Two-dimensional pH distributions and dynamics in bioturbated marine sediments   总被引：2，自引：0，他引：2  

Qingzhi Zhu  Yanzhen Fan 《Geochimica et cosmochimica acta》2006,70(19):4933-4949

The seafloor is the site of intense biogeochemical and mineral dissolution-precipitation reactions which generate strong gradients in pH near the sediment-overlying water interface. These gradients are usually measured in one-dimension vertically with depth. Two-dimensional pH distributions in marine sediments were examined at high resolution (65 × 65 μm pixel) and analytical precision over areas of ∼150 to 225 cm² using a newly developed pH planar fluorosensor. Dramatic three-dimensional gradients, complex heterogeneity, and dynamic changes of pH occur in the surficial zone of deposits inhabited by macrofauna. pH can vary by ±2 units horizontally as well as vertically over millimeter scales. pH minima zones often form in association with redoxclines within a few millimeters of inner burrow walls, and become more pronounced with time if burrows remain stable and irrigated for extended periods. Microenvironmental pH minima also form locally around decaying biomass and relict burrow tracks, and dissipate with time (∼5 d). H⁺ concentrations and fluxes in sandy mud show complex acid-base reaction distributions with net H⁺ fluxes around burrows up to ∼12 nmol cm⁻² d⁻¹ and maximum net reaction rates varying between −90 (consumption) to 120 (production) μM d⁻¹ (∼90 nmol cm⁻¹ d⁻¹ burrow length). Acid producing zones that surround irrigated burrows are largely balanced by acid titration zones along inner burrow walls and outer radial boundaries. The geometry and scaling of pH microenvironments are functions of diagenetic reaction rates and three-dimensional transport patterns determined by sediment properties, such as diffusive tortuosity, and by benthic community characteristics such as the abundance, mobility, and size of infauna. Previously, undocumented biogeochemical phenomena such as low pH regions associated with in-filled relict biogenic structures and burrowing tracks are readily demonstrated by two-dimensional and time-dependent images of pH and sedimentary structure.  相似文献   

Fluid unmixing/immiscibility as an ore-forming process in the giant REE–Nb–Fe deposit, Inner Mongolian, China: Evidence from fluid inclusions     

Hong-Rui Fan  Fang-Fang Hu  Kui-Feng Yang  Kai-Yi Wang 《Journal of Geochemical Exploration》2006,89(1-3):104

The giant Bayan Obo REE–Nb–Fe deposit consists of replacement bodies hosted in dolomite marble made up of magnetite, REE fluorocarbonates, fluorite, aegirine, amphibole, calcite and barite. Two or three phase CO₂-rich, three phase hypersaline liquid–vapor–solid, and two phase liquid-rich inclusions have been recognized in mineralized fluorite and quartz samples. Microthermometry measurements indicate that the carbonic phase in CO₂-rich inclusions is nearly pure CO₂. Fluids involving in REE–Nb–Fe mineralization at Bayan Obo might be mainly of H₂O–CO₂–NaCl–(F–REE) system. Coexistences of brine inclusions and CO₂-rich inclusions with similar homogenization temperatures give evidence that immiscibility happened during REE mineralization. An unmixing of an original H₂O–CO₂–NaCl fluid probably derived from carbonatitic magma. The presence of REE-carbonates as an abundant solid in fluid inclusions shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo.  相似文献   

珠江三角洲城市旅游竞争力空间结构体系初探   总被引：37，自引：4，他引：37  

黄耀丽  李凡  郑坚强  李飞 《地理研究》2006,25(4):730-740

区域城市间旅游竞争力空间结构体系是一个由不同等级、不同空间区位、不同旅游发展阶段的城市通过旅游资源、旅游交通等生产力要素以及客流有机耦合而形成的。本文在深入分析旅游竞争力含义及其空间结构的基础上,采用城市旅游竞争力的多维评价和综合分析的方法,将珠江三角洲城市旅游目的地划分为不同的3个等级,并总结出珠江三角洲城市旅游竞争力具有以广深为轴线的“哑铃”型双极放射状空间形态模式,提出了凭借城市自身比较优势,承担不同层次旅游竞争与合作角色的空间组织模式,旨在通过研究梳理各城市旅游影响要素的优劣差异,认识区域内旅游竞争力的空间结构特征,为进一步探讨形成互利共赢的城市旅游竞争与合作机制奠定基础,促进珠江三角洲城市旅游经济的和谐发展。  相似文献   

辽东栎萌生个体的地上生物量及其构件分配与生长参数的关系   总被引：1，自引：0，他引：1  

孟令彬  包维楷  张咏梅  庞学勇  孙凡 《山地学报》2006,24(2):202-208

选择岷江上游海拔2100-2300m地段的辽东栎萌生株个体69株，测定了每株生长参数（年龄、高度、基径、冠幅）、各器官生物量及地上总生物量，分析了各器官生物量及构件分配与生长参数的相互关系。结果表明，辽东栎萌生株构件分配的大小排序为：茎干〉枝〉皮〉叶：随径级增大。茎干、大枝生物量所占总生物量比例上升，其他器官所占比例减小。辽东栎年龄与高度呈S曲线关系，其他均表现出很好的幂指数函数关系；各构件器官生物量与生长参数大多也呈幂指数函数W=aD^h（D为基径）关系。基径为估测辽东栎萌生株地上各器官生物量及总生物量的最佳因子。  相似文献   

辽东湾北部地区走滑构造特征与油气富集规律   总被引：2，自引：2，他引：2  

范军侠  李宏伟  朱筱敏  田世澄 《古地理学报》2006,8(3):415-418

辽东湾北部地区右行走滑构造特征较为典型,主要表现为:沿走滑断裂带发育雁行式伸展断裂;剖面上发育花状构造;走滑断裂沿走向呈“S”型或反“S”型波状弯曲;沿走滑断裂带断槽与断鼻构造相间分布。分析认为,渐新世晚期,辽东湾北部地区南北向拉张、东西向挤压的区域应力场控制了右行走滑构造的形成,断槽与断鼻构造相间分布是由于沿走滑断裂带局部应力场性质发生改变所致。右行走滑断裂的“S”型弯曲部位为增压弯部位,走滑断裂两侧断块在此汇聚,地层因应力集中而形成断鼻构造;右行走滑断裂的反“S”型弯曲部位为释拉张部位,走滑断裂两侧断块在此离散,地层因拉张而发生断陷形成断槽。受走滑构造所控制,油气沿走滑断层自断槽向断鼻方向运移、聚集而成藏。研究走滑构造发育特征,对于预测圈闭分布以和研究油气富集规律具有重要意义。  相似文献   

邢台矿区山字型构造的发现及其地质意义   总被引：1，自引：0，他引：1  

张纪勋  范志平 《中国煤田地质》2006,18(4):18-21

邢台山字型构造位于河北省邯邢煤田内，其前弧向ES突出，脊柱呈ES-WN走向。分别分析了山字型构造脊柱及其东、西翼反射弧构造形迹特征，对研究区找矿具有重要意义。  相似文献   

淮北煤田孙庄勘探区煤层气赋存规律及影响因素分析     

樊爱英 《中国煤田地质》2006,18(5):25-27

通过对淮北煤田孙庄勘探区地质构造、沉积特征、煤层煤质及煤层气赋存特征的分析，研究认为有利于本区煤层气赋存的主要因素是较大的埋藏深度、较高的壳质组＋镜质组、较高的变质程度、较大的煤层厚度、低透气性的盖层、较缓的地层倾角和封闭性较好的构造条件，推测煤田深部可能具有一定工业价值的煤层气资源。  相似文献   

Oxidation of AsⅢ by Several Manganese Oxide Minerals in Absence and Presence of Goethite     

FENG Xionghan  TAN Wenfeng  LIU Fan  Huada Daniel RUAN  HE Jizheng 《《地质学报》英文版》2006,(2)

  相似文献   

广西东攀剖面二叠-三叠系界线附近头足类动物群与地质时代讨论     

卜建军  吴顺宝  张宏亮  蒙有言  张凡  张立原 《地质科技情报》2006,25(4)

在广西东攀二叠-三叠系界线剖面中发现了Domataceras guangxiensis, Lopingoceras guangdeensis Zhao,Liang et Zheng,Schizoloboceras fusuiensis, Agathiceras sp., Stacheoceras sp.,Pernodoceras robustum Chao et Liang,Dushanoceras cf.rotolarium Zhao, Liang et Zheng,Huananoceras cf.perornatum Chao et Liang,Qianjiangoceras sp.,Laibinoceras cf.compressum Yang,Glyptophiceras sp.,Lytophiceras cf. chamunda(Diener),Ophiceras tingi Tien,Ophiceras sp.化石.在剖面的第2～12-2层产Pernodoceras,Dushanoceras,Huananoceras和Qianjiangoceras化石,均为长兴期菊石带Pseudotirolites-Rotodiscoceras的共生化石.第12-3层产长兴期菊石Laibinoceras cf.compressum Yang.第13-1A～16层产Lytophiceras和 Ophiceras,为早三叠世菊石带Ophiceras-Lytophiceras的带化石.东攀剖面菊石的分布及其与华南其他地区的对比研究表明,广西东攀剖面二叠-三叠系界线位于第12-3层(厚55 cm)内部或者位于第13-1A层的底部.  相似文献   

氢化物发生-原子荧光光谱法测定地球化学样品中痕量碲   总被引：4，自引：4，他引：4  

范凡 《岩矿测试》2005,24(3):225-228

采用焙烧富集分离地球化学样品中痕量Te,并用氢化物发生原子荧光光谱法测定。通过实验确定出方法的最佳实验条件,在此条件下获得的检出限为0.005μg/g,线性范围0.025~10μg/g,精密度(RSD,n=8)为5.03%~9.24%。方法已用于国家一级地球化学标准物质中痕量Te的测定,结果与标准值基本相符。  相似文献