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101.
Four different solution models, the two-parameter Margules, the quasi-chemical (QC), the Wilson and the non-random two-liquid (NRTL) model, have been used for fitting the calorimetric excess enthalpy of solution for the following four binary silicate systems: anorthite-albite, pyrope-grossular, diopside-enstatite and diopside-Ca-Tschermak. All models except the Wilson model yield a satisfactory fit to the data but the NRTL model generally results in the lowest residuals. The use of NRTL and QC facilitates the study of the configurational and non-configurational parts of the excess entropy of mixing.Three different methods, namely those of Kohler, Wohl, and Hillert, have been used to combine binary solution properties to predict ternary solution properties. Comparison of computed excess free energy of mixing in a hypothetical solution shows that all the three methods are viable but the Kohler and Wohl methods are similar to each other and are significantly different from the Hillert method. The Kohler method with one or a combination of different binary models is recommended for predicting multicomponent solution properties.Abbreviations G ex excess free energy of mixing - H ex excess enthalpy of mixing - S ex total excess entropy of mixing - S ex c configurational excess entropy of mixing - W ij interaction energy parameter between speciesi andj - X i mole fraction of speciesi - QC quasi-chemical - NRTL non-random two-liquid - M Margules formulation - W Wohl's formulation - RK Redlich-Kister - K Bertrand-Kohler - H Hillert - Di diopside (CaMgSi2O6) - En enstatite (Mg2Si2O6) - Py pyrope (MgAl2/3SiO4) - Gr grossular (CaAl2/3SiO4) - CaTs Ca-Tschermak (CaAl2SiO6) - Ab albite (NaAlSi3O8) - An anorthite (CaAl2Si2O8)  相似文献   
102.
A basal section of the Lower Proterozoic Transvaal Dolomite from the northern Cape has been re-examined. Numerous associations of stromatolites and other structures have been distinguished in it. Forms of domical stromatolite dominate the structures, but columns, and associations built around spheroidal forms, are also represented. This material accumulated in a telescoped range of environments through the intertidal to a high-energy agitated zone and out into the subtidal.Columnar forms and flat domes from the intertidal zone appear to be remarkably similar to features described from Hamelin Pool at Shark Bay, Western Australia. The subtidal elongate domes and mounds increase in size with depth to reach dimensions of 40 by 10 m, heights of 13 m and relief of 2.5 m. Minor structures on these subtidal forms reflect decreasing energy outwards; included within them are columnar forms in the shallow subtidal zone.It is suggested that deposition within an epeiric sea was away from a headland on a relatively steeply shelving floor affected by currents at right angles to the shore. There are indications that an arid to semi-arid climate existed at that time.  相似文献   
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The method of sequence stratigraphy requires the application of the same workflow and principles irrespective of the age of strata under analysis. In that respect, its application to Precambrian successions is similar to the approach used for Phanerozoic case studies. Differences, however, are recorded in terms of the preservation potential and the amount of data available for analysis; the rates and intensities of the allogenic controls on sedimentation; the environmental conditions and related physical processes; and the evolution of competing groups of organisms and associated biogenic processes. The combined effect of these contrasting aspects accounts for differences in the architecture of depositional sequences, particularly with respect to the relative contributions of various systems tracts to the makeup of a sequence.

The application of sequence stratigraphy to Precambrian basins has considerably enlarged the perspective on the fundamental principles governing the processes of sedimentary basin formation and the mechanisms controlling stratigraphic cyclicity in the rock record. These first-order principles are perhaps the most important contribution of Precambrian research to sequence stratigraphy. At the broader scale of Earth's geological history, the tectonic regimes governing the formation and evolution of sedimentary basins are shown to have been much more erratic in terms of nature and rates than originally inferred solely from the study of the Phanerozoic record. This provides important clues with respect to the criteria that should be involved in the hierarchy system of classification of stratigraphic sequences and bounding surfaces.  相似文献   

106.
Literature review underlines uncertainty in the configuration of the Neoproterozoic supercontinent, (with Rodinia and Palaeopangaea reconstructions enjoying wide support), that stems primarily from inadequate palaeomagnetic data. Nonetheless, breakup of this supercontinent at ca. 0.65 Ga was conducive for epeiric sea formation globally. In the Vindhyan basin, India, a carbonate depositing sea developed over a fluvial-aeolian plain, at approximately 0.6 Ga. The top part of the Vindhyan Supergroup, the Upper Bhander Sandstone, was, however, able to prograde because of a decline in the rate of relative sea level rise. Within this general setting, temporal increases in this rate caused storm deposition at the coastline, largely in a supralittoral setting. Bizarre amalgamation of these storm beds without erosion likely owes its origin to severe curtailment of the velocity of the downwelling flow on the very gentle, muddy coastal slopes, and is thought to be a hallmark of deposition in an open epeiric setting. The storm domination in the Bhander embayment shelf is compatible with the Palaeopangaea supercontinental configuration.  相似文献   
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The Malmani Subgroup northwest of Johannesburg consists of dolomite and chert with only minor clastic sediments.A precise upper intertidal to marginal supratidal analogy and the associated relationship of varied structures suggest that much of the succession represents a tidal flat to intertidal complex formed within differing semiprotected to protected conditions. The dolomites from these environments are recrystallized, reflecting a meteoric influence, and the cherts which are commonly developed within them are also related to prevailing lower pH's. This dolomitization is considered to have been enhanced by the influx of meteoric waters which however resulted in the dolomites having undersaturated iron-manganese ratios. Rare colour-banded dolomites containing columnar stromatolites are thought to represent more steeply shelving intertidal conditions than are normally encountered in the epeiric sea. These dolomites contain quartz crystals rather than chert, suggestive of a lower concentration of silica in the original alkaline solutions. The exposure is part of a very widespread carbonate unit, dated at ca. 2.250 m.y.Subtidal conditions in which large elongate stromatolitic domes developed can be related to a marine transgression across a basal clastic beach sand; and secondly to a progradational tidal flat seawards of which a talus breccia developed on a steepened slope leading down to the subtidal regime. These dolomites formed by interaction with marine waters saturated with respect to iron and manganese, while the absence of chert reflects persisting alkaline conditions.A dark chert-free dolomitic facies with high iron and manganese contents of saturated ratios is considered to have developed in an alkaline lagoonal environment behind a subaqueous bar that is now represented by an overlying thick oolitic unit.The succession contains numerous chert breccias with which shales are associated. The breccias represent subaerial exposure phenomena related to regressions which were followed by periods of short-lived terrigenous influx.  相似文献   
109.
Hormes, A., Akçar, N. & Kubik, P. W. 2011: Cosmogenic radionuclide dating indicates ice‐sheet configuration during MIS 2 on Nordaustlandet, Svalbard. Boreas, 10.1111/j.1502‐3885.2011.00215.x. ISSN 0300‐9483.0300‐9843 Glacial geological field surveys, aerial image interpretation and cosmogenic radionuclide (CRN) dating allowed us to reconstruct the ice‐sheet configuration on Nordaustlandet, the northernmost island of the European sector on the margin of the Arctic Ocean. The timing of deglaciation was investigated by determining the 26Al and 10Be ages of glacially scoured bedrock, weathered periglacial blockfields and glacial erratic boulders. Only 10Be ages were useful for our interpretations, because of unresolved analytical problems with 26Al. Fjords and lowlands on Nordaustlandet yielded Late Weichselian 10Be ages, indicating that actively erosive ice streams scoured the coastal fjord bathymetry during marine isotope stage (MIS) 2. In Murchisonfjorden, ground‐truthed air‐photograph interpretation and 10Be ages of boulders indicated a cold‐based glacier ice cover during MIS 2 on higher plateaus. 10Be ages and lithological studies of erratic boulders on higher and interior plateaus of Prins Oscars Land (>200–230 m a.s.l.) suggest that the Mid‐Weichselian glaciation (MIS 4) might have been more extensive than that during MIS 2.  相似文献   
110.
Irgarol is a triazine photosystem II (PSII) inhibitor that has been used in Sweden as an antifouling ingredient since the 1990s. Early microcosm studies indicated that periphyton was sensitive to irgarol at concentrations regularly found in harbours and marinas. However, field studies of irgarol effects on the Swedish west coast in 1994, using the pollution-induced community tolerance (PICT) approach, failed to detect any effects of the toxicant in the field. A PICT study involves sampling of replicate communities in a gradient of contamination, and a comparison of their community tolerance levels, with an increase being an indication that sensitive species have been eliminated and replaced by more tolerant ones. Typically, short-term assays are used to quantify the community tolerance levels. Later PICT studies in the same area over a 10 year period demonstrate that irgarol tolerance levels have increased, although the contamination pattern has been stable. Our results support the hypothesis that that the PICT potential was low initially, due to a small differential sensitivity between the community members, and that a persistent selection pressure was required to favour and enrich irgarol-tolerant species or genotypes.  相似文献   
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