MTBE, TBA, and TAME Attenuation in Diverse Hyporheic Zones     

by James E. Landmeyer  Paul M. Bradley  Donald A. Trego  Kevin G. Hale  Joseph E. Haas II 《Ground water》2010,48(1):30-41

Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert -butyl ether (MTBE), tert -butyl alcohol (TBA), and tert -amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four sites were investigated on Long Island, New York, characterized by groundwater contaminated with gasoline and fuel oxygenates that ultimately discharge to fresh, brackish, or saline surface water. For each site, contaminated groundwater discharge zones were delineated using pore water geochemistry data from 15 feet (4.5 m) beneath the bottom of the surface water body in the hyporheic zone and seepage-meter tests were conducted to measure discharge rates. These data when combined indicate that MTBE, TBA, and TAME concentrations in groundwater discharge in a 5-foot (1.5-m) thick section of the hyporheic zone were attenuated between 34% and 95%, in contrast to immeasurable attenuation in the shallow aquifer during contaminant transport between 0.1 and 1.5 miles (0.1 to 2.4 km). The attenuation observed in the hyporheic zone occurred primarily by physical processes such as mixing of groundwater and surface water. Biodegradation also occurred as confirmed in laboratory microcosms by the mineralization of U- ¹⁴C-MTBE and U-¹⁴C-TBA to ¹⁴CO₂ and the novel biodegradation of U- ¹⁴C-TAME to ¹⁴CO₂ under oxic and anoxic conditions. The implication of fuel oxygenate attenuation observed in diverse hyporheic zones suggests an assessment of the hyporheic zone attenuation potential (HZAP) merits inclusion as part of site assessment strategies associated with monitored or engineered attenuation.  相似文献   

The Effects of Tidal Export from Salt Marsh Ditches on Estuarine Water Quality and Plankton Communities     

Florian Koch  Christopher J. Gobler 《Estuaries and Coasts》2009,32(2):261-275

Salt marshes are an important transition zone between terrestrial and marine ecosystems, and in their natural state, they often function to cycle or trap terrestrially derived nutrients and organic matter. Many US salt marshes were ditched during the twentieth century, potentially altering their functionality. The goal of this 4-year study was to assess the impact of water from ditches within seven salt marshes on estuarine water quality and plankton communities within four estuaries on Long Island, NY, USA. We found that concentrations of inorganic nutrients (ammonium, phosphate), dissolved and particulate organic nitrogen and carbon (POC, PON, DOC, DON), and total coliform bacteria were significantly enriched in salt marsh ditches compared to the estuaries they discharged into. In addition, concentrations of ammonium and DON became more enriched in ditches as tidal levels decreased, suggesting these constituents were generated in situ. Quantification of nitrogen sources in Flanders Bay, NY, suggested salt marsh ditches could represent a substantial source of N to this estuary during summer months. Experimental incubations demonstrated that water from salt marsh ditches was capable of significantly enhancing the growth of multiple classes of phytoplankton, with large diatoms and dinoflagellates displaying the most dramatic increases in growth. Experiments further demonstrated that salt marsh ditchwater was capable of significantly enhancing pelagic respiration rates, suggesting discharge from ditches could influence estuarine oxygen consumption. In summary, this study demonstrates that tidal draining of salt marsh ditches is capable of degrading multiple aspects of estuarine water quality.  相似文献   

The Enya mounds: a lost mound-drift competition     

D. Van Rooij  V. A. I. Huvenne  D. Blamart  J.-P. Henriet  A. Wheeler  H. de Haas 《International Journal of Earth Sciences》2009,98(4):849-863

The genesis and evolution of cold-water coral banks along the Northeastern Atlantic margin is known to be influenced by several factors, among which the palaeotopography and nature of the coral settling surface, the presence of bottom currents and sediment supply. In this paper, a case study is presented of the Enya mound cluster, located in the southernmost tip of the Belgica mound province, west of Ireland. Below this mound cluster, seismic stratigraphy revealed a yet unmapped local unconformity RD1b, being part of a composite erosion event (RD1). As such, from the Late Miocene to Late Pliocene, at least two erosional events have incised the margin, ending with the final RD1a “moundbase” unconformity, acting as a base for the Enya mounds. During the Quaternary the mounds became outgrown and were covered by a mounded contourite drift. In addition, they are closely associated with a cluster of seabed pockmarks. The bottom current regime which became active since the Middle Pleistocene has certainly influenced the fate of this mound cluster. The occurrence of the pockmarks seems to be related to relatively recent fluid migration processes, however leaving an open question if any previous seepage phases were involved in the growth or initiation of the coral banks.  相似文献   

Human impact on the transport of terrigenous and anthropogenic elements to peri-alpine lakes (Switzerland) over the last decades     

Florian Thevenon  Stefanie B. Wirth  Marian Fujak  John Poté  Stéphanie Girardclos 《Aquatic Sciences - Research Across Boundaries》2013,75(3):413-424

Terrigenous (Sc, Fe, K, Mg, Al, Ti) and anthropogenic (Pb and Cu) element fluxes were measured in a new sediment core from Lake Biel (Switzerland) and in previously well-documented cores from two upstream lakes (Lake Brienz and Lake Thun). These three large peri-alpine lakes are connected by the Aare River, which is the main tributary to the High Rhine River. Major and trace element analysis of the sediment cores by inductively coupled plasma mass spectrometry (ICP-MS) shows that the site of Lake Brienz receives three times more terrigenous elements than the two other studied sites, given by the role of Lake Brienz as the first major sediment sink located in the foothills of the Alps. Overall, the terrigenous fluxes reconstructed at the three studied sites suggest that the construction of sediment-trapping reservoirs during the twentieth century noticeably decreased the riverine suspended sediment load at a regional scale. In fact, the extensive river damming that occurred in the upstream watershed catchment (between ca. 1930 and 1950 and up to 2,300 m a.s.l.) and that significantly modified seasonal suspended sediment loads and riverine water discharge patterns to downstream lakes noticeably diminished the long-range transport of (fine) terrigenous particles by the Aare River. Concerning the transport of anthropogenic pollutants, the lowest lead enrichment factors (EFs Pb) were measured in the upstream course of the Aare River at the site of Lake Brienz, whereas the metal pollution was highest in downstream Lake Biel, with the maximum values measured between 1940 and 1970 (EF Pb > 3). The following recorded regional reduction in aquatic Pb pollution started about 15 years before the actual introduction of unleaded gasoline in 1985. Furthermore, the radiometric dating of the sediment core from Lake Biel identifies three events of hydrological transport of artificial radionuclides released by the nuclear reactor of Mühleberg located at more than 15 km upstream of Lake Biel for the time period 1970–2000.  相似文献   

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures     

Ghislain Dubois  Benjamin Sovacool  Carlo Aall  Maria Nilsson  Carine Barbier  Alina Herrmann  Sébastien Bruyère  Camilla Andersson  Bore Skold  Franck Nadaud  Florian Dorner  Karen Richardsen Moberg  Jean Paul Ceron  Helen Fischer  Dorothee Amelung  Marta Baltruszewicz  Jeremy Fischer  Françoise Benevise  Valérie R. Louis  Rainer Sauerborn 《Chemie der Erde / Geochemistry》2012

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.  相似文献   

Groundwater Evolution and Mineral Alteration Reactions in the Basaltic Rock Sequence of Mt. Wasserkuppe, Germany: A Case Study     

Florian Ludwig  Ingrid Stober  Kurt Bucher 《Aquatic Geochemistry》2012,18(3):185-215

Groundwater sampling was accomplished in the basaltic sequence of the Rh?n mountain range, Germany, in order to investigate hydrochemical groundwater evolution and to delineate mineral alteration reactions involved in natural weathering. The hydrochemical compositions of near-surface groundwaters indicate a Ca/Mg–HCO₃ type with near-neutral pH and evolve to a Na–HCO₃ type with high pH at greater depth. Column experiments were performed with basaltic and phonolitic rock samples to determine individual mineral alteration reactions. The basic reactions could be related to the alteration of olivine, Ca-pyroxene, plagioclase, pyrrhotite, and feldspathoids under formation of secondary clay minerals (smectites, illite) and goethite. The mineral alteration reactions deduced from the leaching experiments by inverse modelling were found to be consistent with the mineral reactions associated with the natural groundwaters. The reactions calculated for groundwater evolution involve the alteration of primary and secondary minerals to produce low-T mineral phase. The conversion of secondary Na-beidellite to illite occurs at a later stage of groundwater evolution, reducing the concentrations of K⁺ and Mg²⁺. Near-surface groundwaters do not indicate significant cation exchange. Initial cation exchange requires elevated pH values, with Mg²⁺ removed from solution preferred to Ca²⁺. Na-alkalisation of the groundwaters at greater depth suggests the exchange of Na⁺ for Mg²⁺ and Ca²⁺ on Na-beidellite, supported by cation exchange on coatings of iron hydroxides as alteration products. Among the mature high-pH groundwater at greater depth, the dissolution of anorthite and albite has significant effect on groundwater composition.  相似文献   

VLBI-derived troposphere parameters during CONT08   总被引：2，自引：2，他引：0  

R. Heinkelmann  J. B?hm  S. Bolotin  G. Engelhardt  R. Haas  R. Lanotte  D. S. MacMillan  M. Negusini  E. Skurikhina  O. Titov  H. Schuh 《Journal of Geodesy》2011,85(7):377-393

Time-series of zenith wet and total troposphere delays as well as north and east gradients are compared, and zenith total delays (ZTD) are combined on the level of parameter estimates. Input data sets are provided by ten Analysis Centers (ACs) of the International VLBI Service for Geodesy and Astrometry (IVS) for the CONT08 campaign (12?C26 August 2008). The inconsistent usage of meteorological data and models, such as mapping functions, causes systematics among the ACs, and differing parameterizations and constraints add noise to the troposphere parameter estimates. The empirical standard deviation of ZTD among the ACs with regard to an unweighted mean is 4.6?mm. The ratio of the analysis noise to the observation noise assessed by the operator/software impact (OSI) model is about 2.5. These and other effects have to be accounted for to improve the intra-technique combination of VLBI-derived troposphere parameters. While the largest systematics caused by inconsistent usage of meteorological data can be avoided and the application of different mapping functions can be considered by applying empirical corrections, the noise has to be modeled in the stochastic model of intra-technique combination. The application of different stochastic models shows no significant effects on the combined parameters but results in different mean formal errors: the mean formal errors of the combined ZTD are 2.3?mm (unweighted), 4.4?mm (diagonal), 8.6?mm [variance component (VC) estimation], and 8.6?mm (operator/software impact, OSI). On the one hand, the OSI model, i.e. the inclusion of off-diagonal elements in the cofactor-matrix, considers the reapplication of observations yielding a factor of about two for mean formal errors as compared to the diagonal approach. On the other hand, the combination based on VC estimation shows large differences among the VCs and exhibits a comparable scaling of formal errors. Thus, for the combination of troposphere parameters a combination of the two extensions of the stochastic model is recommended.  相似文献   

Mediterranean migration futures: Patterns,drivers and scenarios     

Hein de Haas 《Global Environmental Change》2011

This study explores possible futures of Mediterranean migration based on an evaluation of past, current and future drivers of migration in the region. Since 1950, structural shifts in the political economy of the region have fundamentally changed the Mediterranean migration map. Particularly the rise of Gulf economies and south European growth and EU expansion has transformed the northern Mediterranean and the Gulf into new immigration poles. The main drivers of these changes are economic and political. Contrary to conventional beliefs, the role of environmental and also demographic factors seems comparatively limited, probabilistic and indirect. Future climate change and environmental stress may affect internal movement but are unlikely to result in massive international migration. Under most scenarios, Turkey and other North African countries may well evolve into immigration countries coinciding with increasing immigration from sub-Saharan Africa to the entire Mediterranean.  相似文献   

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures     

Ghislain Dubois  Benjamin Sovacool  Carlo Aall  Maria Nilsson  Carine Barbier  Alina Herrmann  Sébastien Bruyère  Camilla Andersson  Bore Skold  Franck Nadaud  Florian Dorner  Karen Richardsen Moberg  Jean Paul Ceron  Helen Fischer  Dorothee Amelung  Marta Baltruszewicz  Jeremy Fischer  Françoise Benevise  Rainer Sauerborn 《Chemie der Erde / Geochemistry》2013

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.  相似文献   

Hα emission objects in Circinus     

S. Noroozi  M. Haas  Z. Chen  R. Chini 《Astronomische Nachrichten》2013,334(3):282-287

We present a new survey for Hα emission objects in the Circinus cloud complex and introduce an efficient photometric method for detecting Hα emission via observations in a narrow‐band filter. The observed flux is compared to a blackbody fit of the continuum. Our search strategy reveals 20 stars with strong Hα emission (EW > 10 Å), eight of them being new detections. All Hα stars display infrared excess corroborating their youth. On the other hand, the region contains a number of infrared excess objects that do not show Hα emission. Our results support the picture that accretion – as witnessed by Hα emission – is a highly variable phenomenon. Therefore, Hα surveys can only trace the temporarily active objects. In contrast, infrared excess is a more robust tracer that reveals most of the population of young stellar objects in a star forming region. Our analysis of the general stellar content of the region yields a reliable distance of 450 pc for the Circinus cloud. Moreover, we find a ratio of total‐to‐selective extinction of R^V = 2.8 suggesting that smaller‐than‐normal dust grains may be present. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献