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11.
Alkaline lavas were erupted as phonolites and trachytes around Karaburhan (Sivrihisar–Eskisehir, NW Anatolia) within the Izmir–Ankara–Erzincan suture zone. These volcanic rocks were emplaced as domes, close and parallel to the ophiolite thrust line. According to 40Ar/39Ar geochronological analyses of sanidine crystals from the phonolites, the age of the alkaline volcanics is 25 Ma (Late Oligocene–Early Miocene).The flow-textured phonolites are porphyritic and consist mainly of sanidine, clinopyroxene, and feldspathoid crystals. The clinopyroxenes show compositional zoning, with aegirine (Na0.82–0.96Fe+30.68–0.83) rims and aegirine–augite cores (containing calcium, magnesium, and Fe+2). Some aegirine–augites are replaced with sodium-, calcium-, and magnesium-rich amphibole (hastingsite). Feldspathoid (hauyne) crystals enriched with elemental Na and Ca have been almost completely altered to zeolite and carbonate minerals. The fine-grained trachytes with a trachytic texture consist of feldspar (oligoclase and sanidine) phenocrystals and clinopyroxene microphenocrystals within a groundmass made up largely of alkali feldspar microlites.Although there are some differences in their element patterns, the phonolites and trachytes exhibit enrichment in LILEs (Sr, K, Rb, Ba, Th) and LREEs (La, Ce, Pr, Nd) and negative anomalies in Nb and Ta. These geochemical characteristics indicate a lithospheric mantle enriched by fluids extracted from the subduction component. In addition, the high 87Sr/86Sr (0.706358–0.708052) and low 143Nd/144Nd (0.512546–0.512646) isotope concentrations of the alkaline lavas reflect a mantle source that has undergone metasomatism by subduction-derived fluids. Petrogenetic modeling indicates that the alkaline lavas generated from the subduction-modified lithospheric mantle have undergone assimilation, fractional crystallization, and crustal contamination, acquiring high Pb, Ba, Rb, and Sr contents and Pb isotopic compositions during their ascent through the thickened crust in an extensional setting.  相似文献   
12.
Sediment provenance analysis remains a powerful method for testing hypotheses on the temporal and spatial evolution of uplifted source regions, but issues such as recycling, nonunique sources, and pre- and post-depositional modifications may complicate interpretation of results from individual provenance techniques. Convergent retroarc systems commonly contain sediment sources that are sufficiently diverse (continental magmatic arc, fold–thrust belt, and stable craton) to enable explicit provenance assessments. In this paper, we combine detrital zircon U–Pb geochronology, heavy mineral identification, Nd isotopic analyses, conventional sandstone petrography, and paleocurrent measurements to reconstruct the clastic provenance history of a long-lived sedimentary basin now exposed in an intermontane zone of the northern Andean hinterland of Colombia. The Middle Magdalena Valley basin, situated between the Central Cordillera and Eastern Cordillera, contains a 5–10 km-thick succession of Upper Cretaceous to Quaternary fill. The integrated techniques show a pronounced change in provenance during the Paleocene transition from the lower to upper Lisama Formation. We interpret this as a shift from an eastern cratonic source to a western Andean source composed of magmatic-arc rocks uplifted during initial shortening of the Central Cordillera. The appearance of detrital chloritoid and a shift to more negative εNd(t=0) values in middle Eocene strata of the middle La Paz Formation are attributed to shortening-related exhumation of a continental basement block (La Cira–Infantas paleohigh), now buried, along the axis of the Magdalena Valley. The diverse provenance proxies also show distinct changes during middle to late Eocene deposition of the Esmeraldas Formation that likely reflect initial rock uplift and exhumation of the fold–thrust belt defining the Eastern Cordillera. Upsection, detrital zircon U–Pb ages and heavy mineral assemblages for Oligocene and younger clastic deposits indicate that the Mesozoic sedimentary cover of the Eastern Cordillera was recycled during continued Cenozoic shortening. Our multidisciplinary provenance study refines the tectonic history of the Colombian Andes and demonstrates that uncertainties related to sediment recycling, nonunique sources, source heterogeneity, and climate in interpreting provenance data can be minimized via an integrated approach.  相似文献   
13.
Computer vision provides several tools for analyzing and simulating textures. The principles of these techniques are similar to those in multiple-point geostatistics, namely, the reproduction of patterns and consistency in the results from a perceptual point of view, thus, ensuring the reproduction of long range connectivity. The only difference between these techniques and geostatistical simulation accounting for multiple-point statistics is that conditioning is not an issue in computer vision. We present a solution to the problem of conditioning simulated fields while simultaneously honoring multiple-point (pattern) statistics. The proposal is based on a texture synthesis algorithm where a fixed search (causal) pattern is used. Conditioning is achieved by adding a non-causal search neighborhood that modifies the conditional distribution from which the simulated category is drawn, depending on the conditioning information. Results show an excellent reproduction of the features from the training image, while respecting the conditioning information. Some issues related to the data structure and to the computer efficiency are discussed.  相似文献   
14.
The Eastern Venezuelan Basin (EVB) contains one of the largest hydrocarbon accumulations in the world. Main petroleum targets are buried structures of the Monagas Fold-Thrust Belt (MFTB) which forms the northeastern edge of the EVB. The objective of this study is to integrate the seismic and well data that has been acquired over the last 10 years across the MFTB and EVB, to create an updated structural model. Three regional cross sections 60-75 km long are presented across an area of 4000 km2.Five structural domains are described: Amarilis, Furrial, Jusepín, Cotoperí and Pirital. They are characterized by thrusts and high-angle reverse faults. Structural style changes along strike are related to variations in depth of detachment levels and to the strike-slip component of the deformation. We have estimated a shortening between 43 and 59 km that increases eastward over a distance of 40 km.The evolution of the MFTB is divided in four episodes based on stratigraphic, structural and thermal maturity evidences: (1) Oligocene-early Miocene initial movement of Pirital thrust. (2) Early Miocene simultaneous movement on Pirital, Furrial and Cotoperí thrusts. (3) Middle Miocene increases in velocity and change in geometry of Pirital thrust, during an out of sequence period of thrusting. (4) Late Miocene to Holocene minor thrust activity. This evolution is consistent with the oblique convergence between the Caribbean and South American plates and the convergence between North and South America that affected Eastern Venezuela during the Cenozoic.By analyzing the along-strike variations in structural style, new exploratory opportunities have been identified. Under the Orocual and Santa Bárbara fields two untested duplex structures are proposed; they were developed during the middle Miocene. Other prospective hydrocarbon traps are associated to oblique transpressive faults that create anticline structures.  相似文献   
15.
Clay mineralogy and trace-element geochemistry of two abyssal cores indicate that the primary source of surface-current-transported detrital material in the southern Grenada Basin changed from a continental, South American terrane to a volcanic, Lesser Antillean terrane at the end of the Pleistocene. The record of benthic foraminiferal assemblages demonstrates that the Caribbean Bottom Water (CBW) was relatively oxygen poor and less corrosive in late Pleistocene glacial times than in interglacial times. The change in the properties of CBW in the Holocene was related to a renewed influx of North Atlantic Deep Water in the Caribbean.  相似文献   
16.
A compilation of literature data on the Fe-Mg composition of coexisting chlorite and chloritoid from metapelites metamorphosed at various P - T  conditions shows that the logarithm of the Fe-Mg partitioning (ln K D) varies linearly with the inverse of temperature, from about 2.4 at 300  °C to about 1.3 at 600  °C. In contrast, no trend was observed with pressure, and the molar volumes of Mg- and Fe-chlorite end-members suggest that the pressure dependence of ln K D is not significant. Therefore, the chloritoid-chlorite Mg-Fe exchange reaction is a potential thermometer and has been empirically calibrated using the analyses of 112 chloritoid-chlorite pairs from 28 different localities. Temperatures estimated using the Chl-Cld thermometer were checked against independent estimates for 20 samples not involved in the calibration (Beni Mzala window, Morocco), and the results are in fair agreement with independent temperature estimates. However, the analytical uncertainties and errors are too large to obtain reliable temperature estimates for extremely Mg-rich or Fe-rich compositions. The Chl-Cld thermometer is unreliable at XMg-CLD<0.2 and XMg-CLD>0.8 at 700  °C, and XMg-CLD<0.1 and XMg-CLD>0.9 at 300  °C. Using the results of the empirical calibration, we calculated new thermodynamic data for daphnite. Implementing these data, it becomes possible to estimate T  and P conditions of metamorphism for the invariant chlorite-chloritoid-quartz-aluminosilicate assemblage that is widespread in low-grade metapelites. These estimates appear to be relevant only in the stability field of kyanite, whereas the uncertainties on the calculated pressure conditions are very large in the stability field of kaolinite and pyrophyllite.  相似文献   
17.
Two years after the Prestige oil spill (POS) an assessment of the effects on benthic fauna was carried out using the data obtained in five multidisciplinary surveys. Otter trawl, beam trawl, suprabenthic sled and box corer were used to study the main benthic compartments, along eight transects perpendicular to the coastline. Beam trawl was also employed to quantify the amount of tar aggregates on the continental shelf. No significant correlations between tar aggregates and species richness, biomass and diversity of benthic communities were found. This result was corroborated when the role of depth, season, latitude and sediment characteristics was examined by canonical ordination, in which POS-related variables had low influence on spatial distribution patterns. Depth and sediment grain diameter profoundly influence epibenthic communities. Sediment organic content is a third key variable for the infaunal, suprabenthic and lower-sized epibenthic communities, but not for the larger epibenthic communities. Nevertheless, a decrease in the densities of several epibenthic indicators was detected the first year after spill, followed by a noteworthy recovery in 2004. Non-macroscopic toxicity and some oceanographic agents are suggested as possible causes of these shifts.  相似文献   
18.
There is a lack of information on monitoring neurotoxicity in offshore commercial species. To help fill this gap, we sampled hake (Merluccius merluccius) and Norway lobster (Nephrops norvegicus) in fishing grounds off the coast of l’Ametlla de Mar (NW Mediterranean) in June 2005 at a depth of 100 m and 400 m. Additionally, at 400 m depth, two other fish species, Micromesistius poutassou and Phycis blennoides were included. Neurotoxicity markers such as Colinesterases (ChEs), namely acethyl- (AChE), butyryl- (BChE), propionyl- (PrChE) and carboxilesterase (CbE) were measured in muscle. Lipid peroxidation (LP), a marker of oxidative damage, was also included. The results are discussed in relation to the animal’s sex, size and fishing depth. A comparison of esterases and LP levels between muscle and liver of hake and between muscle and hepatopancreas of Norway Lobster was made.

AChE was dominant in muscle and CbE in hepatopancreas. No differences between fish species were seen for AChE. However, N. norvegicus, presented lower levels of ChEs and LP. A size-dependence in ChEs was seen for M. merluccius, with larger animals showing significantly lower activities (p < 0.05). Sex-dependence was seen in N. norvegicus for most esterases, except AChE, with males displaying higher activities (p < 0.05). A sampling-depth effect was also seen in the crustacea, with animals from 100 m generally presenting lower esterase activities and higher LP levels.  相似文献   

19.
Seismic downhole-array data provide a unique source of information on actual soil (and overall site) behavior over a wide range of loading conditions that are not readily covered by in-situ or laboratory experimentation procedures. In this paper, free-field downhole-array seismic records are employed to identify and model the recorded response at the Lotung (Taiwan) and Treasure Island (California) sites. At Lotung, a five-accelerometer array recorded the site response during 18 earthquakes (1985–1986). The Treasure Island site was instrumented in 1992 with an array of six accelerometers that recorded a low amplitude earthquake in 1993. Using this downhole data, correlation and spectral analyses are performed to evaluate shear wave propagation characteristics, variation of shear wave velocity with depth and site resonant frequencies and model configurations. In addition, the actual seismic shear stress-strain histories are directly evaluated from the recorded downhole accelerations. These histories provide valuable insight into the mechanisms of site amplification, damping and pore-pressure build-up. Computational simulations of these case histories are performed based on the identified mechanisms of site response. In a companion paper, two additional case histories of site liquefaction are analyzed using records of downhole seismic response.  相似文献   
20.
Downhole records of seismically-induced soil liquefaction are a valuable source of information on the associated mechanisms of stiffness degradation and lateral spreading. In this paper, free-field downhole array seismic records are employed to identify and model the recorded response at Wildlife Refuge (California, USA) and Port Island (Kobe, Japan) sites. The Wildlife Refuge site was instrumented in 1982 with a two-accelerometer array and six piezometers that recorded a case of seismically induced site liquefaction. At Port Island, a four-accelerometer down-hole array recorded strong motion during the recent 1995 Hyogoken-Nanbu earthquake. This earthquake resulted in widespread liquefaction and major ground deformations at Port Island. Using the recorded downhole accelerations at these two sites, the actual seismic shear stress-strain histories are directly evaluated. These histories provide valuable insight into the mechanisms of site liquefaction and associated loss of stiffness and strength. Based on the identified dynamic soil behaviors, computational simulations of the observed seismic response are performed. Optimization techniques are employed to estimate the necessary computational modeling parameters. This document constitutes the second part of a set of two companion papers about site amplification and liquefaction.  相似文献   
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