. Slightly after 4,00014C yr BP there was a dramatic drop in all P pools without any corresponding decreases in total N and carbon. Total P decreased from around 75 to 25–30 μmol g−1. The most dramatic drop occurred in the organic bound and the detrital apatite fractions, which decreased by a factor of 3–4. We explain this as a preferential regeneration of P, especially organic P, compared to other nutrients due to more prevalent anoxic conditions.  相似文献   
20.
We have constructed a numerical model of a galaxy that consists of a stellar, gas and dust disc imbedded within a dark halo. We have used this model to assess the radiation, gravitational and viscous forces on dust grains and to trace their motion through the interstellar medium over a period of 109 yr. We conclude that the disc opacity is a crucial factor in understanding the motion of the grains. Large grains (≈0.1 μm) with low disc opacity will lead to dust expulsion from the stellar disc, while high opacity leads to dust retention. Reasonable disc opacities lead to the recycling of the larger grains from the outer to the inner regions of the galaxy. The larger grains travel at higher velocities than small grains (0.01−0.001 μm), and so the smaller grains remain relatively close to their formation sites. Dust can 'leak' out over the entire surface of the disc because of the imbalance of radiation and gravitational forces. The dust is dynamically coupled to the gas and so although the gas lags behind the dust it is carried along with it. This explains the close correlation between the far-infrared emission from dust and the gas column density. We use a simple analytical model to show how the dust mass of a galaxy may evolve with time and how a significant fraction (90 per cent) of the total dust mass produced may have been expelled into the intergalactic medium.  相似文献   
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