Particle fluxes and recent sediment accumulation on the Aquitanian margin of Bay of Biscay     

Sabine Schmidt  Hélène Howa  Aurelia Mouret  Fabien Lombard  Pierre Anschutz  Laurent Labeyrie 《Continental Shelf Research》2009,29(8):1044-1052

As a part of the ANR-Forclim experiment, particle mass fluxes and sedimentation processes were investigated on the slope of Aquitanian margin of the Bay of Biscay, between the canyons of Cap-Breton and Cap-Ferret. Interface sediments were collected along a depth transect from 145 to 2000 m; simultaneously a mooring line was deployed at the deepest station (WH, 2000 m) with two traps (800 and 1700 m) for a 16-month period (June 2006–November 2007). ²¹⁰Pb activities of settling particles and of interface sediments were determined to study transport processes of particles. Sediment and mass accumulation rates, calculated from excess ²¹⁰Pb profiles in the sediment column, show the expected decreasing trend with depth, as usually observed on margins. Mean particulate mass fluxes at 800 and 1700-m depth at site WH are, respectively, 27 and 70 g m^?2 a^?1.The ²¹⁰Pb budget points out events of temporary high lateral input of particles. The comparison of mass and ²¹⁰Pb fluxes between the water column and the seabed indicates that lateral transport plays an important role in particle accumulation on the Aquitanian margin. Regarding the objectives of the ANR-Forclim program, which aims to improve significantly the interpretation of fossil foraminifera signals, as a proxy for hydrological changes in the North Atlantic ocean, these results highlight advection processes must be considered when interpreting fluxes of foraminifers on the Aquitanian margin.  相似文献   

Hydrous partial melting in the sheeted dike complex at fast spreading ridges: experimental and natural observations   总被引：5，自引：1，他引：4  

Lydéric France  Juergen Koepke  Benoit Ildefonse  Sarah B. Cichy  Fabien Deschamps 《Contributions to Mineralogy and Petrology》2010,160(5):683-704

In ophiolites and in present-day oceanic crust formed at fast spreading ridges, oceanic plagiogranites are commonly observed at, or close to the base of the sheeted dike complex. They can be produced either by differentiation of mafic melts, or by hydrous partial melting of the hydrothermally altered sheeted dikes. In addition, the hydrothermally altered base of the sheeted dike complex, which is often infiltrated by plagiogranitic veins, is usually recrystallized into granoblastic dikes that are commonly interpreted as a result of prograde granulitic metamorphism. To test the anatectic origin of oceanic plagiogranites, we performed melting experiments on a natural hydrothermally altered dike, under conditions that match those prevailing at the base of the sheeted dike complex. All generated melts are water saturated, transitional between tholeiitic and calc-alkaline, and match the compositions of oceanic plagiogranites observed close to the base of the sheeted dike complex. Newly crystallized clinopyroxene and plagioclase have compositions that are characteristic of the same minerals in granoblastic dikes. Published silicic melt compositions obtained in classical MORB fractionation experiments also broadly match the compositions of oceanic plagiogranites; however, the compositions of the coexisting experimental minerals significantly deviate from those of the granoblastic dikes. Our results demonstrate that hydrous partial melting is a likely common process in the root zone of the sheeted dike complex, starting at temperatures exceeding 850°C. The newly formed melt can either crystallize to form oceanic plagiogranites or may be recycled within the melt lens resulting in hybridized and contaminated MORB melts. It represents the main MORB crustal contamination process. The residue after the partial melting event is represented by the granoblastic dikes. Our results support a model with a dynamic melt lens that has the potential to trigger hydrous partial melting reactions in the previously hydrothermally altered sheeted dikes. A new thermometer using the Al content of clinopyroxene is also elaborated.  相似文献   

Ionic surfactants adsorption on heterogeneous surfacesAdsorption de tensioactifs ioniques sur les surfaces hétérogènes     

Jean-Maurice Cases  Jerzy Mielczarski  Ella Mielczarska  Laurent J. Michot  Frédéric Villiéras  Fabien Thomas 《Comptes Rendus Geoscience》2002,334(9):675-688

The adsorption of surfactants from aqueous solution is a phenomenon of major importance in applications ranging from ore flotation and paint technology to enhanced oil recovery. As this paper will illustrate, the process is very complex and of high scientific interest; its results can be extended to the retention of organic compounds (humic and fulvic acids, pollutants...) on solids in the biosphere. For a good understanding of the mechanisms involved in surfactants adsorption at the hydrophilic solid–aqueous solution interface, thermodynamic models have to take into account: (i) the physical chemistry of the surfactant in aqueous solution for choosing the appropriate reference phase, (ii) the surface heterogeneity of the adsorbing solid, (iii) the intensity of normal adsorbate–adsorbent bonds responsible for adsorption, (iv) the intensity of lateral bonds that favour the formation of surface aggregates through cooperative process and finally, (v) suitable theoretical models to describe adsorption phenomena. Once this has been achieved, two systems can be discussed: systems characterised by strong normal adsorbate–adsorbent bonds, currently used in ore flotation, which lead, in the case of heterogeneous surfaces, to the formation of lamellar aggregates at monolayer concentration and bilayer formation for higher concentrations. Systems characterised by weak normal adsorbate–adsorbent bonds, currently used in enhanced oil recovery and hydrocarbon (bio)remediation, which correspond to: (i) formation of globular micelles at the solid surface near the CMC when the temperature is higher than the Krafft point, (ii) formation of bilayered lamellar aggregates in the opposite case, (iii) three-dimensional condensation on substrate (T<T_Krafft) if the ionic surfactant interacts with cations in the bulk. To cite this article: J.-M. Cases et al., C. R. Geoscience 334 (2002) 675–688.  相似文献   

Effects of different crystal faces on the surface charge of colloidal goethite (α-FeOOH) particles: an experimental and modeling study     

Fabien Gaboriaud  Jean-Jacques Ehrhardt 《Geochimica et cosmochimica acta》2003,67(5):967-983

The surface charge of colloidal particles is usually determined by potentiometric titration. These acid-base titrations make it possible to measure the pH of point-of-zero charge (pzc) for oxide minerals. This macroscopic property is the most important parameter used in surface complexation modeling to reproduce experimental data. The pzc values of goethite reported in the literature vary between 7.0 and 9.5. Carbonate adsorption and/or surface morphology are thought to account for this wide range.We demonstrate a procedure for the removal of the carbonate ions that initially adsorb on goethite and strongly affect the titration curves and pzc determination. We also investigated the crystal-face-specific reactivity of two morphologically different goethites. The z-profiles obtained from atomic force microscopy (AFM) images showed that the goethite with the smallest specific surface area (S = 49 m²/g, denoted G49) exhibits 70% of the (001) face, whereas this value is only 30% for the goethite with largest specific surface area (S = 95 m²/g, denoted G95). This morphologic difference results in slightly different pzc values: 9.0 for G49 goethite and 9.1 for G95 geothite. These experimental pzc values have been correlated with multisite complexation calculations using both the full-site and the 1-pK approaches. We used the full-site approach to consider all of the configurations of hydrogen bond interactions with surface site. The resulting mean charges gave estimated pzc values of 8.9 and 9.2 for the (001) and (101) faces, respectively. Considering these theoretical pzc values for individual faces and the face distributions obtained from AFM analysis, the calculated pzc values are in full agreement with the experimental pzc values. However, this morphologic difference is more expressed in surface charge values than in the pzc values. Indeed, the surface charge of G49 goethite is much higher than that of G95 goethite, and the 1-pK calculations make it possible to fit the titration data satisfactorily.  相似文献   

A red algal bloom in the aftermath of the Marinoan Snowball Earth     

Marcel Elie  Afonso C.R. Nogueira  Anne Ndlec  Ricardo I.F. Trindade  Fabien Kenig 《地学学报》2007,19(5):303-308

Organic matter from the cap dolostones overlying the Marinoan‐age glacigenic diamictites of the Araras Group, Amazon craton, has been studied to reconstruct the post‐glacial ecosystem. Molecular fossils indicate that the post‐Marinoan ecosystem was marked by an apparent decline in marine algal diversity. The proliferation of red algae may be explained by environmental changes, such as a massive nutrient input accompanying continental weathering after the ice thaw and a dimer light penetrating sea water due to the drowning of the platform. In addition, the presence of green sulphur bacteria indicates that sea water was stratified with an anoxic (possibly euxinic, i.e. sulphidic) layer at the water–sediment interface. Sulphur cycling probably occurred at the redox boundary as suggested by the recognition of active sulphate reduction. This observation supports a microbially induced model for the formation of the cap dolostones.  相似文献   

Anhydrite–gypsum transition in the argillites of flooded salt workings in eastern France     

Elie Boidin  Françoise Homand  Fabien Thomas  Jacques Yvon 《Environmental Geology》2009,58(3):531-542

This study aims at understanding the physico-chemical interactions between the saturated brine and the rocks enclosing the underground salt workings in Lorraine (eastern France). These anhydrite-rich and argillaceous rocks were characterized in terms of mineralogy, micro-texture and connected porosity. Then, the two main lithofacies, massive anhydrite and anhydrite-rich argillite, were immersed in brine during more than 1 year. During this batch experiment, the argillites were affected by macroscopic splitting, contrarily to the massive anhydrite. Micro-texture and brine chemical analyses clearly show the swelling due to the hydration of anhydrite into gypsum inside the argillites, whereas hydration occurs superficially on the massive anhydrite, due to its very low permeability. Anhydrite–gypsum transformation is promoted by the presence of dissolved strontium and potassium in saturated brine. The low activity of water in saturated brine does not allow the clay fraction to swell significantly during the experiment. Thus, the expansion resulting from the hydration of anhydrite into gypsum might be responsible of the splitting of argillite in a saturated brine environment. The superficial anhydrite hydration on massive anhydrite can be explained by the low amount of connected porosity (less than 1%).  相似文献   

Numerical resolution of well-balanced shallow water equations with complex source terms   总被引：3，自引：0，他引：3  

Qiuhua Liang  Fabien Marche 《Advances in water resources》2009

This paper presents a well-balanced numerical scheme for simulating frictional shallow flows over complex domains involving wetting and drying. The proposed scheme solves, in a finite volume Godunov-type framework, a set of pre-balanced shallow water equations derived by considering pressure balancing. Non-negative reconstruction of Riemann states and compatible discretization of slope source term produce stable and well-balanced solutions to shallow flow hydrodynamics over complex topography. The friction source term is discretized using a splitting implicit scheme. Limiting value of the friction force is derived to ensure stability. This new numerical scheme is validated against four theoretical benchmark tests and then applied to reproduce a laboratory dam break over a domain with irregular bed profile.  相似文献   

Regional flow simulation in fractured aquifers using stress-dependent parameters   总被引：2，自引：0，他引：2  

Preisig G  Joel Cornaton F  Perrochet P 《Ground water》2012,50(3):376-385

A model function relating effective stress to fracture permeability is developed from Hooke's law, implemented in the tensorial form of Darcy's law, and used to evaluate discharge rates and pressure distributions at regional scales. The model takes into account elastic and statistical fracture parameters, and is able to simulate real stress-dependent permeabilities from laboratory to field studies. This modeling approach gains in phenomenology in comparison to the classical ones because the permeability tensors may vary in both strength and principal directions according to effective stresses. Moreover this method allows evaluation of the fracture porosity changes, which are then translated into consolidation of the medium.  相似文献   

10Be‐derived assessment of accelerated erosion in a glacially conditioned inner gorge,Entlebuch, Central Alps of Switzerland     

Fabien Van den Berg  Fritz Schlunegger  Naki Akçar  Peter Kubik 《地球表面变化过程与地形》2012,37(11):1176-1188

Inner gorges often result from the propagation of erosional waves related to glacial/interglacial climate shifts. However, only few studies have quantified the modern erosional response to this glacial conditioning. Here, we report in situ ¹⁰Be data from the 64 km² Entlen catchment (Swiss Alps). This basin hosts a 7 km long central inner gorge with two tributaries that are >100 m‐deeply incised into thick glacial till and bedrock. The ¹⁰Be concentrations measured at the downstream end of the gorge yield a catchment‐wide erosion rate of 0.42 ± 0.04 mm yr^‐1, while erosion rates are consistently lower upstream of the inner gorge, ranging from 0.14 ± 0.01 mm yr^‐1 to 0.23 ± 0.02 mm yr^‐1. However, ¹⁰Be‐based sediment budget calculations yield rates of ~1.3 mm yr^‐1 for the inner gorge of the trunk stream. Likewise, in the two incised tributary reaches, erosion rates are ~2.0 mm yr^‐1 and ~1.9 mm yr^‐1. Moreover, at the erosional front of the gorge, we measured bedrock incision rates ranging from ~2.5 mm yr^‐1 to ~3.8 mm yr^‐1. These rates, however, are too low to infer a post‐glacial age (15–20 ka) for the gorge initiation. This would require erosion rates that are between 2 and 6 times higher than present‐day estimates. However, the downcutting into unconsolidated glacial till favored high erosion rates through knickzone propagation immediately after the retreat of the LGM glaciers, and subsequent hillslope relaxation led to a progressive decrease in erosion rates. This hypothesis of a two‐ to sixfold decrease in erosion rates does not conflict with the ¹⁰Be‐based erosion rate budgets, because the modern erosional time scale recorded by ¹⁰Be cover the past 2–3 ka only. These results point to the acceleration of Holocene erosion in response to the glacial overprint of the landscape. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Interferometry basics in practice: Exercises     

Florentin Millour  Damien Sgransan  Jean-Philippe Berger  Gilles Duvert  Fabien Malbet 《New Astronomy Reviews》2008,52(2-5):208

The following exercises aim to learn the link between the object intensity distribution and the corresponding visibility curves of a long-baseline optical interferometer. They are also intended to show the additional constraints on observability that an interferometer has.This practical session is meant to be carried out with the ASPRO software, from the Jean-Marie Mariotti Center, but can also be done using other observation preparation software, such as viscalc from ESO.There are two main parts with series of exercises and the exercises corrections. The first one aims at understanding the visibility and its properties by practicing with simple examples, and the second one is about UV coverage.  相似文献