Behaviour of REE and mass balance calculations in a lateritic profile over chlorite schists in South Cameroon     

Veronique Kamgang Kabeyene Beyala  Estelle Ndome Effoudou Priso  Georges Emmanuel Ekodeck 《Chemie der Erde / Geochemistry》2009,69(1):61-13

An in situ weathering profile overlying chlorite schists in the Mbalmayo-Bengbis formations (South Cameroon) was chosen for the study of the behaviour of REE and the evaluation of geochemical mass balance. After physical and mineralogical studies, the chlorite schists and the undisturbed weathered materials were chemically analyzed for major elements (X-ray fluorescence and titrimetry) and REE (ICP-MS). The behaviour of the REE in the Mbalmayo weathering system was established in comparison with the REE of the reference parent rock. Mass balance calculations were applied to both major elements and REE. The mineralogy of the materials was determined with the aid of a Philips 1720, diffractometer. The chlorite schists of the Mbalmayo sector show low REE contents (Σ=153.44 ppm). These rocks are relatively rich in LREE (about 125 times the chondritic value) and relatively poor in HREE (about 20 times the chondritic value). The REE diagram normalized to chondrites shows a slightly split graph ((La/Yb)_N=6.18) with marked enrichment in LREE (LREE/HREE=9.50) in relation to HREE. Moreover, these spectra do not present any Ce anomaly, but a slightly positive Eu anomaly. The imperfectly evolved profile, whose materials are genetically linked, shows an atypical behaviour of REE. In effect, the LREE are more mobile than the HREE during weathering ((La/Yb)NASC<1) with weak Ce anomalies. This has been rarely reported in lateritic profiles characterized by higher HREE mobility than LREE during weathering processes with high Ce anomalies. This is either due to the difference in the stability of REE-bearing minerals, or to the weak acidic to basic pH conditions (6.70<pH<7.80), or even due to the average evolution of the weathering materials. The pathway of the REE along the profile is as follows: (1) leaching in the saprolites and summit of the profile, except for Ce, which precipitates very weakly in the nodular materials and the coarse saprolite materials, (2) at the base of the profile, solutions come in contact with chlorite schist formations, at this level, the pH increases (pH=7.79), HREE and a part of LREE partially void of Ce precipitate and (3) the other part of LREE precipitates further up in the profile. The geochemical mass balance calculations reveal that these elements are leached in the same phases as the relatively high Si, Al, K and Fe²⁺ contents.  相似文献   

Paleoproterozoic volcanic rocks in the southern margin of the North China Craton,central China:Implications for the Columbia supercontinent   总被引：1，自引：0，他引：1  

Changming Wang  Xinyu He  Emmanuel John M.Carranza  Chengmin Cui 《地学前缘(英文版)》2019,10(4):1543-1560

The volcanic rocks of the Xiong'er Group are situated in the southern margin of the North China Craton(NCC).Research on the Xiong er Group is important to understand the tectonic evolution of the NCC and the Columbia supercontinent during the Paleoproterozoic.In this study,to constrain the age of the Xiong'er volcanic rocks and identify its tectonic environment,we report zircon LA-ICP-MS data with Hf isotope,whole-rock major and trace element compositions and Sr-Nd-Pb-Hf isotopes of the volcanic rocks of the Xiong'er Group.The Xiong'er volcanic rocks mainly consist of basaltic andesite,andesite.dacite and rhyolite,with minor basalt.Our new sets of data combined with those from previous studies indicate that Xiong'er volcanism should have lasted from 1827 Ma to 1746 Ma as the major phase of the volcanism.These volcanics have extremely low MgO.Cr and Ni contents,are enriched in LREEs and LILEs but depleted in HFSEs(Nb,Ta,and Ti),similar to arc-related volcanic rocks.They are characterized by negative zircon ε_(Hf)_(t) values of-17.4 to 8.8,whole-rock initial ~(87)Sr/~(86)Sr values of 0.7023 to 0.7177 andε_(Nd)(t) values of-10.9 to 6.4.and Pb isotopes(~(206)Pb/~(204)Pb =14.366-16.431,~(207)Pb/~(204)Pb =15.106-15.371,~(208)Pb/~(204)Pb= 32.455-37.422).The available elemental and Sr-Nd-Pb-Hf isotope data suggest that the Xiong'er volcanic rocks were sourced from a mantle contaminated by continental crust.The volcanic rocks of the Xiong'er Group might have been generated by high-degree partial melting of a lithospheric mantle that was originally modified by oceanic subduction in the Archean.Thus,we suggest that the subduction-modified lithospheric mantle occurred in an extensional setting during the breakup of the Columbia supercontinent in the Late Paleoproterozoic,rather than in an arc setting.  相似文献   

Modulating the Impacts of Stochastic Uncertainties Linked to Deposit Locations in Data-Driven Predictive Mapping of Mineral Prospectivity     

Parsa  Mohammad  Carranza  Emmanuel John M. 《Natural Resources Research》2021,30(5):3081-3097

Natural Resources Research - The operation of large-scale ore-forming processes triggers the development of neighboring mineral deposits of the same or related types in a metallogenic province....  相似文献   

‘Borehole Race’ and the Dilemma of Governing the ‘Ungoverned’: Understanding the Urban Political Ecology of Groundwater Exploitation in Nigeria     

Emmanuel M. Akpabio  Ekerette S. Udom 《社会与自然资源》2018,31(9):1030-1044

Groundwater exploitation is an essential aspect of the numerous processes of transforming the urban natural environment for human gains. We use the political ecology of borehole exploitation in Nigeria’s urban environment to understand the micro-and macro-level processes mediating the transformation and changes in urban “groundwater scape”. The fieldwork processes depend on field counting of borehole distribution, in-depth and semi-structured interviews, and a review of secondary literatures. We argue that the social and environmental changes arising from the exploitation of groundwater bespeak the active and continual manifestation of the interplay of combustible interests and power friction among institutional agents within the permissible range of the natural environment. Such dynamic power relations engender a pattern of socio-natural transformation consistent with Swyngedouw’s notion of urban metabolism- “a series of interconnected heterogeneous and dynamic but contested and contestable processes of continuous quantitative and qualitative transformations that re-arranges humans and non-humans in new and often unexpected ways”.  相似文献   

CA (Formerly ISI) Recognition of NRR: Editorial     

Emmanuel John M. Carranza 《Natural Resources Research》2017,26(2):117-118

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Enhancement and Mapping of Weak Multivariate Stream Sediment Geochemical Anomalies in Ahar Area,NW Iran     

Mohammad Parsa  Abbas Maghsoudi  Emmanuel John M. Carranza  Mahyar Yousefi 《Natural Resources Research》2017,26(4):443-455

In this study, stream sediment geochemical data have been subjected to robust principal components analysis (RPCA) and singularity mapping (SM) to enhance and map significant multivariate geochemical anomalies (i.e., mineralization-related) in Ahar area, NW Iran. The RPCA was applied to (a) account for the compositional nature of stream sediment geochemical data using suitable log-ratio transformation, (b) modulate the effect of outliers in component estimation and (c) derive a multivariate geochemical footprint of mineralization. The SM was applied to extract anomalous patterns of the multivariate geochemical footprint of mineralization. The exploration targets were then delineated using Student’s t-statistics analysis. The correlations of mapped exploration targets with the known mineral occurrences and mineralization-related patterns were further evaluated using normalized density index and overall accuracy analyses.  相似文献   

Application of Mineral Exploration Models and GIS to Generate Mineral Potential Maps as Input for Optimum Land-Use Planning in the Philippines   总被引：4，自引：0，他引：4  

Carranza  Emmanuel John M.  Mangaoang  Jerrysal C.  Hale  Martin 《Natural Resources Research》1999,8(2):165-173

The inherent problems of classifying or inventorying potential mineral resources (as opposed to known mineral resources) pose specific challenges. In this paper, the application of a conceptual mineral exploration model and GIS to generate mineral potential maps as input to land-use policy decision-making is illustrated. We implement the criteria provided by a conceptual exploration model for nickeliferous-laterites by using a GIS to classify the nickeliferous-laterite potential of an area in the northeastern part of the Philippines. The spatial data inputs to the GIS are geological map data, topographic map data, and stream sediment point data. Processing of these data yields derivative maps, which are used as indicators of nickeliferous-laterite potential. The indicator maps then are integrated to furnish a nickeliferous-laterite potential map. This map is compared with present land-use classification and policy in the area. The results indicate high potential for nickeliferous-laterite occurrence in the area, but the zones of potential are in places where mineral resources development is prohibited. The prohibition was imposed before the nickeliferous-laterite potential was assessed by this study. Mineral potential classification therefore is a critical input to land-use policy-making so that prospective land is not alienated from future mineral resource development.  相似文献   

Predicted present-day evolution patterns of ice thickness and bedrock elevation over Greenland and Antarctica   总被引：4，自引：0，他引：4  

Philippe Huybrechts  Emmanuel Le Meur 《Polar research》1999,18(2):299-306

This paper discusses predicted evolution patterns of present-day changes of ice thickness, surface elevation, and bedrock elevation over the Greenland and Antarctic continents. These were obtained from calculations with dynamic 3-D ice sheet models which were coupled to a visco-elastic solid Earth model. The experiments were initialized over the last two glacial cycles and subsequently averaged over the last 200 years to obtain the current evolution. The calculations indicate that the Antarctic Ice Sheet is still adjusting to the last glacial-interglacial transition yielding a decreasing ice volume and a rising bedrock elevation of the order of several centimetres per year. The Greenland Ice Sheet was found to be close to a stationary state with a mean thickness change of only a few millimetres per year, but the calculations revealed large spatial differences. Predicted patterns over Greenland are characterized by a small thickening over the ice sheet interior and a general thinning of the ablation area. In Antarctica, almost all of the predicted changes are concentrated in the West Antarctic Ice Sheet, which is still retreating at both the Weddell and Ross Sea margins. Over most of both ice sheets, the model indicates that the surface elevation trend is dominated by ice thickness changes rather than by bedrock elevation changes.  相似文献   

Regularized tomographic inversion with geological constraints          下载免费PDF全文

Vincenzo Lipari  Domenico Urbano  Emmanuel Spadavecchia  Jacopo Panizzardi  Nicola Bienati 《Geophysical Prospecting》2017,65(1):305-315

Reflection tomography is the industry standard tool for velocity model building, but it is also an ill‐posed inverse problem as its solution is not unique. The usual way to obtain an acceptable result is to regularize tomography by feeding the inversion with some a priori information. The simplest regularization forces the solution to be smooth, implicitly assuming that seismic velocity exhibits some degree of spatial correlation. However, velocity is a rock property; thus, the geometry and structure of rock formations should drive correlation in velocity depth models. This observation calls for constraints driven by geological models. In this work, we present a set of structural constraints that feed reflection tomography with geometrical information. These constraints impose the desired characteristics (flatness, shape, position, etc.) on imaged reflectors but act on the velocity update. Failure to respect the constraints indicates either velocity inaccuracies or wrong assumptions concerning the constraints. Reflection tomography with structural constraints is a flexible framework that can be specialized in order to achieve different goals: among others, to flatten the base of salt bodies or detachment surfaces, to recover the horizontalness of oil–water contacts, or to impose the co‐location of the same imaged horizon between PP and PS images. The straightforward application of structural constraints is that of regularizing tomography through geological information, particularly at the latest stages of the depth imaging workflow, when the depth migration structural setting reached a consistent geological interpretation. Structural constraints are also useful in minimizing the well‐to‐seismic mis‐ties. Moreover, they can be used as a tool to check the consistency of interpreters' hypothesis with seismic data. Indeed, inversion with structural constraints will preserve image focusing only if the interpreters' insights are consistent with the data. Results from synthetic and real data demonstrate the effectiveness of reflection tomography with structural constraints.  相似文献   

Identifying the accidental-natural mortality of leporids in the archaeological record: insights from a taphonomical analysis of a pitfall without evidence of human presence     

Maxime Pelletier  Emmanuel Desclaux  Jean-Baptiste Mallye  Evelyne CrÉgut-Bonnoure 《第四纪科学杂志》2020,35(5):677-694

Leporids (Lagomorpha, Mammalia), especially the mountain hare (Lepus timidus) and the European rabbit (Oryctolagus cuniculus), have been among the most abundant small game in western Europe since the Pleistocene. These animals are preferred prey for more than 40 predators, which increases the chances of finding their skeletal remains at archaeological or natural sites, and in particular karstic formations alternately occupied by Palaeolithic human societies and other predators. Moreover, specific eco-ethological characteristics for both species also offer the possibility to produce a substantial quantity of their bones accumulated by natural mortality without predation, making it more difficult to identify their origin in the fossil record. Despite this fact, the taphonomic signature of accidental-natural accumulations of leporids in karsts, such as pitfalls, has never been properly characterised. In order to address these issues, we carried out a detailed taphonomic study of leporid remains in a pitfall without any evidence of human activity, namely at Coulet des Roches (Monieux, Vaucluse, south-eastern France). At this site, leporids are the most abundant species throughout the Last Glacial Maximum sedimentary sequence. The bone accumulation was analysed in order to determine the most relevant criteria to identify a natural accumulation that results from the accidental fall of individuals in the pitfall. The relative proportions of each species are consistent with their current ethology, and their mortality profiles are compatible with the structure of a living natural population. The completeness rate of the different skeletal portions for both species is relatively high, bones are less fragmented and, unlike what might be expected, very few anatomical connections were preserved. The observed anatomical representation, breakage, and bone surface modification patterns are discussed and compared with available data concerning accumulations with predation. Taken together, the identified criteria contribute valuable help in the recognition of accidental mortality in the fossil record, as well as to evaluate the proportion of leporid bones accumulated naturally and those accumulated by predation, human or not, in a deposit.  相似文献