A Tribute to Thomas M. Church: Exploring Chemical Oceanography in the Coastal Zone—The History and Future     

Gregory A. Cutter  David J. Burdige 《Aquatic Geochemistry》2016,22(4):271-274

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The Air-Coastal Sea Chemical Exchange: A Case Study on the New Jersey Coast     

Yuan Gao  Pami Mukherjee  Rafael Jusino-Atresino 《Aquatic Geochemistry》2016,22(4):275-289

The coastal marine atmosphere adjacent to large urban and industrial centers is in general strongly impacted by pollution emissions, resulting in high loading of pollutants in the ambient air. Among the airborne substances are certain trace elements from a variety of emission sources that can serve as micronutrients to marine organisms in coastal waters. High concentrations of such elements in coastal air can result in enhanced air-to-sea deposition fluxes to coastal waters. They could also be transported over the open ocean, affecting the composition of the remote marine atmosphere and then ocean ecosystems. To provide better understanding of the extent of air-to-sea deposition processes on the New Jersey coast, a heavily polluted coastal region on the US East Coast, a synthesis of observation data was carried out for selected trace elements, including Fe, Cd, Cr and Cu, derived from measurements of both size-segregated and bulk aerosol particles, as well as precipitation around the New Jersey coast. The atmospheric input of Hg was also estimated based on measurement data. Results indicated that the total deposition fluxes of most trace elements were higher in Northern coastal NJ compared to Southern coastal NJ, reflecting the differences in the source strengths of these element emissions between the two coastal regions. Dry deposition processes were more significant for common dust-derived elements, particularly Fe and Al, compared with their wet deposition fluxes. However, the processes of precipitation scavenging appeared to be more important for the elements that were often enriched in fine particles including Zn, Cu, Pb and Ni. The removal of Hg from the ambient air was overwhelmingly dominated by atmospheric wet deposition. In the future, atmospheric measurements at more sites on the NJ coast should be performed simultaneously to reduce the spatial and temporal uncertainties associated with atmospheric deposition fluxes estimated in this study.  相似文献   

Marine Chemistry in the Coastal Environment: Principles,Perspective and Prospectus   总被引：1，自引：1，他引：0  

Thomas M. Church 《Aquatic Geochemistry》2016,22(4):375-389

Marine chemistry of the coastal environment starts with principles of rock weathering that use carbonic acid to mobilize elements, only some of which comprise the majority of sea salt. The principle reason is reverse weathering, extensively represented in coastal waters, and returns most elements to newly formed colloids or minerals while recycling carbon dioxide to the atmosphere. This includes the deeper ocean expanse of sediment diagenesis, plus hydrothermal plumes and attendant low-temperature basalt alteration. Within the estuarine and extended shelf regimes, both conservative and non-conservative processes can be distinguished and modeled to determine proportions of weathered elements transmitted to the sea or consumed by reverse weathering. Conceptually, the steady-state processes that lead to the composition of seawater can be viewed as heterogeneous equilibria between dissolved constituents and solid mineral products taking hundreds of millennia. However, initial processes in the estuarine and coastal environment are characterized by shorter term scavenging associated with inorganic and organic colloids. These recycle both carbon and trace elements on timescales commensurate with estuarine flushing and coastal exchange with the ocean. The natural uranium and thorium decay series provide powerful tools for quantifying the rates of estuarine processes, including those within groundwater and the subterranean estuary. In the future, new mass spectrometric and nuclear magnetic resonance techniques will help to define the molecular nature of newly formed estuarine colloids as has been done for dissolved organic matter. As the coastal environment undergoes the forces of climate change in the form of warming and sea level rise, future research should address how these will impact chemistry of the coastal environment as a net source or sink of carbon dioxide and associated organic material.  相似文献   

Hierarchical simulation of aquifer heterogeneity: implications of different simulation settings on solute-transport modeling     

Alessandro Comunian  Leonardo De Micheli  Claudio Lazzati  Fabrizio Felletti  Francesca Giacobbo  Mauro Giudici  Riccardo Bersezio 《Hydrogeology Journal》2016,24(2):319-334

The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves.  相似文献   

The hydrogeology of the military inundation at the 1914–1918 Yser front (Belgium)     

Alexander Vandenbohede 《Hydrogeology Journal》2016,24(2):521-534

Protection against flooding by the sea, drainage of rainwater and integrated management of groundwater and surface-water resources are key issues in low-lying coastal areas. However, under exceptional circumstances, knowledge to keep coastal areas dry and habitable can be used otherwise. Inundation for military purposes is such an example. The hydrogeology of the inundation at the Yser River, Belgium, during the Great War is studied. The inundation started in October 1914 to stop the German advance and lasted until 1918. A water balance and groundwater model are combined to derive the water balance before and during the inundation and to study the impact on the groundwater system. It is concluded that a number of hydrogeological factors contributed to the effectiveness of the inundation. Most importantly, the low-permeability subsoil facilitated loss of inundation water mainly by evaporation. Further, the normal water management strategy of the area (aimed at evacuating excess water towards the sea) was reversed to keep water between the opposing armies. However, the duration of the inundation meant a reorganization of the drainage of areas not inundated; truly an exercise in integrated water management.  相似文献   

Impacts of a large Sahelian city on groundwater hydrodynamics and quality: example of Niamey (Niger)     

Aïssata B. Hassane  Christian Leduc  Guillaume Favreau  Barbara A. Bekins  Thomas Margueron 《Hydrogeology Journal》2016,24(2):407-423

The management of groundwater resources is very important in the semiarid Sahel region, which is experiencing rapid urban development. Impacts of urbanization on groundwater resources were investigated in the unconfined aquifer of the Continental Terminal beneath the city of Niamey, Niger, using water level and chemical data. Hydrodynamic and chemical changes are best described by a combination of factors including the historical development of the city, current land use, water-table depth and topography. Seasonal groundwater recharge occurs with high spatial variability, as indicated by water-level monitoring in all wells, but there was no interannual trend over the 5-year study period. Groundwater salinity shows high spatial variability and a minor rising trend. The highest salinity is in the old city centre, with Na–NO₃ dominant, and it increases seasonally with recharge. Salinity is much lower and more variable in the suburbs (Ca–HCO₃, Ca–NO₃, and Na–NO₃ dominant). Nitrate is the main ionic contaminant and is seasonally or permanently above the international guidelines for drinking water quality in 36 % of sampled wells, with a peak value of 112 mg L^?1 NO₃–N (8 meq L^?1). Comparison of urban and rural sites indicates a long-term increase in groundwater recharge and nitrate enrichment in the urban area with serious implications for groundwater management in the region.  相似文献   

Steady critical discharge rates from vertical and horizontal wells in fresh–saline aquifers with sharp interfaces     

Raziyeh Hendizadeh  Mazda Kompanizare  Mohammad R. Hashemi  G. Reza Rakhshandehroo 《Hydrogeology Journal》2016,24(4):865-876

In this study, the critical (or maximum) discharge rates before saline water enters a well were determined for vertical and horizontal wells in a freshwater aquifer which is separated from a static saline aquifer by a sharp interface. Flow around the well was solved by integration of a point sink solution along the well axis, and both the critical discharge rate and critical interface rise were determined through a comparison of the heads and vertical gradients at the saline–fresh water interface. The rates were determined for vertical and horizontal wells with various lengths and depths for different aquifer salinities. Results were generalized by drawing dimensionless type curves. The results showed that the dimensionless total critical discharge rates are higher for the longer horizontal wells and longer vertical wells with a certain bottom depth, and they almost linearly decrease with well depth at rates of 0.7–0.9. For the dimensionless well length of 0.2, the dimensionless total discharge rate of a horizontal well is about 0.1 more than that of a vertical well with the same length and well-top depth. Also, the critical discharge rates per unit length of well are inversely proportional to well length and remarkably higher for shallower wells. Additionally, the critical pumping rate is proportional to the salinity difference of the aquifers. These results were confirmed by comparison to existing solutions for vertical wells with dimensionless lengths of 0.2, 0.5 and 0.6, and for critical interface rises in the range of 0.75–0.9.  相似文献   

Measures for groundwater security during and after the Hanshin-Awaji earthquake (1995) and the Great East Japan earthquake (2011), Japan     

Tadashi Tanaka 《Hydrogeology Journal》2016,24(2):277-286

Many big earthquakes have occurred in the tectonic regions of the world, especially in Japan. Earthquakes often cause damage to crucial life services such as water, gas and electricity supply systems and even the sewage system in urban and rural areas. The most severe problem for people affected by earthquakes is access to water for their drinking/cooking and toilet flushing. Securing safe water for daily life in an earthquake emergency requires the establishment of countermeasures, especially in a mega city like Tokyo. This paper described some examples of groundwater use in earthquake emergencies, with reference to reports, books and newspapers published in Japan. The consensus is that groundwater, as a source of water, plays a major role in earthquake emergencies, especially where the accessibility of wells coincides with the emergency need. It is also important to introduce a registration system for citizen-owned and company wells that can form the basis of a cooperative during a disaster; such a registration system was implemented by many Japanese local governments after the Hanshin-Awaji Earthquake in 1995 and the Great East Japan Earthquake in 2011, and is one of the most effective countermeasures for groundwater use in an earthquake emergency. Emphasis is also placed the importance of establishing of a continuous monitoring system of groundwater conditions for both quantity and quality during non-emergency periods.  相似文献   

Effects of nonlinear model response on allocation of streamflow depletion: exemplified by the case of Beaver Creek,USA     

David P. Ahlfeld  James C. Schneider  Charles P. Spalding 《Hydrogeology Journal》2016,24(7):1835-1845

Anomalies found when apportioning responsibility for streamflow depletion are examined. The anomalies arise when responsibility is assigned to the two states that contribute to depletion of Beaver Creek in the Republican River Basin in the United States. The apportioning procedure for this basin presumes that the sum of streamflow depletions, computed by comparing simulation model runs with and without groundwater pumping from individual states, approximates the streamflow depletion when both states are pumping. In the case study presented here, this presumed superposition fails dramatically. The stream drying and aquifer-storage depletion, as represented in the simulation model used for allocation, are examined in detail to understand the hydrologic and numerical basis for the severe nonlinear response. Users of apportioning procedures that rely on superposition should be aware of the presence and likely magnitude of nonlinear responses in modeling tools.  相似文献   

The Great Artesian Basin: is it that great?     

Elad Dafny 《Hydrogeology Journal》2016,24(6):1329-1332

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