The geochemical and isotopic composition of aquifer systems in the deltaic region of the Po River plain (northern Italy)     

Dimitra Rapti-Caputo  Giovanni Martinelli 《Hydrogeology Journal》2009,17(2):467-480

The chemical and hydrodynamic characteristics of groundwater in deltaic regions are strongly influenced by the complex stratigraphy of these areas, caused by the continuously varying depositional environments associated with their recent hydrographic evolution. As a case study, the eastern sector of the Po River plain, northern Italy, has been investigated to understand the quality of the available groundwater resources. Based on the analysis of hydrochemical and isotopic data, the recharge characteristics, the groundwater residence time and the aquifer vulnerability are defined. The results show significant qualitative degradation of the unconfined aquifer due to the shallow depth to water, while in the underlying confined aquifer, a hydrochemical facies of Ca–HCO₃ type prevails. The spatial variation and relationship between oxygen-18 and deuterium determine: firstly, hydraulic separation of the two hydrogeological units; secondly, direct infiltration of local precipitation to the unconfined aquifer; thirdly, the occurrence of waters originating in the Alps and locally from the Apennines, pervading the confined aquifer. The tritium results suggest local mixing between the superficial waters and the confined aquifer, occurring along the palaeo-river channels. This increases the pollution vulnerability of the confined hydrogeological unit within the plain, which is the only natural groundwater resource exploited for water supply.  相似文献   

Na, Mg, Ni and Cs distribution and speciation after long-term alteration of a simulated nuclear waste glass: A micro-XAS/XRF/XRD and wet chemical study     

Enzo Curti  Rainer Dähn  Marika Vespa 《Geochimica et cosmochimica acta》2009,73(8):2283-18706

Microscopic distribution and speciation of Na, Mg, Ni and Cs in a simulated (inactive) nuclear waste glass were studied using micro X-ray fluorescence (μ-XRF) and micro X-ray absorption spectroscopy (μ-XAS), after aqueous leaching during 12 years at 90 °C. Na and Mg are major constituents of the glass that can be used to determine the progress of the glass corrosion process and the nature of secondary alteration phases. Ni and Cs represent dose determining long-lived radionuclides (⁵⁹Ni, ¹³⁵Cs) in vitrified nuclear waste.The Na-Mg μ-XRF maps revealed that the core regions of the glass fragments are apparently unaltered and compositionally homogeneous, whereas rims and interstitial spaces are enriched with Mg-rich smectite formed during the leaching process. The micro X-ray absorption near edge structure (μ-XANES) spectra collected at the Mg K-edge in the altered zones show three sharp resonances typical for crystalline Mg-silicates. These resonances are distinctive of Mg occupying undistorted octahedral positions. In contrast, the μ-XANES spectra collected in the core zones of the glass fragments lack this resonance pattern and are identical to the spectra measured on the pristine (unleached) MW glass.Micro extended X-ray absorption fine structure (μ-EXAFS) and μ-XANES analyses at the Ni K-edge revealed three distinct Ni(II) species: (a) Ni uniformly distributed in the glass matrix, (b) micro-inclusions with high Ni concentrations and (c) Ni associated to the Mg-clay. The comparison with reference spectra of unleached MW and other Ni-bearing silicate glasses indicated that species (a) represents the original coordinative environment of Ni in the glass. The μ-EXAFS analyses revealed that species (b) is structural Ni in trevorite (NiFe₂O₄), which probably formed through unmixing processes during the cooling of the glass melt. The μ-EXAFS of species (c) could be successfully modeled assuming specific adsorption or incorporation of Ni into the lattice of trioctahedral Mg-clay minerals. Alternative models assuming other elements (Ni, Al, Fe) in addition to Mg in the second shell could not be fitted successfully.Aqueous concentration data were used to calculate the speciation of the leaching solutions. Saturation index (SI) calculations indicate undersaturation with respect to NiCO₃ and NiSO₄·7H₂O, but oversaturation with respect to β-Ni(OH)₂. The latter result is probably due to the omission of Ni borate and Ni silicate complexes in the speciation calculations, for which formation constants are not available. With the help of estimation techniques, we could infer that such complexes would dominate the Ni speciation and consequently reduce the SI below the saturation of β-Ni(OH)₂.The μ-XRF maps show that Cs is uniformly distributed in the MW glass, since no region with high Cs concentration could be detected. The Cs L_III-edge μ-XAS spectra were all very similar independently of the degree of alteration, indicating similar coordination environments of Cs in the core regions of the glass as well as in the secondary clays. These spectra largely differ from that measured for pollucite (a potential secondary Cs-phase in altered glasses) implying that the coordination environments of Cs in the MW glass and in pollucite are fundamentally different.The present study shows that μ-XRF and μ-XAS are essential tools in determining the fate and the retention mechanisms of radionuclides released from nuclear waste during aqueous alteration. Our spectroscopic analyses allowed us to exclude formation of specific Ni and Cs secondary solids (e.g. nepouite, β-Ni(OH)₂, pollucite) during the aqueous alteration. Ni and Cs are instead distributed as trace elements in the alteration phases formed by major elements during the leaching process. Our results imply that solid solution and/or adsorption equilibria, rather than pure phase solubility equilibria, are the adequate chemical models to determine Ni and Cs aqueous concentrations in performance assessments for radioactive waste repositories.  相似文献   

Geophysical Survey and Archaeological Data at Masseria Grasso (Benevento,Italy)     

Enzo Rizzo  Alfonso Santoriello  Luigi Capozzoli  Gregory De Martino  Cristiano Benedetto De Vita  Daniela Musmeci  Felice Perciante 《Surveys in Geophysics》2018,39(6):1201-1217

The use of geophysical methods in metrology is a significant tool within the wide research topic of landscape archaeology context. Since 2011, the Ancient Appia Landscapes Project aims to recognize dynamics, shapes and layout of the ancient settlement located along the Appia road east of Benevento, and cyclical elements and human activities that influenced the choice of landscapes. The integration of geophysical data with an archaeological infra-site analysis allowed us to investigate the area of Masseria Grasso, about 6 km from Benevento (Campania region, Italy). In this framework, an archaeogeophysical approach (Geomagnetic and Ground Penetrating Radar) was adopted for detecting anomalies potentially correlated with buried archaeological evidences. The geomagnetic results have given a wide knowledge of buried features in a large survey highlighting significant anomalies associated with the presence of buildings, roads and open spaces. These geophysical results permitted us to define the first archaeological excavations and, successively, a detailed Ground Penetrating Radar approach has been provided highlighting the rooms and paved spaces. The overlap between archaeological dataset and geophysical surveys has also allowed recognizing the path of the ancient Appia road near the city of Benevento and hypothesize the settlement organization of the investigated area, which has been identified with the ancient Nuceriola.  相似文献   

The Romagna Apennines,Italy: an eroded duplex     

A. Cerrina Feroni  L. Leoni  L. Martelli  P. Martinelli  G. Ottria  G. Sarti 《Geological Journal》2001,36(1):39-54

The study of clast composition carried out on the alluvial gravels of the Romagna Apennines of northern Italy has provided evidence for an extensive covering of allochthonous units (Ligurian nappe and Epiligurian succession) above the Miocene foredeep deposits (Marnoso‐Arenacea Formation), which has been subsequently eroded during the Late Miocene–Pleistocene uplift. This result is confirmed by the burial history outlined in the Marnoso‐Arenacea Formation through vitrinite reflectance and apatite fission‐track analyses. The Romagna Apennines represent, therefore, a regional tectonic window where the thrust system that displaced the Marnoso‐Arenacea Formation crops out. The geometric relations between this thrust system and the basal thrust of the Ligurian nappe, exposed at the boundaries of the Romagna Apennines (Sillaro Zone and Val Marecchia klippe), are consistent with a duplex structure. Thus, the Romagna Apennines thrust system is an eroded duplex. The duplex roof‐thrust corresponds to the surface of the synsedimentary overthrust of the Ligurian nappe on the Marnoso‐Arenacea Formation; the floor‐thrust is located in the pelagic pre‐foredeep deposits (Schlier Formation). Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Lignin phenols used to infer organic matter sources to Sepetiba Bay – RJ,Brasil     

C.E. Rezende  W.C. Pfeiffer  L.A. Martinelli  E. Tsamakis  J.I. Hedges  R.G. Keil 《Estuarine, Coastal and Shelf Science》2010

Lignin phenols were measured in the sediments of Sepitiba Bay, Rio de Janeiro, Brazil and in bedload sediments and suspended sediments of the four major fluvial inputs to the bay; São Francisco and Guandu Channels and the Guarda and Cação Rivers. Fluvial suspended lignin yields (Σ8 3.5–14.6 mgC 10 g dw⁻¹) vary little between the wet and dry seasons and are poorly correlated with fluvial chlorophyll concentrations (0.8–50.2 μgC L⁻¹). Despite current land use practices that favor grassland agriculture or industrial uses, fluvial lignin compositions are dominated by a degraded leaf-sourced material. The exception is the Guarda River, which has a slight influence from grasses. The Lignin Phenol Vegetation Index, coupled with acid/aldehyde and 3.5 Db/V ratios, indicate that degraded leaf-derived phenols are also the primary preserved lignin component in the bay. The presence of fringe Typha sp. and Spartina sp. grass beds surrounding portions of the Bay are not reflected in the lignin signature. Instead, lignin entering the bay appears to reflect the erosion of soils containing a degraded signature from the former Atlantic rain forest that once dominated the watershed, instead of containing a significant signature derived from current agricultural uses. A three-component mixing model using the LPVI, atomic N:C ratios, and stable carbon isotopes (which range between –26.8 and –21.8‰) supports the hypothesis that fluvial inputs to the bay are dominated by planktonic matter (78% of the input), with lignin dominated by leaf (14% of the input) over grass (6%). Sediments are composed of a roughly 50–50 mixture of autochthonous material and terrigenous material, with lignin being primarily sourced from leaf.  相似文献   

On the Melting Curve at High Pressures     

Enzo Bosch 《Geophysical Journal International》1974,37(1):45-50

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Thermodynamics of AFm-(I₂, SO₄) solid solution and of its end-members in aqueous media     

Laure Aimoz  Dmitrii A. Kulik  Erich Wieland  Enzo Curti  Barbara Lothenbach  Urs Mäder 《Applied Geochemistry》2012

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Streaming motions of galaxy clusters within 12 000 km s⁻¹– V. The peculiar velocity field     

Michael J. Hudson  Russell J. Smith  John R. Lucey  Enzo Branchini 《Monthly notices of the Royal Astronomical Society》2004,352(1):61-75

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Use of ETM+ images to extend stem volume estimates obtained from LiDAR data     

Fabio Maselli  Marta ChiesiAlessandro Montaghi  Enzo Pranzini 《ISPRS Journal of Photogrammetry and Remote Sensing》2011,66(5):662-671

Airborne LiDAR techniques can provide accurate measurements of tree height, from which estimates of stem volume and forest woody biomass can be obtained. These techniques, however, are still expensive to apply repeatedly over large areas. The current paper presents a methodology which first transforms mean stand heights obtained from LiDAR over small strips into relevant stem volume estimates. These are then extended over an entire forest by applying two estimation methods (k-NN and locally calibrated regression) to Landsat ETM+ images. The methodology is tested over a coastal area covered by pine forest in the Regional Park of San Rossore (Central Italy). The results are evaluated by comparison with the ground stem volumes of a recent forest inventory, taking into consideration the effect of stand size. In general, the accuracies of two estimation methods are dependent on the size of the forest stands and are satisfactory only when considering stands larger than 5-10 ha. The outputs of the parametric regression procedure are slightly more stable than those of k-NN and more faithfully reproduce the spatial patterns of the ground data.  相似文献   

Peculiar earthquake damage on a reinforced concrete building in San Gregorio (L��Aquila, Italy): site effects or building defects?     

Marco Mucciarelli  Marcello Bianca  Rocco Ditommaso  Marco Vona  Maria Rosaria Gallipoli  Alessandro Giocoli  Sabatino Piscitelli  Enzo Rizzo  Matteo Picozzi 《Bulletin of Earthquake Engineering》2011,9(3):825-840

In San Gregorio (L’Aquila, Italy) a three-story, reinforced concrete (RC) building had the first floor collapsed following the earthquake of April 6, 2009. The remaining two stories fell with a displacement in the horizontal projection of about 70 cm. This unusual behaviour is made more puzzling by the fact that buildings located at a short distance and with similar features had little or no damage reported. To understand the causes of the collapse we performed strong motion recordings, microtremor measurements, a detailed geological survey, a high-resolution geo-electrical tomography, a borehole with a down-hole test. On the building we performed a geometrical survey and laboratory tests on concrete cores. The acceleration and noise recordings have shown a high amplification with uphill-downhill direction. The geological survey has revealed the presence of co-seismic fractures on stiff soils. Geo-electrical tomography has shown an unexpected, strong discontinuity just below the building. Taking advantage of excavations in adjacent lots, we have highlighted rare cataclastic decimetric bands with a very low resistance material incorporated in well-stratified calcarenites. The same soft material has been founded in the borehole down to 17 m from ground level, showing a shear wave velocity that starts at 250 m/s, increases with depth and has an abrupt transition in calcarenites at 1,150 m/s. The surface geophysical measurements in the vicinity of the site have not shown similar situations, with flat HVSR curves as expected for a rock outcrop, except for a lateral extension of the soft zone. The analysis on the quality of the building materials has yielded values higher than average for the age and type of construction, and no special design or construction deficiencies have been observed. A strong, peculiar site effect thus appears to be the most likely cause of the damage observed.  相似文献