Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite          下载免费PDF全文

Ann‐Christine Ritter  Vasileios Mavromatis  Martin Dietzel  Ola Kwiecien  Felix Wiethoff  Erika Griesshaber  Laura A. Casella  Wolfgang W. Schmahl  Jennifer Koelen  Rolf D. Neuser  Albrecht Leis  Dieter Buhl  Andrea Niedermayr  Sebastian F. M. Breitenbach  Stefano M. Bernasconi  Adrian Immenhauser 《Sedimentology》2017,64(5):1354-1380

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.  相似文献   

Analysis of the contribution of natural sources of radiation to the total dose received by workers     

Carlos Sainz  Ismael Fuente  Luis Quindós  Jose Luis Gutierrez  Jose Luis Arteche  Luis Santiago Quindós 《Acta Geophysica》2010,58(5):957-962

People working with ionising radiation are receiving radiation coming from artificial and natural sources. In Spain, as in many other countries, there is a serious control by the national authorities, Spanish Nuclear Safety Council, of the dose the workers receive from artificial sources. However, until the publication of the European Basic Safety Standards Directive, 96/29/EURATOM, the old criteria referring to the “above natural background” were widely used. This directive was incorporated to the Spanish legislation in July 2001 (BOE 178); in its Title VII it recommends to evaluate the dose coming from natural sources and take it into account for establishing the safety criteria. It is noteworthy to assess the natural doses received at homes and the dose received by workers of radioactive installations subject to regulations, and to compare the two results. The social and economical implications of the results derived can be important in the practical application of the recommendations included in the above-mentioned BOE 178 Directive.  相似文献   

Residual Exchange Flows in Subtropical Estuaries   总被引：1，自引：0，他引：1  

Arnoldo Valle-Levinson  Guillermo Gutierrez de Velasco  Armando Trasviña  Alejandro J. Souza  Reginaldo Durazo  Ashish J. Mehta 《Estuaries and Coasts》2009,32(1):54-67

Observations of residual exchange flows at the entrance to four subtropical estuaries, two of them semiarid, indicate that these flows are mainly tidally driven, as they compare favorably with theoretical patterns of tidal residual flows. In every estuary examined, the tidal behavior was that of a standing or near-standing wave, i.e., tidal elevation and tidal currents were nearly in quadrature. The pattern of exchange flow that persisted at every estuary exhibited inflow in the channel and outflow over the shoals. Curiously, but also fortuitously, this pattern coincides with the exchange pattern driven by density gradients in other estuaries. The tidal stresses and the residual elevation slopes should be the dominant mechanisms that drive such tidal residual pattern because the Stokes transport mechanism is negligible for standing or near-standing waves. Time series measurements from the semiarid estuaries showed fortnightly modulation of the residual flow by tidal forcing in such a way that the strongest net exchange flows developed with the largest tidal distortions, i.e., during spring tides. This modulation is opposite to the modulation that typically results in temperate estuaries, where the strongest net exchange flows tend to develop during neap tides. The fortnightly modulation on tidal residual currents could be inferred from previous theoretical results because residual currents arise from tidal distortions but is made explicit in this study. The findings advanced herein should allow the drawing of generalities about exchange flow patterns in subtropical estuaries where residual flows are mainly driven by tides.  相似文献   

Human and Environmental Factors Affect Patterns of Crop Diversity in an Ethiopian Highland Agroecosystem     

Leah H. Samberg  Carol Shennan  Erika S. Zavaleta 《The Professional geographer》2013,65(3):395-408

The Ethiopian highlands are a center of diversity for numerous globally important crops. Heterogeneous landscapes, traditional agricultural practices, and inaccessibility have created and maintained diverse subsistence agroecosystems. We surveyed sixty-three farms in twelve communities of the Gamo highlands and found high levels of on-farm diversity of crop species and varieties. The extent and nature of this diversity are related to both ecological factors, namely elevation, and anthropogenic factors such as land-use history, accessibility to markets and extension, and strength and scale of farmer exchange networks. These human landscape features have the potential to both enhance and mediate effects of elevation and other environmental factors on crop diversity. The interaction of environmental and anthropogenic forces on the diversity of crops grown by farmers affects the strategies farmers employ to adapt their farming to changing conditions.  相似文献   

The use of radon as tracer in environmental sciences     

Luis S. Quindos Poncela  Carlos Sainz Fernandez  Ismael Fuente Merino  Jose L. Gutierrez Villanueva  Alberto Gonzalez Diez 《Acta Geophysica》2013,61(4):848-858

Radon can be used as a naturally occurring tracer for environmental processes. By means of grab-sampling or continuous monitoring of radon concentration, it is possible to assess several types of dynamic phenomena in air and water. We present a review of the use of radon and its progeny at the University of Cantabria. Radon can be an atmospheric dynamics indicator related with air mass interchange near land-sea discontinuities as well as for the study of vertical variations of air parameters (average values of different types of stability: 131–580 Bq m^?3). Concerning indoor gas, we present some results obtained at Altamira Cave (Spain): from 222 to 6549 Bq m^?3 (Hall) and from 999 to 6697 Bq m^?3 (Paintings Room). Finally, variations of radon concentration in soil (0.3 to 9.1 kBq m^?3) and underground water (values up to 500 Bq l^?1) provide relevant information about different geophysical phenomena.  相似文献   

Geology of the epithermal Ag–Au Huevos Verdes vein system and San José district, Deseado massif, Patagonia, Argentina     

Andreas Dietrich  Ronald Gutierrez  Eric P. Nelson  Paul W. Layer 《Mineralium Deposita》2012,47(3):233-249

The San José district is located in the northwest part of the Deseado massif and hosts a number of epithermal Ag–Au quartz veins of intermediate sulfidation style, including the Huevos Verdes vein system. Veins are hosted by andesitic rocks of the Bajo Pobre Formation and locally by rhyodacitic pyroclastic rocks of the Chon Aike Formation. New ⁴⁰Ar/³⁹Ar constraints on the age of host rocks and mineralization define Late Jurassic ages of 151.3 ± 0.7 Ma to 144.7 ± 0.1 Ma for volcanic rocks of the Bajo Pobre Formation and of 147.6 ± 1.1 Ma for the Chon Aike Formation. Illite ages of the Huevos Verdes vein system of 140.8 ± 0.2 and 140.5 ± 0.3 Ma are 4 m.y. younger than the volcanic host rock unit. These age dates are among the youngest reported for Jurassic volcanism in the Deseado massif and correlate well with the regional context of magmatic and hydrothermal activity. The Huevos Verdes vein system has a strike length of 2,000 m, with several ore shoots along strike. The vein consists of a pre-ore stage and three main ore stages. Early barren quartz and chalcedony are followed by a mottled quartz stage of coarse saccharoidal quartz with irregular streaks and discontinuous bands of sulfide-rich material. The banded quartz–sulfide stage consists of sulfide-rich bands alternating with bands of quartz and bands of chlorite ± illite. Late-stage sulfide-rich veinlets are associated with kaolinite gangue. Ore minerals are argentite and electrum, together with pyrite, sphalerite, galena, chalcopyrite, minor bornite, covellite, and ruby silver. Wall rock alteration is characterized by narrow (< 3 m) halos of illite and illite/smectite next to veins, grading outward into propylitic alteration. Gangue minerals are dominantly massive quartz intergrown with minor to accessory adularia. Epidote, illite, illite/smectite, and, preferentially at deeper levels, Fe-chlorite gangue indicate near-neutral pH hydrothermal fluids at temperatures of >220°C. Kaolinite occurring with the late sulfide-rich veinlet stage indicates pH < 4 and a temperature of <200°C. The Huevos Verdes system has an overall strike of 325°, dipping on average 65° NE. The orientations of individual ore shoots are controlled by vein strike and intersecting north-northwest-striking faults. We propose a structural model for the time of mineralization of the San José district, consisting of a conjugate shear pair of sinistral north-northwest- and dextral west-northwest-striking faults that correspond to R and R′ in the Riedel shear model and that are related to master faults (M) of north-northeast-strike. Veins of 315° strike can be interpreted as nearly pure extensional fractures (T). Variations in vein strike predict an induced sinistral shear component for strike directions of >315°, whereas strike directions of <315° are predicted with an induced dextral strike–slip movement. The components of the structural model appear to be present on a regional scale and are not restricted to the San José district.  相似文献   

Optimal location of piles in slope stabilization by limit analysis   总被引：2，自引：1，他引：1  

Xinpo Li  Xiangjun Pei  Marte Gutierrez  Siming He 《Acta Geotechnica》2012,7(3):253-259

Many studies have been conducted to establish the optimal location of a row of piles to reinforce and stabilize slopes. However, the results obtained are very different, and in some cases even inconsistent and contradictory. The factor of safety of piled slopes is determined by the magnitude of resistive forces exerted by the piles on the slope. At the same time, the maximum retaining forces provided by the piles are also affected by the pile position. In this paper, the problem of the optimal location of piles used to stabilize slopes is analyzed using a combination of limit slope stability analysis and the theory of Ito and Matsui (Soils Found 15:43?C59, 8) to calculate limit lateral loads on piles. Using an illustrative example slope, some of the issues including the most effective position, the most suitable position, and the position with the largest safety factor are discussed. The results show that the most effective pile position, the most suitable pile position, and pile position where the factor of safety can take maximum value are different from each other for a given slope.  相似文献   

<Emphasis Type="Italic">Scombroclupea occidentalis</Emphasis> sp. nov. (Clupeiformes,Teleostei) from the Cenomanian (Cretaceous) Plattenkalk deposits of NE Mexico     

Samuel Giersch  Eberhard Frey  Wolfgang Stinnesbeck  Christina Ifrim  José Manuel Padilla Gutierrez 《Swiss Journal of Geoscience》2011,104(1):73-84

A new species of the clupeid genus Scombroclupea is described from the Upper Cretaceous (Cenomanian) Plattenkalk locality “Loma la Mula” in Coahuila, northeastern Mexico. The material provides new osteological data for the genus, which clarify its systematic position. The Mexican Scombroclupea points to an occurrence of the genus in the western Tethys and indicates a vicariant event between S. macrophthalma from Lebanon and Croatia and the new species described herein. The analysis of the functional morphology of Scombroclupea supports the reconstruction of an oscillatory locomotion mode in this genus.  相似文献   

26Al‐26Mg isotope systematics of the first solids in the early solar system     

Noriko T. Kita  Qing‐Zhu Yin  Glenn J. MacPherson  Takayuki Ushikubo  Benjamin Jacobsen  Kazuhide Nagashima  Erika Kurahashi  Alexander N. Krot  Stein B. Jacobsen 《Meteoritics & planetary science》2013,48(8):1383-1400

High‐precision bulk aluminum‐magnesium isotope measurements of calcium‐aluminum‐rich inclusions (CAIs) from CV carbonaceous chondrites in several laboratories define a bulk ²⁶Al‐²⁶Mg isochron with an inferred initial ²⁶Al/²⁷Al ratio of approximately 5.25 × 10^?5, named the canonical ratio. Nonigneous CV CAIs yield well‐defined internal ²⁶Al‐²⁶Mg isochrons consistent with the canonical value. These observations indicate that the canonical ²⁶Al/²⁷Al ratio records initial Al/Mg fractionation by evaporation and condensation in the CV CAI‐forming region. The internal isochrons of igneous CV CAIs show a range of inferred initial ²⁶Al/²⁷Al ratios, (4.2–5.2) × 10^?5, indicating that CAI melting continued for at least 0.2 Ma after formation of their precursors. A similar range of initial ²⁶Al/²⁷Al ratios is also obtained from the internal isochrons of many CAIs (igneous and nonigneous) in other groups of carbonaceous chondrites. Some CAIs and refractory grains (corundum and hibonite) from unmetamorphosed or weakly metamorphosed chondrites, including CVs, are significantly depleted in ²⁶Al. At least some of these refractory objects may have formed prior to injection of ²⁶Al into the protosolar molecular cloud and its subsequent homogenization in the protoplanetary disk. Bulk aluminum and magnesium‐isotope measurements of various types of chondrites plot along the bulk CV CAI isochron, suggesting homogeneous distribution of ²⁶Al and magnesium isotopes in the protoplanetary disk after an epoch of CAI formation. The inferred initial ²⁶Al/²⁷Al ratios of chondrules indicate that most chondrules formed 1–3 Ma after CAIs with the canonical ²⁶Al/²⁷Al ratio.  相似文献   

Evolution of the Taupo Volcanic Center, New Zealand: petrological and thermal constraints from the Omega dacite     

Sarah E. Gelman  Chad D. Deering  Francisco J. Gutierrez  Olivier Bachmann 《Contributions to Mineralogy and Petrology》2013,166(5):1355-1374

The 20 ka ~0.1 km³ Omega dacite, which erupted shortly after the 26.5 ka Oruanui super-eruption, compositionally stands out among Taupo Volcanic Zone (TVZ) magmas, which are overwhelmingly characterized by rhyolites (>90 % by volume). The previously reported presence of inherited zircons in this zircon-undersaturated magma has provided unequivocal evidence for the involvement of upper-crustal material in a 1–10 year timescale prior to the Omega eruption. However, whether this crustal involvement is characterized by wholesale, melting of preexisting crust or subordinate bulk assimilation into an already differentiated magma body remains unclear. To disentangle these processes, we describe the mineral chemistry of the major phases present in the Omega dacite and determine intensive parameters describing magma chamber conditions. Dominantly unimodal populations of plagioclase (An_50–60), orthopyroxene (Mg# from 58 to 68), and clinopyroxene (Mg# from 65 to 73), along with coexisting equilibrium pairs of Fe–Ti oxides, constrain pre-eruptive temperatures to 850–950 °C, a pressure between ~3 and 7 kbars, and an oxygen fugacity of ~NNO. MELTS thermodynamic modeling suggests that this phase assemblage is in equilibrium with the bulk rock and glass compositions of the Omega dacite at these estimated P–T–fO₂ pre-eruptive conditions. Combining these petrological observations with insights into conductive thermal models of magma–crust interactions, we argue that the Omega dacite more likely formed in the mid-to-lower crust via protracted processing through fractional crystallization coupled with some assimilation (AFC). Incorporation of crustal material is likely to have occurred at various stages, with the inherited zircons (and potentially parts of glomerocrysts) representing late and subordinate upper-crustal assimilants. This petrogenetic model is consistent with the presence of a differentiating crustal column, consisting of a polybaric fractional crystallization and assimilation history. On the basis of petrological, thermal, and geophysical considerations, upper-crustal reservoirs, which feed large-scale rhyolitic volcanism in the TVZ, most likely take the form of large, long-lived crystal mush zones. Following large eruptions, such as the Oruanui event, this mush is expected to crystallize significantly (up to 70–80 vol% crystals) due to syn-eruptive decompression. Hence, the Omega dacite, immediately post-dating the Oruanui event, potentially represents incoming deeper recharge of less-evolved magma that was able to penetrate the nearly solidified upper-crustal mush. Over the past 20,000 years, similar intermediate recharge magmas have incrementally reheated, reconstructed, and reactivated the upper-crustal mush zone, allowing a gradual return to rhyolitic volcanism at the Taupo Volcanic Center.  相似文献