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201.
202.
含钒金红石可见光下催化降解亚甲基蓝实验研究 总被引:2,自引:0,他引:2
利用含有钒等杂质的金红石可部分吸收可见光的特性,以500 W卤素灯作为光源,实验研究了其对亚甲基蓝的可见光催化降解,结果表明,该金红石具有催化活性,7 h后亚甲基蓝可降解71 2%。经过加热、粉碎改性方法处理后的金红石光催化活性明显提高,加热1 100 ℃的金红石样品7 h后可使亚甲基蓝的降解率达到90 4%。增加光照强度、加入适当的H2O2 都可提高降解效果。实验为充分开发利用天然金红石提出了新的途径,为环境污染治理提出了新方法。 相似文献
203.
通过对桩侧和桩底后压浆,可大幅度提高钻孔灌注桩单桩承载力.应用桩-土理论分析了后压浆中浆液对土体及桩体的作用,并从分析影响桩基承载力的因素出发,研究了后压浆的作用机理.在渗透率小的地层中后压浆以压密注浆为主,在渗透率大的地层中后压浆以渗透注浆为主.为避免过分压裂土层,在压浆过程中应控制灌浆压力.压浆量是影响后压浆质量和提高单桩承载力的关键因素之一. 相似文献
204.
金龙山——丘岭金矿区含金矿源为层上泥盆统南羊山组和下石炭统袁家沟组。组成含金矿源层岩石为高频互层的细碎屑岩-碳酸盐岩,其中细砂岩、粉砂岩、碳酸盐岩含成矿流体物性较好.页岩、板岩含成矿流体物性较差,构成屏蔽层。金鸡岭Ⅰ级复式向斜控制着金、砷、锑等异常范围;松枣Ⅱ级复式背斜控制着金的矿化带;金龙山-丘岭金矿Ⅲ级背斜控制着金的矿(化)体;镇安——板岩镇断裂的次级断裂是金矿化体的容矿有利位置。在成矿过程中,构造变形与成矿流体的形成、运移及储集密切相关。其规律是:①原生构造导致成矿流体的初次聚集。②第一期构造变形导致成矿流体的聚集。③第二期构造变形导致成矿流体运移及金矿床形成。此期变形是金的主要成矿期。④第三期构造变形使成矿流体进一步聚集和金矿体的富集。⑤第四期构造变形是石英方解石脉的形成时期。总结出矿床形成模式。据此提出了在4种不同的构造部位找金的方向。 相似文献
205.
本文通过对渭北东部岩溶地下水环境同位素组成特征的研究,分析了大气降水、地表水、地下水三者之间的转化关系,并对研究区岩溶地下水的形成进行了初步探讨,认为大气降水是研究区岩溶地下水的补给源,地表水与地下水之间存在水力联系,地表水对地下水的补给占补给水源的74.3%。西部岩溶裸露区为岩溶水的直接补给区,其周边浅埋区为岩溶水的间接补给区,东南部的岩溶中-深埋区为岩溶水的径流排泄区。 相似文献
206.
文章从国内外滑坡灾害、滑坡灾害的危害及现有滑坡监测方法等方面,论述了滑坡灾害带来的危害性,从而验证了滑坡监测的重要性。但目前现行的滑坡监测手段各有不足之处。针对这种情况,提出了新的测量方法改进其不足之处。位相测量剖面术的测量原理是将LCD投影仪安装于滑坡体上,在滑坡体外稳定地带放置监测系统,CCD光束中心垂直于滑坡体位移方向,监测系统由望远镜头和CCD组成,CCD输出的视频信号进入计算机。通过软件对图像进行处理,绘制出滑坡整体的三维面貌,并计算出滑动的距离,从而有效的观测滑坡体的运动过程。 相似文献
207.
Analysis of the environmental sensitivities of a typical dynamic epikarst system at the Nongla monitoring site, Guangxi, China 总被引:6,自引:0,他引:6
Nongla, a typical karst dynamic system (KDS) monitoring site, is located at Nongla Village, Mashan County, Guangxi, China. The data from a Greenspan CTDP300 multichannel data logger indicates that the KDS is highly sensitive to environmental changes. Multi-day and diurnal physico-chemical composition of epikarst spring water is quite different under different climatic conditions. During a day with no rainfall, water temperature and air temperature have similar variations. Electrical conductivity (EC) has good positive correlation with pH value and water temperature. During rainstorms, the physico-chemical composition of the spring water is initially strongly effected by dilution, pH and EC drop rapidly. However, half to one hour later, EC returns to normal and the CO2 effects will be the dominant physical effect. This is due to the high fissure rates and high permeability in the epikarst zone. Dilution effects were observed during the entire rainstorm event,whereas, it only acts during the earliest period of light rain. Therefore, it is necessary to examine the water–rock–CO2 combination as a whole system to explain the hydrochemical behavior of epikarst processes. 相似文献
208.
M. Koch-Müller P. Dera Y. Fei H. Hellwig Z. Liu J. Van Orman R. Wirth 《Physics and Chemistry of Minerals》2005,32(5-6):349-361
We synthesized superhydrous phase B (shy-B) at 22 GPa and two different temperatures: 1200°C (LT) and 1400°C (HT) using a
multi-anvil apparatus. The samples were investigated by transmission electron microscopy (TEM), single crystal X-ray diffraction,
Raman and IR spectroscopy. The IR spectra were collected on polycrystalline thin-films and single crystals using synchrotron
radiation, as well as a conventional IR source at ambient conditions and in situ at various pressures (up to 15 GPa) and temperatures
(down to −180°C). Our studies show that shy-B exists in two polymorphic forms. As expected from crystal chemistry, the LT
polymorph crystallizes in a lower symmetry space group (Pnn2), whereas the HT polymorph assumes a higher symmetry space group (Pnnm). TEM shows that both modifications consist of nearly perfect crystals with almost no lattice defects or inclusions of additional
phases. IR spectra taken on polycrystalline thin films exhibit just one symmetric OH band and 29 lattice modes for the HT
polymorph in contrast to two intense but asymmetric OH stretching bands and at least 48 lattice modes for the LT sample. The
IR spectra differ not only in the number of bands, but also in the response of the bands to changes in pressure. The pressure
derivatives for the IR bands are higher for the HT polymorph indicating that the high symmetry form is more compressible than
the low symmetry form. Polarized, low-temperature single-crystal IR spectra indicate that in the LT-polymorph extensive ordering
occurs not only at the Mg sites but also at the hydrogen sites. 相似文献
209.
Shantanu Keshav Alexandre Corgne Michael Bizimis Yingwei Fei 《Geochimica et cosmochimica acta》2005,69(11):2829-2845
In this experimental study, we examine the mineral-melt partitioning of major and trace elements between clinopyroxene and CO2-rich kimberlitic melts at a pressure of 6 GPa and temperatures of 1410°C and 1430°C. The melts produced contain ∼ 28 wt% dissolved CO2, and are saturated with olivine and clinopyroxene. To assess the effects of temperature, crystal and melt compositions on trace element partitioning, experiments were performed in the model CaO-MgO-Al2O3-SiO2-CO2 system. Our results reveal that all the elements studied, except Al, Mg, Si, and Ga, are incompatible in clinopyroxene. Partition coefficients show a considerable range in magnitude, from ∼ 10−3 for DU and DBa to ∼ 2.5 for DSi. The two experimental runs show similar overall partitioning patterns with the D values being lower at 1430°C. Rare earth elements display a wide range of partition coefficients, DLa (0.012-0.026) being approximately one order of magnitude lower than DLu (0.18-0.23). Partition coefficients for the 2+ and 3+ cations entering the M2-site exhibit a near-parabolic dependence on radius of the incorporated cations as predicted from the lattice strain model. This underlines the contribution made by the crystal structure toward controlling the distribution of trace elements. Using data obtained in this study combined with that in the published literature, we also discuss the effects that other important parameters, namely, melt composition, pressure, and temperature, could have on partitioning.Our partition coefficients have been used to model the generation of the Group I (GI) kimberlites from South Africa. The numerical modeling shows that kimberlitic melts can be produced by ∼0.5% melting of a MORB-type depleted source that has been enriched by small-degree melts originating from a similar depleted source. This result suggests that the source of GI kimberlites may be located at the lithosphere-asthenosphere transition. Percolation of small degree melts from the asthenosphere would essentially create a metasomatic horizon near the bottom of the non-convecting sublithospheric mantle. Accumulation of such small degree melts together with the presence of volatiles and conductive heating would trigger melting of the ambient mantle and subsequently lead to eruption of kimberlitic melts. Additionally, our model shows that the GI source can be generated by metasomatism of a 2 Ga old MORB source ca. 1 Ga ago. Assuming that MORB-type mantle is the most depleted source of magmas on earth, then this is the oldest age at which the GI source could have existed. However, this age most likely reflects the average age of a series of metasomatic events than that of a single event. 相似文献
210.
不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。 相似文献