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101.
Abstract– Analyses by the Mars Exploration Rover (MER), Spirit, of Martian basalts from Gusev crater show that they are chemically very different from terrestrial basalts, being characterized in particular by high Mg‐ and Fe‐contents. To provide suitable analog basalts for the International Space Analogue Rockstore (ISAR), a collection of analog rocks and minerals for preparing in situ space missions, especially, the upcoming Mars mission MSL‐2011 and the future international Mars‐2018 mission, it is necessary to synthesize Martian basalts. The aim of this study was therefore to synthesize Martian basalt analogs to the Gusev crater basalts, based on the geochemical data from the MER rover Spirit. We present the results of two experiments, one producing a quench‐cooled basalt (<1 h) and one producing a more slowly cooled basalt (1 day). Pyroxene and olivine textures produced in the more slowly cooled basalt were surprisingly similar to spinifex textures in komatiites, a volcanic rock type very common on the early Earth. These kinds of ultramafic rocks and their associated alteration products may have important astrobiological implications when associated with aqueous environments. Such rocks could provide habitats for chemolithotrophic microorganisms, while the glass and phyllosilicate derivatives can fix organic compounds.  相似文献   
102.
Raman spectra were acquired on a series of natural and synthetic sulfide minerals, commonly found in enstatite meteorites: oldhamite (CaS), niningerite or keilite ((Mg,Fe)S), alabandite (MnS), troilite (FeS), and daubreelite (Cr2FeS4). Natural samples come from three enstatite chondrites, three aubrites, and one anomalous ungrouped enstatite meteorite. Synthetic samples range from pure endmembers (CaS, FeS, MgS) to complex solid solutions (Fe, Mg, Ca)S. The main Raman peaks are localized at 225, 285, 360, and 470 cm?1 for the Mg‐rich sulfides; at 185, 205, and 285 cm?1 for the Ca‐rich sulfides; at 250, 370, and 580 cm?1 for the Mn‐rich sulfides; at 255, 290, and 365 cm?1 for the Cr‐rich sulfides; and at 290 and 335 cm?1 for troilite with, occasionally, an extra peak at 240 cm?1. A peak at 160 cm?1 is present in all Raman spectra and cannot be used to discriminate between the different sulfide compositions. According to group theory, none of the cubic monosulfides oldhamite, niningerite, or alabandite should present first‐order Raman spectra because of their ideal rocksalt structure. The occurrence of broad Raman peaks is tentatively explained by local breaking of symmetry rules. Measurements compare well with the infrared frequencies calculated from first‐principles calculations. Raman spectra arise from activation of certain vibrational modes due to clustering in the solid solutions or to coupling with electronic transitions in semiconductor sulfides.  相似文献   
103.
Landslide risk perception: a case study in Southern Italy   总被引:2,自引:0,他引:2  
Perceptions of risk are a key issue when seeking to develop systems, practices and policies to protect local populations. This is particularly evident when risk mitigation strategies involve non-structural measures such as relocation and warning systems which presuppose the active involvement of the communities in question. This study adopts an interdisciplinary approach to studying the perceptions, knowledge and opinions on landslide risk amongst residents in Sarno, a small town in Southern Italy which was hit by disastrous landslides on 5–6 May 1998. The paper presents the results of a survey conducted in the months of March, April and May 2013 using a purpose-designed questionnaire. The survey was conducted using face-to-face interviews with 100 residents, 60 of whom live inside the so-called “red zone”, a territory declared at high residual risk soon after the events of 1998. The questionnaire included questions relating to perceived risk exposure, trust in institutions responsible for risk management, evaluations of risk mitigation measures and the early-warning strategy. The results of the study clearly emerges, amongst other issues, that the organisms which are responsible for risk management in Sarno need to develop more effective communication strategies in order to transmit knowledge about the actions implemented to reduce landslide risk in the area.  相似文献   
104.
The fifth version of natural river water certified reference material, SLRS‐5 (National Research Council – Conseil National de Recherches Canada), is commonly used to control the quality of major and trace element measurements. Concentrations of silicon and thirty‐one uncertified trace elements have been reported for the certified reference material SLRS‐4, but they are not yet available for SLRS‐5. Here, SLRS‐5/SLRS‐4 ratios were deduced from SLRS‐5 and SLRS‐4 measurements by inductively coupled plasma‐atomic emission spectrometry and high‐resolution inductively coupled plasma‐mass spectrometry for certified elements and thirty‐five uncertified elements (rare earth elements, B, Bi, Br, Cs, Ga, Ge, Hf, Li, Nb, P, Pd, Rb, Rh, S, Sc, Si, Sn, Th, Ti, Tl, Y). Both reference materials were measured directly one after the other, so that calculated elemental ratios would not be notably influenced either by calibration uncertainties or by eventual long‐term instrumental drift. The computed ratios are in good agreement with those deduced from the certified values. We also report concentrations for thirty‐three uncertified elements in SLRS‐5 by combining the measured SLRS‐5/SLRS‐4 ratios and the published SLRS‐4 values. The resulting new data set provides target SLRS‐5 values, which will be useful in quality control procedures.  相似文献   
105.
Zn and Cd concentrations, stable lead isotopes and 210Pb-derived chronology were determined in a sediment core sampled at Sepetiba Bay (South-eastern Brazil). During the last decades, the bay’s watershed has been modified by the increase of industrial activities and human interventions. In particular, Zn and Cd ore treatment plants were built near the coast in 1960 and 1970, respectively, and water has been diverted from the adjacent Paraíba do Sul River watershed since 1950. The core collected at shallow depth near the industrial area exhibits four successive events: (i) at 50 cm depth, a change in the 206Pb/207Pb ratio from about 1.162 to more than 1.18 might be the result of the São Francisco Channel opening and water diversion from Paraíba do Sul river; (ii) at 40 cm depth, Zn concentration starts to increase (up to 0.8 mg g−1) (iii) above 30 cm depth, relatively high Cd concentrations (up to 1.6 μg g−1) are observed and (iv) at 16 cm depth, change in unsupported 210Pb slope is probably related to a waste dam built to prevent strong metal contamination in the bay. Sediment accumulation rates evaluated by Zn and Cd profiles used as time-markers are higher than those calculated from 210Pb-based chronology models. Using the constant initial concentration (CIC) model both events are supposed to date back to about 1884 and 1902, respectively, while using the constant rate of supply (CRS) model it shifts to about 1925 and 1935. Such discrepancies are probably assigned to the fact that these models do not take into account site-specific local sedimentation dynamics. In the study area, particles deposition seems to be controlled by enrichment with unsupported 210Pb transported by runoff from a mangrove flat bank. Chronology derived from a model that assumes an exponential increase of the initial 210Pb activity fits well with the estimated rates obtained from historical events.  相似文献   
106.
Although phytoliths, constituted mainly by micrometric opal, exhibit an important control on silicon cycle in superficial continental environments, their thermodynamic properties and reactivity in aqueous solution are still poorly known. In this work, we determined the solubility and dissolution rates of bamboo phytoliths collected in the Réunion Island and characterized their surface properties via electrophoretic measurements and potentiometric titrations in a wide range of pH. The solubility product of “soil” phytoliths ( at 25 °C) is equal to that of vitreous silica and is 17 times higher than that of quartz. Similarly, the enthalpy of phytoliths dissolution reaction is close to that of amorphous silica but is significantly lower than the enthalpy of quartz dissolution. Electrophoretic measurements yield isoelectric point pHIEP = 1.2 ± 0.1 and 2.5 ± 0.2 for “soil” (native) and “heated” (450 °C heating to remove organic matter) phytoliths, respectively. Surface acid-base titrations allowed generation of a 2-pK surface complexation model. Phytoliths dissolution rates, measured in mixed-flow reactors at far from equilibrium conditions at 2 ? pH ? 12, were found to be intermediate between those of quartz and vitreous silica. The dissolution rate dependence on pH was modeled within the concept of surface coordination theory using the equation:
  相似文献   
107.
The Andean foreland basin overlaps the Cretaceous-Paleogene Salta rift basin in northwestern Argentina. Knowledge of the relationship between rift and foreland basins is key to understanding the initial stages of foreland basin development related to Andean shortening. We present a new stratigraphic scheme for the Luracatao Valley, revealing that the Quebrada de los Colorados Formation (Payogastilla Group) lies over the Santa Bárbara Subgroup (Salta Group) through an erosional unconformity that turns into an angular unconformity close to folds and faults recorded in the Santa Bárbara Subgroup. The base of the Quebrada de los Colorados Formation shows growth strata along the west frontal limb of an anticline with Santa Bárbara units in its core. The finding of a mammalian fossil at the base of the Quebrada de los Colorados Formation allows us to assign a Middle-Upper Eocene age to the sedimentation; therefore, the time elapsed between the deposition of the final postrift strata and the beginning of Andean sedimentation was brief and constrained to the Lower-Middle Eocene. This data indicates that the Eocene deformation phase described in other portions of the Puna-Cordillera Oriental transition (e.g., the northern Calchaquí Valley and Aguilar range) is also present in the Luracatao Valley, offering new tools for interpreting the ages and distributions of the initial episodes of sedimentation and deformation related to the Andean shortening. Thus, the Luracatao Valley provides new evidence for tracking the distribution of the Paleogene deformation in northwestern Argentina.  相似文献   
108.
Multi-imaging and Bayesian estimation for photon counting with EMCCDs   总被引:1,自引:0,他引:1  
A multi-imaging strategy is proposed and experimentally tested to improve the accuracy of photon counting with an electron multiplying CCD (EMCCD), by taking into account the random nature of its on-chip gain and the possibility of multiple photodetection events on one pixel. This strategy is based on Bayesian estimation on each image, with a priori information given by the sum of the images. The method works even for images with large dynamic range, with more improvement in the low light level areas. In these areas, two thirds of the variance added by the EMCCD in a conventional imaging mode are removed, making the physical photon noise predominant in the detected image.  相似文献   
109.
Continental ‘overfilled’ conditions during rift initiation are conventionally explained as due to low creation of accommodation compared with sediment supply. Alternatively, sediment supply can be relatively high from the onset of rifting due to an antecedent drainage system. The alluvial Lower Group of the western Plio–Pleistocene Corinth rift is used to investigate the interaction of fluvial sedimentation with early rifting. This rift was obliquely superimposed on the Hellenide mountain belt from which it inherited a significant palaeorelief. Detailed sedimentary logging and mapping of the well‐exposed syn‐rift succession document the facies distributions, palaeocurrents and stratigraphic architecture. Magnetostratigraphy and biostratigraphy are used to date and correlate the alluvial succession across and between fault blocks. From 3·2 to 1·8 Ma, a transverse low sinuosity braided river system flowed north/north‐east to east across east–west‐striking active fault blocks (4 to 7 km in width). Deposits evolved downstream from coarse alluvial conglomerates to fine‐grained lacustrine deposits over 15 to 30 km. The length scale of facies belts is much greater than, and thus not directly controlled by, the width of the fault blocks. At its termination, the distributive river system built small, stacked deltas into a shallow lake margin. The presence of a major antecedent drainage system is supported by: (i) a single major sediment entry point; (ii) persistence of a main channel belt axis; (iii) downstream fining at the scale of the rift basin. The zones of maximum subsidence on individual faults are aligned with the persistent fluvial axis, suggesting that sediment supply influenced normal fault growth. Instead of low accommodation rate during the early rift phase, this study proposes that facies progradation can be controlled by continuous and high sediment supply from antecedent rivers.  相似文献   
110.
In 1963, E. Saurin and J.‐P. Carbonnel discovered the Sre Sbov site on an alluvial terrace of the Mekong River in central Cambodia. Saurin described a lithic typology dating to the Lower/Middle Pleistocene from this site. Although the original lithic assemblage has been lost, this typology has been used continuously as a reference by Southeast Asian prehistorians. In 2007, a Khmer–French team conducted excavations at Sre Sbov that yielded numerous pebbles and cobbles showing apparently convincing handmade removals, as Saurin had previously described. However, an in‐depth study of this assemblage, combined with a geological survey of the area, led to the conclusion that the stones were, in fact, of natural origin, and that for this reason their typology should be disregarded. Using satellite imagery and geological surveys, we explain how such a misinterpretation may have occurred and define a “buffer zone,” corresponding to the maximal extent of the proto‐Mekong River, where fluvially reworked pebbles and cobbles resembling artifacts may be recovered. © 2009 Wiley Periodicals, Inc.  相似文献   
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