On using a generalized linear model to downscale daily precipitation for the center of Portugal: an analysis of trends and extremes     

Mário Pulquério  Pedro Garrett  Filipe Duarte Santos  Maria João Cruz 《Theoretical and Applied Climatology》2015,120(1-2):147-158

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New stacked central configurations for the planar 5-body problem   总被引：1，自引：0，他引：1  

Jaume Llibre  Luis Fernando Mello  Ernesto Perez-Chavela 《Celestial Mechanics and Dynamical Astronomy》2011,110(1):43-52

A stacked central configuration in the n-body problem is one that has a proper subset of the n-bodies forming a central configuration. In this paper we study the case where three bodies with masses m ₁, m ₂, m ₃ (bodies 1, 2, 3) form an equilateral central configuration, and the other two with masses m ₄, m ₅ are symmetric with respect to the mediatrix of the segment joining 1 and 2, and they are above the triangle generated by {1, 2, 3}. We show the existence and non-existence of this kind of stacked central configurations for the planar 5-body problem.  相似文献   

Quantum vacuum fluctuations and dark energy     

Emilio Santos 《Astrophysics and Space Science》2010,326(1):7-10

It is shown that the curvature of space-time induced by vacuum fluctuations of quantum fields should be proportional to the square of Newton’s constant G. This offers a possible explanation for the success of the formula ρ∼ Gm ⁶ c ² h ⁻⁴, ρ being the dark energy density and m a typical mass of elementary particles.  相似文献   

Biogeochemical processes and nutrient cycling within an artificial reef off Southern Portugal     

Falcão M  Santos MN  Vicente M  Monteiro CC 《Marine environmental research》2007,63(5):429-444

This study (2002/2004) examines the effect of artificial reef (AR) structures off the southern coast of Portugal on biogeochemical process and nutrient cycling. Organic and inorganic carbon, nitrogen, phosphorus and chlorophyll a were determined monthly in sediment cores and settled particles for a two-year period. Ammonium, nitrates, phosphates, silicates, total organic nitrogen and phosphorus, chlorophyll a and phaeopigments were also determined monthly in water samples within AR and control sites. Results of the two-year study showed that: (i) there was a significant exponential fit between organic carbon and chlorophyll a (r2=0.91; p<0.01) in reef sediment suggesting an increase of benthic productivity; (ii) organic carbon and nitrogen content in settled particles within AR environment was about four times higher two years after reef deployment; (iii) nutrients and chlorophyll a in the water column were higher at AR than control site. Two years after AR deployment, dissolved organic and inorganic compounds in near bottom water were 30-60% higher, emphasizing benthic remineralization processes at AR's organically rich sediment. Marked chemical changes in the ecosystem were observed during the two-year study period, reinforcing the importance of these structures for sandy coastal areas rehabilitation through trophic chain pull-out.  相似文献   

Lanthanide sorption on smectitic clays in presence of cement leachates     

Evgeny Galunin  Maria J. Santos  Miquel Vidal 《Geochimica et cosmochimica acta》2010,74(3):862-23407

Due to their potential retention capacity, clay minerals have been proposed for use in the engineered barriers for the storage of high-level radioactive actinides in deep geological waste repositories. However, there is still a lack of data on the sorption of actinides in clays in conditions simulating those of the repositories. The present article examines the sorption of two lanthanides (actinide analogues) in a set of smectitic clays (FEBEX bentonite, MX80 bentonite, hectorite, saponite, Otay montmorillonite, and Texas montmorillonite). Distribution coefficients (K_d) were determined in two media: water and 0.02 mol L⁻¹ Ca, the latter representing the cement leachates that may modify the chemical composition of the water in contact with the clay. The K_d values of the lanthanides used in the experiments (La and Lu) varied greatly (25-50 000 L kg⁻¹) depending on the ionic medium (higher values in water than in the Ca medium), the initial lanthanide concentration (up to three orders of magnitude decrease inversely with lanthanide concentration), and the examined clay (up to one order of magnitude for the same lanthanide and sorption medium). Freundlich and Langmuir isotherms were used to fit sorption data to allow comparison of the sorption parameters among smectites. The model based on the two-site Langmuir isotherms provided the best fit of the sorption data, confirming the existence of sorption sites with different binding energies. The sites with higher sorption affinity were about 6% of the total sorption capacity in the water medium, and up to 17% in the Ca medium, although in this latter site sorption selectivity was lower. The wide range of K_d values obtained regarding the factors examined indicated that the retention properties of the clays should also be considered when selecting a suitable clay for engineered barriers.  相似文献   

Thermal expansion and high-temperature P21/c–C2/c phase transition in clinopyroxene-type LiFeGe2O6 and comparison to NaFe(Si,Ge)2O6     

Günther J. Redhammer  Fernando Cámara  Matteo Alvaro  Fabrizio Nestola  Gerold Tippelt  Sebastian Prinz  Jan Simons  Georg Roth  Georg Amthauer 《Physics and Chemistry of Minerals》2010,37(10):685-704

A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) Å, β = 108.844(6)°, V = 442.75(16) ų, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the $(\bar{1}\,0\,1) A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) ?, β = 108.844(6)°, V = 442.75(16) ?³, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the ([`1] 0 1)(\bar{1}\,0\,1) plane, mostly along [0 1 0], and pure shear in the (0 1 0) plane due to the decrease of β. From comparison with silicate analogues, the germanate clinopyroxenes are more expansible, while the P2₁/c expands more than the C2/c phase. The evolution of Q ² (calculated as the normalized intensity of b-type reflections) with T in the framework of the Landau theory has been done using a standard expression for a first order phase transition. We observe a jump of Q ₀² = 0.538(2) at T _tr, with T _c of 481(7) K, b/a = −2,290 K, and c/a = 3,192 K, and thus far from being tri-critical point. A closely related composition (LiFe³⁺Si₂O₆) shows an equivalent phase transition at 228 K, which is very close to the tri-critical point and 561 K cooler. This result indicates that a change in the composition of tetrahedral sites can have dramatic effects on the P2₁/c ↔ C2/c displacive phase transition in clinopyroxenes. The major changes observed in the evolution of the crystal structure with T are observed in the M2 polyhedron, with a volume decrease by ca. 13.3%, compared to ca. 1.3% observed in the M1 polyhedron. The tetrahedra behave as rigid units with neither a significant change of volume at T > T _tr (<1‰), nor a change of tilting of the basal plane. No change in coordination is observed at T > T _tr in the M2 polyhedron, which remains sixfold coordinated although a strong deformation of this polyhedron is observed. This deformation is related to a strong change by 51.4° at T _tr of the kinking angle (O3–O3–O3 angle) of the B-chain of tetrahedra, which switches from O-rotated to S-rotated [from 143.3(5)° to 194.7(6)°]. The A-chain is S-rotated at T < T _tr [206.8(5)° at 703 K] and extends by 12° at the transition.  相似文献   

Ultrasonic Spectral and Complexity Measurements on Brine and Oil Saturated Rocks     

C. A. Santos  V. Urdaneta  G. Jaimes  L. Trujillo 《Rock Mechanics and Rock Engineering》2010,43(3):351-359

The effects of the rheological properties of fluids on the acoustic behavior of heterogeneous media like rocks are usually very difficult to characterize. We show here that, in ultrasonic tests and their spectral characterizations, signal attenuation is the most evident difference between water and oil saturated rock samples. Density effects, as explained by the inertial component of the Biot’s poroelastic theory, along with entropic analysis seem to provide a good understanding of the pore-fluid effects on the acoustic response of saturated rocks.  相似文献   

Application of multi-isotope ratios to study the source and quality of urban groundwater in Metro Manila,Philippines   总被引：1，自引：0，他引：1  

Takahiro Hosono  Fernando Siringan  Tsutomu Yamanaka  Yu Umezawa  Shin-ichi Onodera  Takanori Nakano  Makoto Taniguchi 《Applied Geochemistry》2010

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Extreme events and disasters: a window of opportunity for change? Analysis of organizational,institutional and political changes,formal and informal responses after mega-disasters   总被引：3，自引：3，他引：0  

J. Birkmann  P. Buckle  J. Jaeger  M. Pelling  N. Setiadi  M. Garschagen  N. Fernando  J. Kropp 《Natural Hazards》2010,55(3):637-655

Disaster associated with natural hazards can lead to important changes—positive or negative—in socio-ecological systems. When disasters occur, much attention is given to the direct disaster impacts as well as relief and recovery operations. Although this focus is important, it is noteworthy that there has been little research on the characteristics and progress of change induced by disasters. Change, as distinct from impacts, encompasses formal and informal responses to disaster events and their direct and indirect impacts. While smaller disasters do not often lead to significant changes in societies and organizational structures, major disasters have the potential to change dominant ways of thinking and acting. Against this background, the article presents an analytical framework for distinguishing change from disaster impacts. Drawing from research in Sri Lanka and Indonesia, formal and informal changes after the Indian Ocean Tsunami of 2004 are examined and discussed against the background of the conceptual framework. The changes examined range from the commencement of the peace process in Aceh, Indonesia, to organizational and legal reforms in Sri Lanka. The article concludes that change-making processes after disasters need to be understood more in depth in order to derive important strategic policy and methodological lessons learned for the future, particularly in view of the increasing complexity and uncertainty in decision making due to climate change.  相似文献   

Introduction     

María dos Santos Afonso  Miguel A. Blesa 《Aquatic Geochemistry》2010,16(2):223-224

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