Thermal expansion and spontaneous strain associated with the normal-incommensurate phase transition in melilites     

S. L. Webb  C. R. Ross II  J. Liebertz 《Physics and Chemistry of Minerals》1992,18(8):522-525

The linear thermal expansions of åkermanite (Ca₂MgSi₂O₇) and hardystonite (Ca₂ZnSi₂O₇) have been measured across the normal-incommensurate phase transition for both materials. Least-squares fitting of the high temperature (normal phase) data yields expressions linear in T for the coefficients of instantaneous linear thermal expansion, $$\alpha _1 = \frac{1}{l}\frac{{dl}}{{dT}}$$ for åkermanite: $$\begin{gathered} \alpha _{[100]} = 6.901(2) \times 10^{ - 6} + 1.834(2) \times 10^{ - 8} T \hfill \\ \alpha _{[100]} = - 2.856(1) \times 10^{ - 6} + 11.280(1) \times 10^{ - 8} T \hfill \\ \end{gathered} $$ for hardystonite: $$\begin{gathered} \alpha _{[100]} = 15.562(5) \times 10^{ - 6} - 1.478(3) \times 10^{ - 8} T \hfill \\ \alpha _{[100]} = - 11.115(5) \times 10^{ - 6} + 11.326(3) \times 10^{ - 8} T \hfill \\ \end{gathered} $$ Although there is considerable strain for temperatures within 10° C of the phase transition, suggestive of a high-order phase transition, there appears to be a finite ΔV of transition, and the phase transition is classed as “weakly first order”.  相似文献   

Computation of surface energies in an electrostatic point charge model: I. Theory     

C. F. Woensdregt 《Physics and Chemistry of Minerals》1992,19(1):52-58

The attachment energies, the slice energies and the specific surface energies can be calculated in an electrostatic point charge model using the formula derived by Madelung for the potential introduced by an infinite row of equally spaced point charges. Power series are given for the Hankel function iH ₍₀₎ ⁽¹⁾ (iy) and Ψ(x)=d ln x!/dx. The logarithmic expression in the Madelung formula converges rapidly when applying a power series, which combines equally charged cations and anions. Besides the specific surface energy (γ ^hkl), the slice energy (E _s ^hkl ) and the attachment energy (E _a ^hkl ) can be considered as special categories of surface energies as they depend on surface configurations as well. The specific surface energy γ is the energy per unit area of surface needed to split the crystal parallel to a face (hkl). The attachment energy (E _a) is the energy released per mole, when a new slice of thickness d _hkl crystallizes on an already existing crystal face (hkl). The growth rate of the crystal face (hkl) is a function of its attachment energy. The slice energy (E _s) is the energy released per mole, when a new slice d _hkl is formed from the vapour neglecting the influence of edge energies. The lattice energy (E _c) which is the energy released per mole of a crystal crystallizing from the vapour, is given by the following relation: E _c=E _a+E _s.  相似文献   

Structure of the αFexAl1:xOOH solid solution     

J. L. Hazemann  A. Manceau  Ph. Sainctavit  C. Malgrange 《Physics and Chemistry of Minerals》1992,19(1):25-38

The three-dimensional local organisation around Fe atoms in a natural diaspore (Al_0.9955Fe_0.0045OOH) has been investigated by angular measurements of X-ray absorption spectra. It is demonstrated that in a single crystal of diaspore, the absorption cross-section exhibits the special case of trichroism where three independent measurements are needed to determine the absorption cross-section for any direction of polarization. Extended X-ray absorption fine structure (EXAFS) spectra were thus recorded at the following orientations of the polarization vector: , , and . The incoming white beam was monochromatized using two Si(331) crystals, which deliver at the Fe K-edge a completely linearly polarized X-ray beam. The reliability of our measurements was checked by comparing the isotropic EXAFS spectrum calculated from the three orthogonal measurements to the one of the diaspore powder recorded at the magic angle. It is shown that Fe³⁺ ions are not randomly distributed within the diaspore framework. Furthermore, only part of the Fe³⁺ ions substitutes Al, the others being located in the channels of the structure. The 3D local structure of the Fe domains has been modeled assuming hematite-like clusters of three Fe octahedra topotactically grafted to aluminous chains. These Fe clusters are thought to represent ancient multinuclear Fe surface complexes having formed at the time of the diaspore growth, and being sealed in its bulk structure. The whole crystal of diaspore is then thought to have kept the memory of the heterogeneous nucleation mechanism of these hematite nuclei. In addition to the well-known examples of atom segregations, ion vacancies, and intergrowths of discrete phases, this new type of crystal defect represents another evidence of non-equilibrium crystallization process under the thermodynamic and kinetic conditions that prevail at the earth's surface.  相似文献   

Computation of surface energies in an electrostatic point charge model: II. Application to zircon (ZrSiO4)     

C. F. Woensdregt 《Physics and Chemistry of Minerals》1992,19(1):59-69

The attachment energies, the slice energies and the specific surface energies can be calculated in an electrostatic point charge model using the formula derived by Madelung for the potential introduced by an infinite row of equally spaced point charges. Power series are given for the Hankel function iH ₍₀₎ ⁽¹⁾ (iy) and (x)=d ln x!/dx. The logarithmic expression in the Madelung formula converges rapidly when applying a power series, which combines equally charged cations and anions. Besides the specific surface energy ( ^hkl), the slice energy (E _s ^hkl ) and the attachment energy (E _a ^hkl ) can be considered as special categories of surface energies as they depend on surface configurations as well. The specific surface energy is the energy per unit area of surface needed to split the crystal parallel to a face (hkl). The attachment energy (E _a) is the energy released per mole, when a new slice of thickness d _hkl crystallizes on an already existing crystal face (hkl). The growth rate of the crystal face (hkl) is a function of its attachment energy. The slice energy (E _s) is the energy released per mole, when a new slice d _hkl is formed from the vapour neglecting the influence of edge energies. The lattice energy (E _c) which is the energy released per mole of a crystal crystallizing from the vapour, is given by the following relation: E _c=E _a+E _s.  相似文献   

Synthesis and stability of bastnaesites in a part of the system (Ce,La)-F-H-C-O     

Dr. L. C. Hsu 《Mineralogy and Petrology》1992,47(1):87-101

Summary Bastnaesites of Ce and La and their OH-analogs were synthesized and their stability relations were determined atPf = 1 kbar andT = 400 to 900°C in a part of the system (Ce,La)-F-H-C-0. The initial fluid compositions were such that and HF/(HF + H₂O) ratios were 0 to 0.172. XRD and IR studies indicate that bastnaesites equilibrated in initial fluids low in HF are all F-enriched. The hydroxylbastnaesite-(La) is stable up to 810°C and the fluorbastnaesite-(La) is stable up to 860°C. Their condensed breakdown products are La₂O₂CO₃ and LaOF, respectively. The stability of Ce bastnaesites is slightly dependent. The hydroxylbastnaesite-(Ce) is stable up to 660°C at the defined by the IQF buffer and up to 640°C by the MH buffer. The fluorbastnaesite-(Ce) is stable up to 800°C at the defined by the IQF and up to 760°C by the MH buffer. The condensed breakdown product for the hydroxyl end-member is simply CeO₂ but for the fluorine one is a combination of CeO₂, CeF₃, and CeOF. Factors, such as OH vs F, , and bulk composition, that affect the stability of individual species are discussed. Petrogenic implications resulting from the present study include that bastnaesites can be stable from hydrothermal to magmatic conditions, that F-enriched species can form in an environment relatively low in F content, and that OH-species are rare and occur only in low-temperature environments essentially devoid of F.

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Synthese und Stabilität von Bastndsil in einem Teil des Systems (Ce,La)-F-H-C-O

Zusammenfassung Ce- und La-Bastnäsite, sowie deren OH-Analoga wurden synthetisiert und ihre Stabilitätsbeziehunger beiP _f = 1 kbar undT = 400 bis 900°C wurden im System (Ce,La)F-H-C-O bestimmt. Die anfänglichen Flüssigkeitszusammensetzungen waren so, daß und die HF/(HF + H₂O)-Verhältnisse 0–0.172 waren. Röntgenpulver- und Ultrarot-Untersuchungen zeigten, daß Bastnäsite, die mit anfänglich HF-armen Flüssigkeiten equilibriert wurden, alle an F angereichert sind. Hydroxilbastndsit-(La) ist bis 810°C und Fluorbastnäsit-(La) bis 860°C stabil. Ihre festen Zersetzungsprodukte sind La₂O₂O₃, bzw. LaOF. Die Stabilität der Ce-Bastnäsite hängt etwas von ab. Hydroxilbastnäsit-(Ce) ist bei des Eisen-Quarz-Fayalit-Puffers bis 660°C stabil und mit Magnetit-Hämatit-Puffer bis 640°C. Das feste Zerfallsprodukt ist für das Hydroxil-Glied nur CeO₂, für das Fluor-Glied eine Mischung aus CeO₂, CeF₃ und CeOF. Faktoren, welche die Stabilität der einzelnen Spezies beeinflussen, werden diskutiert, wie das Verhältnis OH zu F, und die Gesamtzusammensetzung. Petrogenetische Folgerungen aus der vorliegenden Studie schließen ein, daß Bastnäsite von hydrothermalen bis zu magmatischen Bedingungen stabil sein können, daß sich an F angereicherte Glieder in relativ F-armer Umgebung bilden können, und daß OH-Glieder selten sind und nur unter Bildungsbedingungen niedriger Temperatur und weitgehender Abwesenheit von F auftreten.

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With 8 Figures  相似文献   

Fluid-rock interaction in the Mo-bearing Nebelstein greisen complex,Bohemian Massif (Austria)     

F. Koller  H. Högelsberger  C. Köeber 《Mineralogy and Petrology》1992,45(3-4):261-276

Summary In the Nebelstein area, molybdenite-bearing greisens occur together with peraluminous leucogranites. In the compositional change of the granites to the greisens, there is an almost complete loss of Na, combined with a decrease in Ca, Mg, Sr, and Ti concentrations. The progressive alteration is reflected by lower homogenization temperatures and increasing salinity in aqueous fluid inclusions. The fluid regime prior to greisenization was water-dominated with low salt contents, while the early stage of the greisen development was characterized by a mixed fluid containing carbon dioxide and water. This was succeeded by a moderate saline aqueous fluid which caused the mineralization by exchange of metal ions for Na⁺(Ca²⁺, K⁺). A negative correlation between salt content in fluid inclusions and Na₂O concentrations in the bulk rocks supports this model. Mass balance calculations for this interaction yield a minimum fluid-rock ratio of approximately 2 : I. Greisenization took place at a minimum pressure of 180 MPa (1.8 kb) and in a temperature range between 200 and < 400 °C.

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Fluid-Gestein-Wechselwirkung in dem Molybdänit führenden Greisenkomplex Nebelstein, Böhmische Masse (Österreich)

Zusammenfassung Die Molybdänglanz führenden Greisengesteine des Nebelsteins sind an peraluminöse Granite gebunden. Bei der Alteration der Granite ist für den Übergang Biotitgranit zu Greisen eine weitestgehende Verarmung an Na zu beobachten, gleichzeitig nehmen auch die Gehalte an Ca, Mg, Sr und Ti ab. Die fortschreitende Greisenbildung dokumentiert sich in den wäßrigen Flüssigkeitseinschlüssen durch steigende Salinität bei sinkenden Homogenisierungstemperaturen. Die fluide Phase war vor der Greisenbildung H₂O dominiert und niedrig salinar. Der Beginn der Alterationsprozesse ist durch CO₂ und H₂O hältige Fluide gekennzeichnet. Danach folgt ein Anstieg der Salinität, der auf den Austausch von Metallchloridlösungen gegen Na⁺, K^- und Ca^2- zurückgeführt wird. Dies läßt sich durch eine negative Korrelation der Salinität in den Flüssigkeitseinschlüssen mit dem Na-Gehalt der Gesteine belegen. Daraus wurde die Volumsbeziehung der den Granit durchströmenden fluiden Phase relativ zum Gestein mit mindestens 2 : 1 abgeleitet. Die Mineralisation fand bei einem Minimaldruck von 1,8 kb in einem Temperaturbereich von 200 - < 400 °C statt.

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This paper was presented at the IGCP 291 Project Symposium Metamorphic Fluids and Mineral Deposits, ETH Zürich, March21–23,1991.  相似文献   

The gawler ranges,South Australia: an unusual volcanic massif     

E. M. Campbell  C. R. Twidale 《The Australian geographer》1991,22(1):24-33

The volcanic residuals of the Gawler Ranges together form an extensive massif that in its gross morphology differs markedly from most exposures of silicic volcanic rocks. The upland developed in two stages, the first involving differential fracture‐controlled subsurface weathering, the second the stripping of the regolith. As a result, an irregular weathering front was exposed, with domical projections prominent. These bornhardts are etch forms, and they are of considerable antiquity.

The differential weathering of the rock mass reflects the exploitation of various fracture systems by shallow groundwaters. Orthogonal fracture systems at various scales, sheet fractures and columnar joints control the morphology of the bornhardts in gross and in detail.

The exploitation of the structural base, which was established in the Middle Protero‐zoic, probably took place throughout the Late Proterozoic and the Palaeozoic, though only minor remnants of the Proterozoic land surface remain. The major landscape features developed during the Mesozoic. The weathering which initiated the bornhardts occurred in the Jurassic or earlier Mesozoic, and the landforms were exposed in Late Cretaceous to Early Tertiary times.

Though structural forms dominate the present landscape, some major and some minor landforms are best explained in terms of climatic changes of the later Cainozoic. The palaeodrainage system, established under humid conditions by the Early Tertiary, was alluviated during the Cainozoic arid phases, and salinas were formed. The sand dunes of the region also reflect this aridity.  相似文献   

Population and geography in India     

Chandna RC 《Population geography : a journal of the Association of Population Geographers of India》1991,13(1-2):1-6

The field of population geography was first introduced during the 1960s in India and advanced under the direction of Gosal at the Punjab University. Teaching and research in population geography were introduced by Chandigarh at Punjab University, which today is the main center of research activity. Population geography in India has followed the main tenets of geography in general and is based on spatial perspectives. Deficits are apparent in the paucity of research on socioeconomic implications of spatial distributions, but there is infrastructural feedback to support theory development. Theoretical advances moving from theory to fact or from empirical fact to theory are limited. Comprehensive training in methodology and quantitative techniques is needed for further development of population theory: multivariate analysis, factor analysis, principal component analysis, model building, hypothesis testing, and theory formulation. Methodological sophistication will also help in understanding and interpreting the diverse and complex Indian demographic situation. The analysis of population geography in the Indian spatial, cultural, political, and historical context may be applied to other less developed countries of similar sociocultural background. The Indian Census has contributed over the 100 years of its existence reliable and efficiently produced data on a wide variety of measures at assorted scales down to the village level. Field work among geographers has not achieved a level of development commensurate with population censuses. Recent doctoral research has focused on qualitative studies of local situations. Research topics range from the distribution and structure of population, mortality, fertility, and migration to peripheral issues of social segregation. Popular topics include urbanization, labor force, sex composition, literacy, and population growth. Distribution of population and density studies have amounted to only 2 in 30 years. Population texts are in abundance. The Punjab University is the headquarters of the Association of Population Geographers, which publishes the journal "Population Geography." Many advances are still needed in a timely fashion.  相似文献   

The Mees CCD imaging spectrograph     

Matthew J. Penn  Donald L. Mickey  Richard C. Canfield  Barry J. Labonte 《Solar physics》1991,135(1):163-177

The Mees CCD (MCCD) instrument is an imaging spectroscopy device which uses the 25 cm coronagraph telescope and the 3.0 m Coudé spectrograph at Mees Solar Observatory (MSO) on Haleakala, Maui. The instrument works with resolving power up to R 200 000 with significant throughput from 3934 Å (Caii K) to 10 000 Å. A fast guiding active mirror stabilizes the image during observations. A rapidly writing magnetic tape storage system allows observations to be recorded at 256 kbytes s^–1. Currently, the MCCD is used for imaging spectroscopy of solar flares at 6563 Å (H), and velocity measurements of umbral oscillations; future plans include emission line studies of active region coronae, and photospheric studies of solar oscillations.  相似文献   

Period variation of selected cepheids     

József Vinkó 《Astrophysics and Space Science》1991,183(1):17-36

The aim of the present paper is to study the period as well as -velocity changes of 12 cepheid-type variable stars in order to find possible evidence for duplicity. Light-time effect was found in the O-C diagram of RY CMa, the orbital period being about 5200 days. Furthermore, especially spectroscopic observations are needed to confirm the duplicity or render the accurate orbital solution possible.  相似文献