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Martha Riherd Weller Marian Furst T.A. Tombrello D.S. Burnett 《Geochimica et cosmochimica acta》1978,42(7):999-1009
We have analyzed B in carbonaceous chondrites in order to clarify a factor of 100 difference between the solar system B abundance derived from the solar photosphere and that inferred from previous meteorite data. Consistent results were obtained from two instrumental methods for B analysis: (a) counting of the high energy betas from 12B produced by the 11B(d,p) reaction, and (b) measurement of particle track densities from 10B(n,α)7Li in a plastic track detector affixed to a homogenized meteorite sample. Contamination is a major problem in B analyses, but extensive testing showed that our results were not seriously affected. Our B concentrations are typically 1–2 ppm and are a factor of 2–6 lower than previous carbonaceous chondrite measurements. Our data for the Cl chondrites Ivuna and Orgueil would indicate a solar system B/Si atomic abundance ratio of 58 × 10?6, but this is still a factor of 2–10 higher than the photospheric estimates. It may be that B is depleted in the sun by thermonuclear processes; however, the similarity of photospheric and meteoritic Be abundances is a problem for this point of view. Alternatively, B may be enhanced in carbonaceous chondrites, but this would make B a cosmochemically unique element. A mm-sized (Fe,Mn,Mg)CO3 crystal from Orgueil shows no B enrichment. We find 10B ≤ 1016 atoms/g in two Allende fine-grained inclusions suggesting that B is not a refractory element under solar nebula conditions. This 10B limit, when taken as a limit on 10Be when the inclusion formed, puts constraints on the possibility of a solar system synthesis of 26Al. For a proton spectrum of E?a, a must be ≥ 3 if a solar gas is irradiated or a ≥1.5 if dust of solar composition is irradiated. 相似文献
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Evan K. Nyer 《Ground Water Monitoring & Remediation》1999,19(1):62-66
"The EPA decided that showing the presence of DNAPL would prove that cleanup to non-detect was improbable, and that a new end point could be selected."
"The only thing that really matters is the total mass of from the natural attenuation." 相似文献
"The only thing that really matters is the total mass of from the natural attenuation." 相似文献
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Phillip H. Larson Ronald I. Dorn R. Evan Palmer Zack Bowles Emma Harrison Scott Kelley 《自然地理学》2014,35(5):369-389
The Sonoran Desert portion of the Basin and Range physiographic province contains a number of streams that now flow across once-closed basins. We explore here the research questions of if and how granitic rock pediments respond to the transition from rimming endorheic basins to bordering through-flowing streams. Granitic rock pediments of the northern Usery and eastern McDowell Mountains once graded to the closed Miocene–Pliocene Pemberton basin that occupied the present-day location of the confluence of the Salt and Verde Rivers. The process of lake overflow, which integrated these rivers, first aggraded fill terraces that, in turn, caused aggradation of a mantle of transported grus on bedrock pediments. Subsequent episodic incision of the Salt and Verde rivers lowered the base level; this led to the development of erosional features such as rolling topography of a degrading pediment mantle; exposure of the former piedmont angle and its associated zones of enhanced bedrock decay and regolith carbonate; and exposure of spheroidally weathered bedrock and emerging tors, some of which experienced 20th century erosion. The granitic pediments of the former Pemberton Basin, which now transport grus to the Salt and Verde rivers, have actively adjusted to aggradational and degradational events associated with drainage integration and do not appear to be inherited from an ancient wet climatic interval. 相似文献
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Mineral inclusions in fibrous diamonds: constraints on cratonic mantle refertilization and diamond formation 总被引:1,自引:0,他引:1
We analyzed mineral microinclusions in fibrous diamonds from the Wawa metaconglomerate (Superior craton) and Diavik kimberlites (Slave craton) and compared them with published compositions of large mineral inclusions in non-fibrous diamonds from these localities. The comparison, together with similar datasets available for Ekati and Koffiefontein kimberlites, suggest a general pattern of metasomatic alteration imposed on the ambient mantle by formation of fibrous diamond. Calcium and Fe enrichment of peridotitic garnet and pyroxenes and Fe enrichment of olivine associated with fibrous diamond-forming fluids contributes to refertilization of the cratonic mantle. Saline—carbonatitic—silicic fluid trapped by fibrous diamonds may represent one of the elusive agents of mantle refertilization. Calcium enrichment of peridotitic garnet and pyroxenes is expected in local mantle segments during fibrous diamond production, as Ca in the carbonatitic fluids is deposited into the surrounding mantle when oxidized carbon is reduced to diamond. Harzburgitic garnet evolves towards Ca-rich compositions even when it interacts with Ca-poor saline fluids. An unusual trend of Mg enrichment to Fo95–98 is observed in some olivine inclusions in Wawa fibrous diamonds. The trend may result from the carbonatitic composition of the fluid that promotes crystallization of magnesian olivine and preferentially oxidizes the fayalite component. We propose a generic model of fibrous and non-fibrous diamond formation from carbonatitic fluids that explains enrichment of the mantle in mafic magmaphile and incompatible elements and accounts for locally metasomatized compositions of diamond inclusions. 相似文献
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