Héritage et sources des métaux d'après la géochimie isotopique du plomb     

Eric Marcoux  Hubert Bril 《Mineralium Deposita》1986,21(1):35-43

Résumé Les galènes et sulfoantimoniures de plomb des filons quartzeux, barytiques et fluorés du Haut-Allier (district de Brioude-Massiac) ont fait l'objet d'analyses isotopiques du plomb. Les résultats montrent l'existence de deux populations de plomb appartenant à chacune des deux phases minéralisatrices reconnues dans la région.La première population (18,108<²⁰⁶Pb/²⁰⁴Pb<18,181) est rapportée à la phase mésothermale permienne. Elle comprend les sulfosels précoces des filons antimonifères ainsi que la galène des filons plombo-stannifères. L'homogénéité isotopique confirme la liaison génétique existant entre ces différents types filoniens et leur appartenance à un même processus métallogénique. Le socle métamorphique régional apparaît comme la source possible du plomb.La relative dispersion des valeurs isotopiques de la seconde population (18,215<²⁰⁶Pb/²⁰⁴Pb<18,472), d'âge liasique, est corrélable avec la situation géographique et géologique des filons. Elle est due à deux phénomènes complémentaires: le lessivage d'un segment crustal comprenant le socle métamorphique avec une participation graduée du granite uranifère de la Margeride et la réassimilation partielle du plomb des filons permiens. Ce dernier phénomène d'héritage métallique se traduit au niveau des paragenèses par la formation de filons à sulfosels dominants.

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Lead isotope analyses are reported for galena and lead sulfosalts from quartz, barite and fluorite vein deposits from the Haut-Allier (Brioude-Massiac district). The data define two lead populations reflecting the two mineralization episodes in this region.The first population (18,108<²⁰⁶Pb/²⁰⁴Pb<18,181) is related to the Permian mesothermal episode. It includes early sulfosalts from antimony veins and galena from lead-stanniferous veins. The Pb isotopic homogeneity confirms the relationship between the different vein types and their formation by a single metallogenic process. The metamorphic basement is the potential source of lead.The second population includes quartz-barite and fluorite veins. It shows much more isotopic variation (18,215<²⁰⁶Pb/²⁰⁴Pb<18,472) correlating with the geographical and geological location of the veins. Because the veins have a contemporaneous age, the isotopic dispersion therefore depends on two complementary phenomena: the leaching of a large volume of crust, including metamorphic basement, with a progressive contribution of the uraniferous granite of Margeride; and the partial remobilization of lead from Permian veins. The latter inheritance phenomena result in the genesis of major lead-sulfosalt vein deposits.

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Effects of temperature-dependent material properties and radioactive heat production on simple basin subsidence models     

Richard A. Ketcham  Eric C. Beam  Michelle A. Kominz 《Earth and Planetary Science Letters》1995,130(1-4):31-44

The effects of applying laboratory-derived material parameters to simple thermal basin subsidence models are examined. The temperature-dependent properties of thermal conductivity, specific heat and the coefficient of thermal expansion are considered, as well as conductivity contrasts between the crust and mantle and lithosphere-scale radiogenic heat production. The effects of conductivity and radioactivity are complementary, and can be predicted from the way in which they influence the initial and final steady-state geothermal gradient. A convex-up initial gradient, such as is generated by the conductivity and radioactivity functions and is also assumed to be the case based on independent evidence, will lead to more initial subsidence than in a simple constant-parameter model. The final subsidence will also be greater in the modified model, due to the fact that the stretching event will result in a lithospheric column which is intrinsically cooler than in the pre-deformation case. Because the coefficient of thermal expansion rises with increasing temperature, including its temperature dependence will result in a model with substantially less initial subsidence than one with a constant value. When these parameters are combined into a single model, the initial subsidence is approximately 15–20% less than in the constant-parameter model if radioactivity is not included, and 10% less if it is, while the final subsidence is about 5% greater without radioactivity and 7–9% greater with radioactivity included. Depending on the magnitude of extension, these effects can translate into differences of tens to hundreds of meters when compared to the constant-parameter model.  相似文献   

Autoxidation of N(III), S(IV), and other Species in Frozen Solution – A Possible Pathway for Enhanced Chemical Transformation in Freezing Systems     

Eric A. Betterton  Darcy J. Anderson 《Journal of Atmospheric Chemistry》2001,40(2):171-189

The chemistry of glycolaldehyde (hydroxyacetaldehyde) relevant to the troposphere has been investigated using UV absorption spectrometry and FTIR absorption spectrometry in an environmental chamber. Quantitative UV absorption spectra have been obtained for the first time. The UV spectrum peaks at 277 nm with a maximum cross section of (5.5± 0.7)×10^–20 cm² molecule^–1. Studies of the ultraviolet photolysis of glycolaldehyde ( = 285 ± 25 nm) indicated that the overall quantum yield is > 0.5 in one bar of air, with the major products being CH₂OH and HCO radicals. Rate coefficients for the reactions of Cl atoms and OH radicals with glycolaldehyde have been determined to be (7.6± 1.5)×10^–11 and (1.1± 0.3)×10^–11 cm³ molecule^–1 s^–1, respectively, in good agreement with the only previous study. The lifetime of glycolaldehyde in the atmosphere is about 1.0 day for reaction with OH, and > 2.5 days for photolysis, although both wet and dry deposition should also be considered in future modeling studies.  相似文献   

Bioterrorism: A ‘New’ Global Environmental Health Threat     

Eric K. Noji 《Global Change & Human Health》2001,2(1):46-53

Biological weapons represent a unique "environmental" hazard. The pathogens involved are natural in the sense that they are risks that naturally occur in our environment. However they are unnatural in the way in which they are inflicted upon society. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

Detection Time for Plausible Changes in Annual Precipitation, Evapotranspiration, and Streamflow in Three Mississippi River Sub-Basins     

Alan D. Ziegler  Edwin P. Maurer  Justin Sheffield  Bart Nijssen  Eric F. Wood  Dennis P. Lettenmaier 《Climatic change》2005,72(1-2):17-36

We use diagnostic studies of off-line variable infiltration capacity (VIC) model simulations of terrestrial water budgets and 21st-century climate change simulations using the parallel climate model (PCM) to estimate the time required to detect predicted changes in annual precipitation (P), evapotranspiration (E), and discharge (Q) in three sub-basins of the Mississippi River Basin. Time series lengths on the order of 50–350 years are required to detect plausible P, E, and Q trends in the Missouri, Ohio, and Upper Mississippi River basins. Approximately 80–160, 50, and 140–350 years, respectively, are needed to detect the predicted P, E, and Q trends with a high degree of statistical confidence. These detection time estimates are based on conservative statistical criteria (α = 0.05 and β = 0.10) associated with low probability of both detecting a trend when it is not occurring (Type I error) and not detecting a trend when it is occurring (Type II error). The long detection times suggest that global-warming-induced changes in annual basin-wide hydro-climatic variables that may already be occurring in the three basins probably cannot yet be detected at this level of confidence. Furthermore, changes for some variables that may occur within the 21st century might not be detectable for many decades or until the following century – this may or may not be the case for individual recording station data. The long detection times for streamflow result from comparatively low signal-to-noise ratios in the annual time series. Finally, initial estimates suggest that faster detection of acceleration in the hydrological cycle may be possible using seasonal time series of appropriate hydro-climatic variables, rather than annual time series.  相似文献   

Inverted-polarity electrical structures in thunderstorms in the Severe Thunderstorm Electrification and Precipitation Study (STEPS)     

W. David Rust  Donald R. MacGorman  Eric C. Bruning  Stephanie A. Weiss  Paul R. Krehbiel  Ronald J. Thomas  William Rison  Timothy Hamlin  Jeremiah Harlin 《Atmospheric Research》2005,76(1-4):247

Balloon-borne electric field soundings and lightning mapping data have been analyzed for three of the storms that occurred in the Severe Thunderstorm Electrification and Precipitation Study field program in 2000 to determine if the storms had inverted-polarity electrical structures. The polarities of all or some of the vertically stacked charge regions in such storms are opposite to the polarities observed at comparable heights in normal storms. Analyses compared the charge structures inferred from electric field soundings in the storms with charges inferred from three-dimensional lightning mapping data. Charge structures were inferred from electric field profiles by combining the one-dimensional approximation of Gauss's law with additional information from three-dimensional patterns in the electric field vectors. The three different ways of inferring the charge structure in the storms were found to complement each other and to be consistent overall. Charge deposition by lightning possibly occurred and increased the charge complexity of one of the storms.Many of the cloud flashes in each case were inverted-polarity flashes. Two storms produced ground flash activity comprised predominantly of positive ground flashes. One storm, which was an isolated thunderstorm, produced inverted-polarity cloud flashes, but no flashes to ground. The positive and negative thunderstorm charge regions were found at altitudes where, respectively, negative and positive charge would be found in normal-polarity storms. Thus, we conclude that these storms had anomalous and inverted-polarity electrical structures. Collectively, these three cases (along with the limited cases in the refereed literature) provide additional evidence that thunderstorms can have inverted-polarity electrical structures.  相似文献   

Annual ENSO simulated in a coupled ocean–atmosphere model     

Tomoki Tozuka  Jing-Jia Luo  Sebastien Masson  Swadhin K. Behera  Toshio Yamagata   《Dynamics of Atmospheres and Oceans》2005,39(1-2):41

Using an output from 200-year integration of the Scale Interaction Experiment of EU project-F1 model (SINTEX-F1), the annual ENSO reproduced in the coupled general circulation model is investigated, suggesting the importance of reproducing an annual cycle in realistically simulating ENSO events. Although many features of the annual ENSO are reproduced, the northward expansion of sea surface temperature anomaly (SSTA) in the eastern tropical Pacific stays south of the equator. It is suggested that this model bias is due to the excitation of the too strong Rossby waves in the southeastern tropical Pacific, which reflect at the western boundary and intrude into the eastern equatorial Pacific. The zonal wind stress anomaly along the equator also plays an important role in generating the equatorial Kelvin waves. The amplitude of SSTA for the annual ENSO mode is reproduced, but its variance is only 20% of the observation; this is again due to the lack of northward migration of seasonal SSTA in the equatorial region and weaker coastal Kelvin waves along South America. Remedies for the model bias are discussed.  相似文献   

Global change and the intensification of agriculture in the tropics   总被引：3，自引：2，他引：3  

Eric Keys  William J. McConnell 《Global Environmental Change》2005,15(4):320-337

Bridging understanding of local environmental change with regional and global patterns of land-use and land-cover change (LUCC) remains a key goal and challenge for our understanding of global environmental change. This meta-analysis attempts to bridge local and regional scales of LUCC by demonstrating the ways in which previously published case studies can be compared and used for a broader regional synthesis in the tropics. In addition to providing results from a meta-analysis, this paper suggests ways to make future case studies more widely comparable.  相似文献   

Trace element zoning in pyroxenes from ODP Hole 735B gabbros: diffusive exchange or synkinematic crystal fractionation?     

Yongjun Gao  Jochen Hoefs  Eric Hellebrand  Anette von der Handt  Jonathan E. Snow 《Contributions to Mineralogy and Petrology》2007,153(4):429-442

Major and trace element profiles of clinopyroxene grains in oceanic gabbros from ODP Hole 735B have been investigated by a combined in situ analytical study with ion probe, and electron microprobe. In contrast to the homogeneous major element compositions, trace elements (REE, Y, Cr, Sr, and Zr) show continuous core to rim zoning profiles. The observed trace element systematics in clinopyroxene cannot be explained by a simple diffusive exchange between melts and gabbros along grain boundaries. A simultaneous modification of the melt composition is required to generate the zoning, although Rayleigh fractional crystallization modelling could mimic the general shape of the profiles. Simultaneous metasomatism between the cumulate crystal and the porous melt during crystal accumulation is the most likely process to explain the zoning. Deformation during solidification of the crystal mush could have caused squeezing out of the incompatible element enriched residual melts (interstitial liquid). Migration of the melt along grain boundaries might carry these melt out of the system. This process named as synkinematic differentiation or differentiation by deformation (Natland and Dick in J Volcanol Geotherm Res 110(3–4):191–233, 2001) may act as an important magma evolution mechanism in the oceanic crust, at least at slow-spreading ridges.  相似文献   

Permanganate Treatment of an Emplaced DNAPL Source     

Neil R. Thomson  Eric D. Hood  Grahame J. Farquhar 《Ground Water Monitoring & Remediation》2007,27(4):74-85

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