Variations of stress directions in the western Alpine arc   总被引：4，自引：0，他引：4  

E. Eva  & S. Solarino 《Geophysical Journal International》1998,135(2):438-448

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Catalysis by mineral surfaces: Implications for Mo geochemistry in anoxic environments     

Trent P. VorlicekGeorge R. Helz 《Geochimica et cosmochimica acta》2002,66(21):3679-3692

Fixation of Mo in sulfidic environments is believed to be preceded by conversion of geochemically passive MoO₄²⁻ to particle-reactive thiomolybdates (MoO_xS_4−x²⁻). In aqueous solution, these transformations are general-acid catalyzed, implying that proton donors can accelerate both the forward and reverse reactions. Here, we explore whether mineral surfaces also catalyze thiomolybdate interconversions. The rate of MoS₄²⁻ hydrolysis is investigated in the presence and absence of natural kaolinite (KGa-1b) and synthetic Al₂O₃ and SiO₂ phases. Comparison of rates achieved with these phases suggests that the Al oxyhydroxide component in kaolinite furnishes the catalytic activity. An anhydrous Al₂O₃ phase is catalytically inactive until hydrated (and therefore protonated). Surface kinetics with kaolinite at mildly alkaline pH are consistent with rate limitation by formation or decomposition of monomeric surface complexes; oligomeric surface intermediates may become important at MoS₄²⁻ > 20 μmol/L, higher than is likely to be found in nature. The pH dependence of the kaolinite-catalyzed reaction suggests that weak-acid surface sites promote hydrolysis. Intermediate thiomolybdates or molybdate appears to compete for active sites, inhibiting MoS₄²⁻ hydrolysis. Catalysis of MoOS₃²⁻ hydrolysis is also observed but has not been studied systematically. Thiomolybdate hydrolysis is inhibited slightly by sulfate and more strongly by phosphate. Low NaCl concentrations (<10⁻² mol/L) promote hydrolysis, but higher NaCl concentrations retard the reaction to a small extent. A mechanism is postulated involving expansion of the coordination number around Mo from 4 to 6 under the influence of the surface. The effective concentration of surface sites available to Mo in sediment pore waters is likely to be large enough to greatly accelerate thiomolybdate hydrolysis and sulfidation. Possibly this explains why Mo capture in seasonally or intermittently anoxic environments often occurs through processes operating within sediments but not in overlying waters.  相似文献   

Climatic and oceanographic changes in the Northeast Atlantic reflected by magnetic properties of sediments deposited on the Portuguese Margin during the last 340 ka   总被引：1，自引：0，他引：1  

Eva Moreno  Nicolas Thouveny  Doriane DelangheI.Nick McCave  Nick J Shackleton 《Earth and Planetary Science Letters》2002,202(2):465-480

Rock magnetic parameters measured along two giant piston cores MD95-2040 (40°34′N, 9°51′W) and MD95-2042 (37°47′N, 10°09′W) collected off the Portuguese Margin, related to other proxy-climatic data, have been used to reconstruct magnetic mineralogical changes of, in relation to environmental and climatic conditions over the North Atlantic, Western Europe and Northwest Africa during the last three climatic cycles (since isotope stage 10). Thin discrete layers containing coarse grains of titano-magnetite are associated with events of iceberg discharge during Heinrich events 1-6 [Heinrich, Quat. Res. 29 (1988) 142] that have equivalent events in isotope stages 5-8. Concentrations of fine-grained (Ti-) magnetite and hematite/goethite, varying in phase opposition, are directly linked with alternations of cold and warm climatic periods. Spectral analyses of the rock magnetic signals reveal Milankovitch periods at 100 and 41 ka, confirming the relationship with long-term climatic changes at high latitudes. The nature (Ti-magnetite) and size range of the finest ferrimagnetic fraction as well as its variation, suggest a control by deep currents carrying a colloidal/clayey fraction from remote sources (Iceland, Faeroes, mid-Atlantic Ridge). Variation of hematite/goethite contents is linked with transport by rivers and winds from the neighbouring continent. A tight correlation with the D-O cycles in Greenland ice records confirms that North Atlantic oceanic regimes and continental wind regimes were strongly influenced by millennial scale climatic changes throughout the last 350 ka.  相似文献   

Aerosol optical thickness retrieval over the Atlantic Ocean using GOES imager data     

M Moula  J Verdebout  H Eva 《Physics and Chemistry of the Earth》2002,27(35):1525-1531

An algorithm based on simulated satellite signal calculated by the 6S radiative transfer model has been developed in order to retrieve the aerosol optical thickness of dust over the Atlantic ocean. The algorithm is applied to the visible channel of Geostationary Operational Environmental Satellite (GOES 8) images. The inversion uses a look-up table giving the satellite signal intensity as a function of surface albedo, viewing geometry, solar illumination and the optical properties of the aerosols. The study consists of assessing the feasibility of monitoring and mapping the transport of suspended particles across the Atlantic from the Sahara to the Caribbean. The study area is between 10 and 25 N and 30 and 65 W. The optical thickness of aerosols has been calculated over a period of 11 days between 10th and 20th of June 1997 for the 14:15 UT GOES image acquisition. The calculated aerosol optical thickness ranges from 0.0 to 0.81 with an important event of dust presence occurring between 13th and 16th of June. The retrieved aerosol optical thickness is in good agreement with the values obtained between 14h UT and 15h UT from ground based sun photometer measurements on the island of Guadeloupe, and a coefficient correlation (R²) of 0.88 has been found between the data sets.  相似文献   

Inorganic nutrient acquisition in a shallow clearwater lake – dominance of benthic microbiota     

Eva Andersson  Anna-Kristina Brunberg 《Aquatic Sciences - Research Across Boundaries》2006,68(2):172-180

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Comparing analytical and numerical approaches to meteoroid orbit determination using Hayabusa telemetry     

Trent Jansen‐Sturgeon  Eleanor K. Sansom  Philip A. Bland 《Meteoritics & planetary science》2019,54(9):2149-2162

Fireball networks establish the trajectories of meteoritic material passing through Earth's atmosphere, from which they can derive pre‐entry orbits. Triangulated atmospheric trajectory data require different orbit determination methods to those applied to observational data beyond the Earth's sphere of influence, such as telescopic observations of asteroids. Currently, the vast majority of fireball networks determine and publish orbital data using an analytical approach, with little flexibility to include orbital perturbations. Here, we present a novel numerical technique for determining meteoroid orbits from fireball network data and compare it to previously established methods. The re‐entry of the Hayabusa spacecraft, with its known pre‐Earth orbit, provides a unique opportunity to perform this comparison as it was observed by fireball network cameras. As initial sightings of the Hayabusa spacecraft and capsule were made at different altitudes, we are able to quantify the atmosphere's influence on the determined pre‐Earth orbit. Considering these trajectories independently, we found the orbits determined by the novel numerical approach to align closer to JAXA's telemetry in both cases. Using simulations, we determine the atmospheric perturbation to become significant at ~90 km—higher than the first observations of typical meteorite dropping events. Using further simulations, we find the most substantial differences between techniques to occur at both low entry velocities and Moon passing trajectories. These regions of comparative divergence demonstrate the need for perturbation inclusion within the chosen orbit determination algorithm.  相似文献   

Averaged model to study long-term dynamics of a probe about Mercury     

Eva Tresaco  Jean Paulo S. Carvalho  Antonio F. B. A. Prado  Antonio Elipe  Rodolpho Vilhena de Moraes 《Celestial Mechanics and Dynamical Astronomy》2018,130(2):9

This paper provides a method for finding initial conditions of frozen orbits for a probe around Mercury. Frozen orbits are those whose orbital elements remain constant on average. Thus, at the same point in each orbit, the satellite always passes at the same altitude. This is very interesting for scientific missions that require close inspection of any celestial body. The orbital dynamics of an artificial satellite about Mercury is governed by the potential attraction of the main body. Besides the Keplerian attraction, we consider the inhomogeneities of the potential of the central body. We include secondary terms of Mercury gravity field from \(J_2\) up to \(J_6\), and the tesseral harmonics \(\overline{C}_{22}\) that is of the same magnitude than zonal \(J_2\). In the case of science missions about Mercury, it is also important to consider third-body perturbation (Sun). Circular restricted three body problem can not be applied to Mercury–Sun system due to its non-negligible orbital eccentricity. Besides the harmonics coefficients of Mercury’s gravitational potential, and the Sun gravitational perturbation, our average model also includes Solar acceleration pressure. This simplified model captures the majority of the dynamics of low and high orbits about Mercury. In order to capture the dominant characteristics of the dynamics, short-period terms of the system are removed applying a double-averaging technique. This algorithm is a two-fold process which firstly averages over the period of the satellite, and secondly averages with respect to the period of the third body. This simplified Hamiltonian model is introduced in the Lagrange Planetary equations. Thus, frozen orbits are characterized by a surface depending on three variables: the orbital semimajor axis, eccentricity and inclination. We find frozen orbits for an average altitude of 400 and 1000 km, which are the predicted values for the BepiColombo mission. Finally, the paper delves into the orbital stability of frozen orbits and the temporal evolution of the eccentricity of these orbits.  相似文献   

Experiments on the morphological controls of velocity inversions in bedrock canyons          下载免费PDF全文

Brendan Hunt  Jeremy G. Venditti  Eva Kwoll 《地球表面变化过程与地形》2018,43(3):654-668

A better understanding of bedrock incision mechanisms and processes is essential to the study of long‐term landscape evolution. Yet, little is known about flow dynamics in bedrock rivers, limiting our ability to make realistic predictions of local bedrock incision rates. A recent investigation of flow through bedrock canyons of the Fraser River revealed that plunging flows, defined by the downward‐directed movement of near surface flow toward the channel bed, occur in channels that have low width‐to‐depth ratios. Plunging flows occur into deep scour pools, which are often coincident with lateral constrictions and channel spanning submerged ridges (sills). A phenomenological investigation was undertaken to reproduce the flow fields observed in the Fraser canyons and to explore morphological controls on the occurrence and relative strength of plunging flow in bedrock canyons. Our observations show that the plunging flow structure can be produced along a scour pool entrance slope by accelerating the flow at the canyon entrance either over submerged sills or through lateral constrictions. Plunging flow appears to be a function of convective deceleration into a scour pool which can be enhanced by sill height, the amount of the channel width that is constricted, pool entrance slope, discharge, and a reduction in channel width‐to‐depth ratio. Plunging flow greatly enhances the potential for incision to occur along the channel bed and is an extreme departure from the assumptions of steady, uniform flow in bedrock incision models, highlighting the need for improved formulations that account for fluid flow. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Directional wave spectra at the regional scale with the KuROS airborne radar: comparisons with models     

Le Merle  Eva  Hauser  Danièle  Tison  Céline 《Ocean Dynamics》2019,69(6):679-699

Ocean Dynamics - In situ observations, satellite observations, and regional observations from airborne remote sensing are very useful to characterize sea state evolution and related physical...  相似文献   

Interaction of wind and cold-season hydrologic processes on erosion from complex topography following wildfire in sagebrush steppe     

Samantha P. Vega  C. Jason Williams  Erin S. Brooks  Frederick B. Pierson  Eva K. Strand  Peter R. Robichaud  Robert E. Brown  Mark S. Seyfried  Kathleen A. Lohse  Kayla Glossner  Jennifer L. Pierce  Clay Roehner 《地球表面变化过程与地形》2020,45(4):841-861

Wildfire is a natural component of sagebrush (Artemisia spp.) steppe rangelands that induces temporal shifts in plant community physiognomy, ground surface conditions, and erosion rates. Fire alteration of the vegetation structure and ground cover in these ecosystems commonly amplifies soil losses by wind- and water-driven erosion. Much of the fire-related erosion research for sagebrush steppe has focused on either erosion by wind over gentle terrain or water-driven erosion under high-intensity rainfall on complex topography. However, many sagebrush rangelands are geographically positioned in snow-dominated uplands with complex terrain in which runoff and sediment delivery occur primarily in winter months associated with cold-season hydrology. Current understanding is limited regarding fire effects on the interaction of wind- and cold-season hydrologic-driven erosion processes for these ecosystems. In this study, we evaluated fire impacts on vegetation, ground cover, soils, and erosion across spatial scales at a snow-dominated mountainous sagebrush site over a 2-year period post-fire. Vegetation, ground cover, and soil conditions were assessed at various plot scales (8 m² to 3.42 ha) through standard field measures. Erosion was quantified through a network of silt fences (n = 24) spanning hillslope and side channel or swale areas, ranging from 0.003 to 3.42 ha in size. Sediment delivery at the watershed scale (129 ha) was assessed by suspended sediment samples of streamflow through a drop-box v-notch weir. Wildfire consumed nearly all above-ground live vegetation at the site and resulted in more than 60% bare ground (bare soil, ash, and rock) in the immediate post-fire period. Widespread wind-driven sediment loading of swales was observed over the first month post-fire and extensive snow drifts were formed in these swales each winter season during the study. In the first year, sediment yields from north- and south-facing aspects averaged 0.99–8.62 t ha⁻¹ at the short-hillslope scale (~0.004 ha), 0.02–1.65 t ha⁻¹ at the long-hillslope scale (0.02–0.46 ha), and 0.24–0.71 t ha⁻¹ at the swale scale (0.65–3.42 ha), and watershed scale sediment yield was 2.47 t ha⁻¹. By the second year post fire, foliar cover exceeded 120% across the site, but bare ground remained more than 60%. Sediment yield in the second year was greatly reduced across short- to long-hillslope scales (0.02–0.04 t ha⁻¹), but was similar to first-year measures for swale plots (0.24–0.61 t ha⁻¹) and at the watershed scale (3.05 t ha⁻¹). Nearly all the sediment collected across all spatial scales was delivered during runoff events associated with cold-season hydrologic processes, including rain-on-snow, rain-on-frozen soils, and snowmelt runoff. Approximately 85–99% of annual sediment collected across all silt fence plots each year was from swales. The high levels of sediment delivered across hillslope to watershed scales in this study are attributed to observed preferential loading of fine sediments into swale channels by aeolian processes in the immediate post-fire period and subsequent flushing of these sediments by runoff from cold-season hydrologic processes. Our results suggest that the interaction of aeolian and cold-season hydrologic-driven erosion processes is an important component for consideration in post-fire erosion assessment and prediction and can have profound implications for soil loss from these ecosystems. © 2019 John Wiley & Sons, Ltd.  相似文献