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In this study, the decolorization, dearomatization, and mineralization efficiencies of different advanced oxidation processes (AOPs; namely O3, O3/Fe(II), O3/Fe(II)/UVA, and O3/TiO2/UVA) were investigated for the azo dye C.I. Reactive Red 194 (RR194). The effects of pH (3–11), amount of TiO2 (0.05–1 g/L), and concentration of Fe(II) (0.1–1.6 mM) were investigated for the applied methods. The decolorization and mineralization efficiencies of the photocatalytic ozonation system (O3/TiO2/UVA) were increased by decreasing the pH of the dye solution in contrast to the ozonation system (O3). Decolorization of RR194 was increased in the photocatalytic ozonation system with an increasing amount of catalyst however, a decreasing was occurred for the homogeneous catalytic system (O3/Fe(II)) when increasing the concentration of catalyst. The decolorization efficiency of the homogeneous catalytic system (O3/Fe(II)) was enhanced when combined with UVA light. In our study, the most efficient method for dearomatization and mineralization was the O3/TiO2/UVA among the applied AOPs. 相似文献
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Erdal Eren 《洁净——土壤、空气、水》2010,38(8):758-763
The adsorption behavior of methyl orange (MO) from aqueous solution onto raw bentonite (RB) sample was investigated as a function of parameters such as pH, inorganic anion, contact time, and temperature. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms. Langmuir adsorption capacity was found to be 34.34 mg/g at pH 4.0. The pseudo‐first‐order, pseudo‐second‐order kinetic, and the intra‐particle diffusion models were used to describe the kinetic data. The values of the energy (Ea), enthalpy (ΔH≠), and entropy of activation (ΔS≠) were calculated as 38.62 kJ/mol, 36.04 kJ/mol, and ?150.05 J/mol K, respectively, at pH 4.0. 相似文献
14.
Erdal Kosun André Poisson Attila Çiner Roland Wernli Olivier Monod 《Journal of Asian Earth Sciences》2009,34(3):466-479
The Çatallar Basin is one of the Miocene basins located in the southern part of the Bey Da?lar? Massif (SW Turkey). This basin has been reinvestigated and new stratigraphic and sedimentological data are now presented. The Çatallar Basin lies in paraconformity on the Bey Da?lar? carbonate platform of Late Cretaceous to Palaeogene age. It consists of an impersistent, shallow-marine carbonate base (Karabay?r formation, Late Oligocene to Early Burdigalian) followed by an onlapping detrital sequence including the Akçay and Ba?beleni formations (Langhian to Serravallian). The Akçay formation mainly contains turbidites in which several debris-flows and olistostromes are intercalated. The lowest debris flows derive from the local carbonate platforms of Cretaceous and Palaeogene age. Higher, the debris flows and olistostromes contain large carbonate blocks deriving from nearby sources (Bey Da?lar? platform carbonates), whereas the accompanying pebbles originate from the allochthonous ophiolitic units located farther to the north (Lycian Nappes) or to the east (Antalya Nappes). The origin of these ophiolitic detritus is a matter of debate. The new data obtained in this study favour a northern origin. 相似文献
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Hayri Baytan Ozmen Mehmet Inel Erdal Akyol Bayram Tanık Cayci Hayri Un 《Natural Hazards》2014,71(1):63-84
An earthquake has struck Simav, Kutahya, located in the western part of Turkey on May 19, 2011. This paper focuses on the evaluation of the regional damage data and detailed investigation on a set of selected reinforced concrete buildings in Simav county center. The soil properties in Simav are examined in detail using multi-channel analysis of surface wave measurements, boreholes and laboratory test data. The damages are observed to be independent of soil conditions being hilly or plain, both in regional and Simav county center level. However, a slight relation is observed: as the soil period increases, so does the damage. The most damaged buildings are the four story buildings, resembling the case after some other earthquakes in Turkey. Regarding the detailed numerical evaluations on the building set, the properties highly correlated with seismic damage are investigated. Based on the obtained findings, it is concluded that the global building properties may not be enough to establish a strong relation with damage due to the local damages at the structural member level, especially for smaller seismic events. 相似文献
16.
During its storage or ascent, basaltic magma inevitably interacts with the surrounding rocks. In this study, schist xenoliths incorporated within ascending basalt are examined. Heating of the xenoliths combined with decompression effect of rapid magma uprise led to dehydration melting of hydrous minerals producing hercynitic spinel, melt, sillimanite and FeTi oxides. The melt is rhyolitic, strongly peraluminous (1.77 < A/CNK < 2.35) and corundum normative. It may contain up to 8 wt%FeOt. It occurs between the foliation planes and in the intragranular environment. Dehydration melting of micas in the schist is probably related to combined effects of heating by basaltic magma and decompression due to the rapid rise. Melting of xenoliths was a progressive process at low pressure. To cite this article: H. Bayhan et al., C. R. Geoscience 338 (2006). 相似文献
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This study aims to remove of Cu2+, Cd2+, and Pb2+ ions from solution and to investigate the adsorption isotherms, adsorption kinetics, and ion‐exchange affinities of these metals using waste activated sludge (AS) biomass. The adsorptions of the metals on biomass were optimal at an acidic pH value of 6.0 based on its monolayer capacities. Maximum monolayer capacities of AS biomass (qmax) were calculated as 0.478, 0.358, and 0.280 mmol g?1 for Cu2+, Cd2+, and Pb2+, respectively, and the adsorption equilibrium time was found as 60 min for each metal. The adsorbed amount of metal rose with increasing of initial metal ion concentration. The equilibrium adsorption capacity of AS for initial 0.25 mmol L?1 metal concentration was determined as 0.200, 0.167, and 0.155 mmol g?1 for Cu2+, Cd2+, and Pb2+ ions, respectively. These relevant values were determined as 0.420, 0.305, and 0.282 mmol g?1 for Cu2+, Cd2+, and Pb2+ ions, respectively, when initial metal concentration was 0.50 mmol L?1. In the multi‐metal sorption system, the adsorption capacity of AS biomass was observed in the order of Cu2+ > Cd2+ > Pb2+. In the presence of 100 mmol L?1 H+ ion, the order of ion‐exchange affinity with H+ was found as Cu2+ > Cd2+ > Pb2+. The adsorption kinetics were also found to be well described by the pseudo‐second‐order and intraparticle diffusion models. Two different rate constants were obtained as ki1 and ki2 and ki1 (first stage) was found to be higher than ki2 (second stage). 相似文献
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The Haymana basin in central Anatolia (Turkey) formed on a Late Cretaceous to Middle Eocene fore-arc accretionary wedge. A
sequential model is proposed for the 1-km-thick Lutetian Yamak turbidite complex (YTC) which is the youngest paleotectonic
unit of the basin. The YTC represents a prograding submarine fan subdivided into three depositional sequences (DS), each several
hundred meters thick. Each depositional sequence consists of a turbidite system (TS), with sandstone and conglomeratic sandstone
beds alternating with mudstones, overlain by basin plain mudstones. In each turbidite system, the sandstone and mudstone sequential
organization allows the distinction of smaller subdivisions, namely, basic sequences (BS) and basic units (BU), with each
basic sequence being composed of several basic units. This subdivision, associated with a two-dimensional geometric reconstruction
of the YTC, leads to a better understanding of the evolution in time and space of the submarine fan system. Lower to middle
fan depositional lobes, and upper fan and slope channels, are represented. As a whole, the YTC progressed from a sand-poor
to a sand-rich system. Depositional sequences (DS) of the YTC may correspond to third-order sea-level cycles of tectonic origin.
Accordingly, fourth- and fifth-order cycles might be proposed for the BS and BU, respectively. However, partly because of
the limited extent of exposures, the allocyclic origin of these finer subdivisions remains problematic. 相似文献
19.
Erdal afak 《Soil Dynamics and Earthquake Engineering》2006,26(1):65-70
Foundation impedance functions provide a simple means to account for soil–structure interaction (SSI) when studying seismic response of structures. Impedance functions represent the dynamic stiffness of the soil media surrounding the foundation. The fact that impedance functions are frequency dependent makes it difficult to incorporate SSI in standard time-history analysis software. This paper introduces a simple method to convert frequency-dependent impedance functions into time-domain filters. The method is based on the least-squares approximation of impedance functions by ratios of two complex polynomials. Such ratios are equivalent, in the time-domain, to discrete-time recursive filters, which are simple finite-difference equations giving the relationship between foundation forces and displacements. These filters can easily be incorporated into standard time-history analysis programs. Three examples are presented to show the applications of the method. 相似文献
20.
An empirical method for design of grouted bolts in rock tunnels based on the Geological Strength Index (GSI) 总被引：4，自引：0，他引：4
The procedure presented in this paper has been developed for the design of grouted rock bolts in rock tunnels during preliminary design stage. The proposed approach provides a step-by-step procedure to set up a series of practical guidelines for optimum pattern of rock bolting in a variety of rock mass qualities. For this purpose, a new formula for the estimation of the rock load (support pressure) is recommended. Due to its wide-spread acceptance in the field of rock engineering, the Geological Strength Index (GSI) is adopted in support pressure equation. For poor and very poor rock mass where the GSI < 27, the use of Modified-GSI is, instead, recommended. The supporting action is assumed to be provided by rock bolts carrying a total load defined by the rock load height. The mechanism of bolting is assumed to rely on roof arch forming and suspension principle. Integrated with support pressure function, the bolt density parameter is modified in order to provide an optimized bolt pattern for any shape of tunnel. The modified bolt density can also be used in analysis of a reinforced tunnel in terms of Ground Reaction Curve (GRC) in such a way as to evaluate the reinforced rock mass and the tunnel convergence. By doing so, the effectiveness of the bolting pattern is well evaluated. The proposed approach based on GSI is believed to overcome constrains and limitations of existing empirical bolt design methods based on RMR or Q-system, which are doubtful in poor rock mass usage. The applicability of the proposed method is illustrated by the stability analysis and bolt design of a rail-road tunnel in Turkey. 相似文献