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121.
Since the mid 1990s, the Atlantic and Gulf Coast regions have experienced a dramatic increase in the number of hurricane landfalls. In eastern North Carolina alone, eight hurricances have affected the coast in the past 9 years. These storms have exhibited individualistic hydrologic, nutrient, and sediment loading effects and represent a formidable challenge to nutrient management aimed at reducing eutrophication in the Pamlico Sound and its estuarine tributaries. Different rainfall amounts among hurricanes lead to variable freshwater and nutrient discharge and variable nutrient, organic matter, and sediment enrichment. These enrichments differentially affected physical and chemical properties (salinity, water residence time, transparency, stratification, dissolved oxygen), phytoplankton primary production, and phytoplankton community composition. Contrasting ecological responses were accompanied, by changes in nutrient and oxygen cycling, habitat, and higher trophic levels, including different direct effects on fish populations. Floodwaters from the two largest hurricances, Fran (1996) and Floyd (1999), exerted, multi-month to multi-annual effects on hydrology, nutrient loads, productivity, and biotic composition. Relatively low rainfall coastal hurricanes like Isabel (2003) and Ophelia (2005) caused strong vertical mixing and storm surges, but relatively minor hydrologic and nutrient effects. Both hydrologic loading and wind forcing are important drivers and must be integrated with nutrient loading in assessing short-term and long-term ecological effects of these storms. These climatic forcings cannot be managed but should be considered in the development of water quality management strategies for these and other large estuarine ecosystems faced with increasing frequencies and intensities of hurricane activity.  相似文献   
122.
Interannual variability over South America (SA) is mainly controlled by the El Niño-Southern Oscillation (ENSO) phenomenon. This study investigates the ENSO precipitation signal during austral spring (September–October–November-SON) over SA. Three global circulation models-GCMs-(MPI, GFDL and HadGEM2) are used for RegCM4 (Regional Climate Model version 4) downscaling of the present (1975–2005) near-future (2020–2050) and far-future (2070–2098) climates using two greenhouse gas stabilization scenarios (RCP4.5 and RCP8.5). For the present climate, only HadGEM2 simulates a frequency of El Niño (EN) and La Niña (LN) years similar to the observations. In terms of ENSO frequency changes, only in the far-future RCP8.5 climate there is greater agreement among GCMs, indicating an increase (decrease) of EN (LN) years. In the present climate, validation indicates that only the RegCM4 ensemble mean provides acceptable precipitation biases (smaller than ±20 %) in the two investigated regions. In this period, the GCMs and RegCM4 agree on the relationship between ENSO and precipitation in SA, i.e., both are able to capture the observed regions of positive/negative rainfall anomalies during EN years, with RegCM4 improving on the GCMs’ signal over southeastern SA. For the near and far future climates, in general, the projections indicate an increase (decrease) of precipitation over southeastern SA (northern-northeastern SA). However, the relationship between ENSO and rainfall in most of RegCM4 and GCM members is weaker in the near and far future climates than in the present day climate. This is likely connected with the GCMs’ projection of the more intense ENSO signal displaced to the central basin of Pacific Ocean in the far future compared to present climate.  相似文献   
123.
This paper reports on recent progress towards improved predictions of a land surface-hydrological modelling system, Modélisation Environmentale–Surface et Hydrologie (MESH), via its calibration over the Laurentian Great Lakes Basin. Accordingly, a “global” calibration strategy is utilized in which parameters for all land class types are calibrated simultaneously to a number of sub-basins and then validated in time and space. Model performance was evaluated based on four performance metrics, including the Nash-Sutcliffe (NS) coefficient and simulated compared with observed hydrographs. Results from two calibration approaches indicate that in the model validation mode, the global strategy generates better results than an alternative calibration strategy, referred to as the “individual” strategy, in which parameters are calibrated individually to a single sub-basin with a dominant land type and then validated in a different sub-basin with the same dominant land type. The global calibration strategy was relatively successful despite the large number of calibration parameters (51) and relatively small number of model evaluations (1000) used in the automatic calibration procedure. The NS values for spatial validation range from 0.10 to 0.72 with a median of 0.41 for the 15 sub-basins considered. Results also confirm that a careful model calibration and validation is needed before any application of the model.  相似文献   
124.
The O’okiep Copper District is the oldest formal mining area in South Africa. Between 1852 and 2002, the 2,500 km2 area yielded two million tons of copper from 32 mines ranging in ore tonnages from 140,000 to 37 million tons. This paper summarizes the calendar of events from the formation of the first primitive crust 1,700–2,000?Ma ago to early Cambrian times ~500?Ma ago, with particular emphasis on the Namaquan (Grenville) Orogeny, notably: the O’okiepian Episode (1,180–1,210?Ma ago) of alpine-type folding, regional granite plutonism, and granulite facies metamorphism and the Klondikean Episode (1,020–1,040?Ma ago) of open and tight folding and the intrusion of the Rietberg Granite and the Koperberg Suite. Almost all of the copper in the O’okiep District occurs in the Koperberg Suite, of which there are 1,700 small bodies that constitute 0.7% of the outcrop area. The suite comprises jotunite, anorthosite, biotite diorite, and hypersthenic rocks ranging from leuconorite to hypersthenite, and it is one of only two world examples of economic copper mineralization in rocks of the anorthosite–charnockite kindred; the second example is Caraiba, Brazil. High I Sr and low ε Nd (for a 1,030 Ma intrusion age), and high μ 2 of 10.1, for Koperberg rock-types indicate a crustal progenitor for the suite, and the presence of jotunite suggests a (subducted) crustal source at ca. 40–50 km depth. The magmatic sulphide paragenesis in the Koperberg Suite is chalcopyrite?+?pyrrhotite (Narrap-type ore) that, in a number of ore-bodies, has been inverted under upper amphibolite facies conditions to bornite?+?Ti-free magnetite (Carolusberg-type ore). Meteoric fluids resulted in supergene Cu enrichment in Koperberg bodies to ~500?m below the pre-Nama peneplane, and lower greenschist facies metamorphism 500–570?Ma ago is reflected by inter alia Hoits-type ore bearing second-generation bornite?+?chalcopyrite(±?covellite?±?chalcocite).  相似文献   
125.
The Beni Bousera peridotite massif and its metamorphic surrounding rocks have been analyzed by the fission track (FT) method. The aim was to determine the cooling and uplift history of these mantle and associated crustal rocks after the last major metamorphic event that dates back to the Lower Miocene–Upper Oligocene time (~22–24 Ma). The zircon FT analyses give an average cooling—i.e., below 320 °C—age of ~19.5 Ma. In addition, the apatite FT data give an average cooling—i.e., below 110 °C—age of ~15.5 Ma. Taking into account the thermal properties of the different thermochronological systems used in this work, we have estimated a rate of cooling close to 50 °C/Ma. This cooling rate constrains a denudation rate of about ~2 mm year?1 from 20 to 15 Ma. These results are similar to those determined in the Ronda peridotite massif of the Betic Cordilleras documenting that some ultrabasic massifs of the internal zones of the two segments of the Gibraltar Arc have a similar evolution. However, Burdigalian sediments occur along the Betic segment (Alozaina area, western Betic segment) unconformably overlying peridotite. At this site, ultramafic rock was exposed to weathering at ages ranging from 20.43 to 15.97 Ma. Since the Beni Bousera peridotite was still at depth until 15.5 Ma, we infer that no simple age projection from massif to massif is possible along the Gibraltar Arc. Moreover, the confined fission track lengths data reveal that a light warming (~100 °C) has reheated the massif during the Late Miocene before the Pliocene–Quaternary tectonic uplift.  相似文献   
126.
Brachiopod shells are widely used as an archive to reconstruct elemental and isotopic composition of seawater. Studies, focused on oxygen and carbon isotopes over the last decades, are increasingly extending to the emerging calcium isotope system. To date, only little attention has been paid to test the reliability of fossil brachiopods on their modern counterparts.In this context, the present study investigates two modern brachiopods, Terebratulina septentrionalis (eastern Canada, 5–30 m depth, 7.1 °C seasonal temperature variation, two-layer shell) and Gryphus vitreus (northern Mediterranean, 200 m depth, constant all-year round temperature, three-layer shell). Both species were sampled along the ontogenetic growth direction and calcium, oxygen, and carbon isotopes as well as elemental concentration were measured. Calcium isotopes were analyzed on TIMS. The elemental composition was analyzed by LA-ICP-MS and ICP-AES.The results indicate an intra-specimen δ44/40Ca variation ranging from 0.16 to 0.33‰, pointing to a fairly homogenous distribution of calcium isotopes in brachiopod shells. However, in the light of the suggested 0.7‰ increase in calcium isotopes over the Phanerozoic such intra-specimen variations constrain ocean reconstruction. δ44/40Ca values of T. septentrionalis do not seem to be affected by growth rate. Calcium isotopic values of G. vitreus are heavy in the central part of the shell and trend towards lighter values in peripheral areas approaching the maximum isotopic composition of T. septentrionalis. The maximum inter-species δ44/40Ca difference of 0.62‰ between T. septentrionalis and G. vitreus indicates that care should be taken when using different taxa, species with different strontium content or brachiopods with specialized shell structure, such as G. vitreus, for ocean water reconstruction in terms of Ca isotopic composition. T. septentrionalis may record Ca isotopic fractionation related to seasonal seawater temperature variations in its shell but this is difficult to resolve at the current analytical precision. Average δ18O-derived temperatures of the two investigated species are close to on-site measured temperatures.  相似文献   
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