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31.
This discussion paper, by a Working Group of INTIMATE (Integration of ice‐core, marine and terrestrial records) and the Subcommision on Quaternary Stratigraphy (SQS) of the International Commission on Stratigraphy (ICS), considers the prospects for a formal subdivision of the Holocene Series/Epoch. Although previous attempts to subdivide the Holocene have proved inconclusive, recent developments in Quaternary stratigraphy, notably the definition of the Pleistocene–Holocene boundary and the emergence of formal subdivisions of the Pleistocene Series/Epoch, mean that it may be timely to revisit this matter. The Quaternary literature reveals a widespread but variable informal usage of a tripartite division of the Holocene (‘early’, ‘middle’ or ‘mid’, and ‘late’), and we argue that this de facto subdivision should now be formalized to ensure consistency in stratigraphic terminology. We propose an Early–Middle Holocene Boundary at 8200 a BP and a Middle–Late Holocene Boundary at 4200 a BP, each of which is linked to a Global Stratotype Section and Point (GSSP). Should the proposal find a broad measure of support from the Quaternary community, a submission will be made to the International Union of Geological Sciences (IUGS), via the SQS and the ICS, for formal ratification of this subdivision of the Holocene Series/Epoch. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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Summary. The crustal structure beneath the exposed terranes of southern Alaska has been explored using coincident seismic refraction and reflection profiling. A wide-angle reflector at 8–9 km depth, at the base of an inferred low-velocity zone, underlies the Peninsular and Chugach terranes, appears to truncate their boundary, and may represent a horizontal decollement beneath the terranes. The crust beneath the Chugach terrane is characterized by a series of north-dipping paired layers having low and high velocities that may represent subducted slices of oceanic crust and mantle. This layered series may continue northward under the Peninsular terrane. Earthquake locations in the Wrangell Benioff zone indicate that at least the upper two low-high velocity layer pairs are tectonically inactive and that they appear to have been accreted to the base of the continental crust. The refraction data suggest that the Contact fault between two similar terranes, the Chugach and Prince William terranes, is a deeply penetrating feature that separates lower crust (deeper than 10 km) with paired dipping reflectors, from crust without such reflectors.  相似文献   
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We present mid-infrared spectra and images from the Gemini-N (+MICHELLE) observational campaign of Comet 9P/Tempel 1 before, during, and after its encounter with Deep Impact. We use our thermal grain model to probe the 10 μm properties of the dust grains in the coma of the comet. Before impact (3 July 2005 UT), and more than 24 h after impact (5, 16, and 28 July 2005 UT), the comet dust grains were composed mostly of amorphous olivine, and were relatively large (peak of the grain size distribution ). For the night of impact, we extract spectra by centering on the nucleus, and offset 1″ from the nucleus in the direction of the impact ejecta plume. We find small dust grains (∼0.2 μm) of a diverse mineralogy (amorphous olivine, amorphous pyroxene, amorphous carbon, and crystalline olivine) populating the ejecta. The submicron sized dust grains move faster than the other, larger grains (?0.7 μm), with amorphous olivine and amorphous carbon traveling together, and amorphous pyroxene and crystalline olivine dispersing at a similar rate. Deriving a velocity law from a time-of-flight analysis, we find that the material traveled with a velocity law scaled by and with a power of p=0.5. This velocity power-law requires a sustained release of grains for the duration of 45-60 min after impact. Since the mineral species are traveling at different speeds, and there was a sustained release of grains due to a possible “gas-plume,” we conclude that the different minerals did not originate from grain aggregates destroyed by the impact, but instead arise from an inhomogeneous nucleus.  相似文献   
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Thallium(I) has been added to estuarine sediment suspended in various natural and artificial aqueous samples in order to examine its reactivity under simulated estuarine conditions. In river water and sea water, adsorption of Tl to sediment was so rapid that a period of desorption-relaxation succeeded instantaneous adsorption. Entire time-courses could not be fitted with a conventional kinetic model, but pseudo-first-order forward and reverse rate constants of 0.0044 and 0.30 h−1, respectively, were derived for river water by omitting measurements defining the adsorption “overshoot” observed at the onset of the experiment. The extent of adsorption after a 16 h equilibration period was considerably greater in river water than in sea water, and displayed a quasi-linear increase with increasing pH over the range 2-9 in the former but no clear dependence on pH in the latter. A logarithmic reduction in the sediment-water distribution coefficient, KD, was observed on estuarine mixing from river water to sea water. Experiments conducted in electrolyte solutions coupled with inorganic equilibrium speciation modeling revealed that the effect was the combined result of a reduction in the activity of Tl+, an increase in the proportion of TlCl0 and increasing competition for adsorption sites from K+ with an increase in salinity. Overall, there was little experimental evidence for either the oxidation of Tl+ or its complexation by dissolved organic matter. The findings of the investigation are discussed in terms of the likely behavior of Tl in estuaries.  相似文献   
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Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe3(SO4)2(OH)6, where A = K, Na, Rb, and NH4. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:
Sample Chemical composition S o/(J mol−1 K−1)
K-jarosite K0.92(H3O)0.08Fe2.97(SO4)2(OH)5.90(H2O)0.10 427.4 ± 0.7
Na-jarosite Na0.95(H3O)0.05Fe3.00(SO4)2(OH)6.00 436.4 ± 4.4
Rb-jarosite RbFe2.98(SO4)2(OH)5.95(H2O)0.05 411.9 ± 4.1
NH4-jarosite (NH4)0.87(H3O)0.13Fe3.00(SO4)2(OH)6.00 447.2 ± 4.5
Defect jarosite K0.94(H3O)0.06Fe2.34(SO4)2(OH)4.01(H2O)1.99 412.7 ± 4.1
There are additional configurational entropies of 13.14 and 8.23 J mol−1 K−1 in defect and NH4-jarosite, respectively. A detailed analysis of the synchrotron X-ray diffraction patterns showed a large anisotropic peak broadening for defect and NH4-jarosite. The fits to the low-temperature (approx. <12 K) C p data showed that our samples can be divided into two groups. The first group is populated by the K-, Na-, Rb-, and NH4-jarosite samples, antiferromagnetic at low temperatures. The second group contains the H3O-jarosite (studied previously) and the defect jarosite. H3O- and defect jarosite are spin glasses and their low-T C p was fit with the expression C p = γT + ΣB j T j , where j = (3, 5, 7, 9). The linear term is typical for spin glasses and the sum represents the lattice contribution to C p. Surprisingly, the C p of the K-, Na-, Rb-, and NH4-jarosite samples, which are usually considered to be antiferromagnetic at low temperatures, also contains a large linear term. This finding suggests that even these phases do not order completely, but have a partial spin-glass character below their Néel transition temperature.  相似文献   
38.
The effectiveness of larval behavior in regulating transport between well-mixed, low-inflow estuaries and coastal waters in seasonally arid climates is poorly known. We determined the flux of an assemblage of benthic crustacean larvae relative to physical conditions between a shallow estuary and coastal waters on the upwelling coast of northern California (38°18′N, 123°03′W) from 29 to 31 March 2006. We detected larval behaviors that regulate transport in adjacent coastal waters and other estuaries for only two taxa in the low-inflow estuary, but they were apparent for taxa outside the estuary. Vertical mixing in the shallow estuary may have overwhelmed larvae of some species, or salinity fluctuations may have been too slight to cue tidal vertical migrations. Nevertheless, all larval stages of species that complete development in nearshore coastal waters were present in the estuary, because they remained low in the water column reducing seaward advection or they were readily exchanged between the estuary and open coast by tidal flows. Weak tidal flows and gravitational circulation at the head of the estuary reduced seaward transport during development for species that completed development nearshore, whereas larval release during nocturnal ebb tides enhanced seaward transport for species that develop offshore. Thus, nonselective tidal processes dominated larval transport for most species back and forth between the low-inflow estuary and open coastal waters, whereas in adjacent open coastal waters, larval behavior in the presence of wind-induced shear was more important in regulating migrations between adult and larval habitats along this upwelling coast.  相似文献   
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How do we understand national climate change politics in the United States? Using a methodological innovation in network analysis, this paper analyzes discussions about the issue within the US Congress. Through this analysis, the ideological relationships among speakers providing Congressional testimony on the issue of climate change are mapped. For the first time, issue stances of actors are systematically aggregated in order to measure coalitions and consensus among political actors in American climate politics in a relational way. Our findings show how consensus formed around the economic implications of regulating greenhouse gases and the policy instrument that should do the regulating. The paper is separated into three sections. First, we review the ways scholars have looked at climate change policymaking in the United States, paying particular attention to those who have looked at the issue within the US Congress. Next, we present analysis of statements made during Congressional hearings on climate change over a four-year period. Our analysis demonstrates how a polarized ideological actor space in the 109th Congress transforms into a more consensual actor landscape in the 110th Congress, which is significantly less guided by partisan differences. This paper concludes by discussing how these findings help us understand shifting positions within American climate politics and the implications of these findings.  相似文献   
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