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81.
82.
The extent of complexation of calcium(II) and copper(II) with 33 carbohydrates found in seawater has been determined potentiometrically using calcium and copper ion-selective electrodes. The measurements were performed in an essentially neutral aqueous medium at 25°C in 0.70 M KNO3.Neutral sugars form very weak 1:1 complexes with Ca(II) and Cu(II) ions. Sugars with carboxylate groups from much stronger complexes. KCu(II) >KCa(II)) for a given sugar. The extent of complexation is dependent on the conformation of the sugar ligand.  相似文献   
83.
84.
Based on studies of sediment accumulations deposited from-and erode by-alongslope flowing ocean currents on the European continental margin from Porcupine (Ireland) to Lofoten (Norway), the evolution of the Cenozoic paleocirculation was reconstructed as part of the STRATAGEM project. There is evidence of ocean current-controlled erosion and deposition in the Rockall Trough, in the Faeroe-Shetland Channel and on the Vøring Plateau since the late Eocene, although the circulation pattern remains ambiguous. The late Palaeogene flow in the Rockall Trough was almost probably driven by southerly-derived Tethyan Outflow Water. The extent and strength of any northerly-derived flow is uncertain. From the early Neogene (early-mid-Miocene), there was a massive regional expansion of contourite drift development both in the North Atlantic and in the Norwegian-Greenland Sea. This was most probably related to the development of the Faroe Conduit, the opening of the Fram Strait and the general subsidence of the Greenland-Scotland Ridge. These may have combined to cause a considerable acceleration in the exchange and overflow of deep waters between the Arctic and Atlantic Oceans. An early late Neogene (late early Pliocene) regional erosional event has been ascribed to a vigorous pulse of bottom-current activity, most probably the result of a global reorganisation of ocean currents associated with the closure of the Central American Seaway. During the late Neogene, contourites and sediment drifts developed in deep-water basins, between units of glacigenic sediments as well as infill of several paleo-slide scars. These sediments were derived from areas of bottom-current erosion as well as from the development of Plio-Pleistocene prograding sediment wedges, incorporating the extensive sediment supply derived from shelf-wide ice sheets. Presently a profound winnowing prevails along the shelf and upper slope due to the inflowing currents of Atlantic water. Depocentres of sediments derived from the winnowing are located (locally) in lower slope embayments and in slide scars.  相似文献   
85.
To enhance global water use assessment, the WaterGAP3 model was improved for back-calculating domestic, manufacturing and thermoelectric water uses until 1950 for 177 countries. Model simulations were carried-out on a national scale to estimate water withdrawals and consumption as well as cooling water required for industrial processes and electricity production. Additionally, the amount of treated and untreated wastewater as generated by the domestic and manufacturing sectors was modeled. In the view of data availability, model simulations are based on key socio-economic driving forces and thermal electricity production. Technological change rates were derived from statistical records in order to consider developments in water use efficiency, which turned out to have a crucial role in water use dynamics. Simulated domestic and industrial water uses increased from ca. 300 km3 in 1950 to 1345 km3 in 2010, 12% of which were consumed and 88% of which were discharged back into freshwater bodies. The amount of domestic and manufacturing wastewater increased considerably over the last decade, but only half of it was untreated. The downscaling of the untreated wastewater volume to river basin scale indicates a matter of concern in East and Southeast Asia, Northern Africa, and Eastern and Southern Europe. In order to reach the Millennium Development Goals, securing water supply and the reduction of untreated wastewater discharges should be amongst the priority actions to be undertaken. Population growth and increased prosperity have led to increasing water demands. However, societal and political transformation processes as well as policy regulations resulting in new water-saving technologies and improvements counteract this development by slowing down and even reducing global domestic and industrial water uses.  相似文献   
86.
Acta Geotechnica - The hole erosion test (HET) was developed to simulate piping erosion and to study the erosion parameters of cohesive soils. The erosion rate in the HET is evaluated by the...  相似文献   
87.
This paper is the second in a series describing the southern Galactic Disk Survey (GDS) performed at the Univer‐sitätssternwarte Bochum near Cerro Armazones in Chile. Haas et al. (2012, Paper I) presented the survey design and the characteristics of the observations and data. They identified ∼2200 variable stars in an area of 50 square degrees with more than 50 observations in 2011. Here we present the first complete version of the GDS covering all 268 fields with 1323 square degrees along the Galactic disk including revised data from Paper I. The individual fields were observed up to 272 times and comprise a maximum time span between September 2010 and May 2015. We detect a total of 64 151 variable sources, which are presented in a catalog including some of their properties and their light curves. A comparison with the International Variable Star Index (VSX) and All Sky Automated Survey (ASAS) indicates that 56794 of these sources are previously unknown variables. Furthermore, we present U, B, V, r ′, i ′, z ′ photometry for all sources within the GDS, resulting in a new multi‐color catalog of nearly 16×106 sources detected in at least one filter. Both the GDS and the near‐infrared VISTA Variables in the Via Lactea survey (VVV) complement each other in the overlap area of about 300 square degrees enabling future comparison studies. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
88.
U–Pb zircon geochronology, Sr–Nd isotope and bulk-rock geochemistry have been applied to meta-igneous and meta-sedimentary rocks from high-pressure metamorphic mélanges exposed on the Cycladic islands of Tinos, Syros and Andros. Ion microprobe (SHRIMP) U–Pb zircon dating of 7 samples representing meta-igneous blocks (Tinos), a blackwall zone (Tinos) and chlorite–talc schists from block-matrix contacts (Syros and Tinos) yielded Cretaceous ages of c. 80 Ma. Many of the criteria commonly used to distinguish between magmatic or metamorphic zircon genesis (internal structure, Th/U ratio, REE characteristics, Ti-in zircon thermometry, enclosed mineral phases) do not provide unambiguous constraints for the mode of formation. However, a magmatic origin for Cretaceous zircon of meta-gabbros and eclogites is considered likely. Supporting evidence for a previously suggested metamorphic origin for c. 80 Ma zircon in eclogite has not been found. Zircon of the same age occurring in chlorite–talc schists is presumably related to non-magmatic processes. Well-defined Cretaceous age groups clustering at c. 79 Ma also occur in the detrital zircon populations of 2 quartz mica schists representing the mélange matrix on Tinos, and suggest a much later time for sediment accumulation than previously assumed. The importance of c. 57 Ma zircon ages remains unclear, but may record either HP metamorphic processes or a post-57 Ma depositional age. The youngest age group in a third quartz mica schist from Tinos, collected outside the main mélange occurrences, clusters at c. 226–238 Ma. In all clastic metasediments from Tinos, most data points plot along the concordia between c. 300 and 900 Ma; single data points indicate concordant ages of c. 2.5 Ga, 2.3 Ga and 1 Ga, respectively. The youngest 206Pb/238U age group that has been recognized in a felsic paragneiss from Andros indicates an age of 163.1 ± 3.9 Ma, and mostly represents overgrowths around zircon with ages in the range from ~ 272 to ~ 289 Ma. Single data points of other inherited cores provided 206Pb/238U ages of c. 630 and c. 930 Ma. Meta-gabbros from Tinos show a large compositional variability and were found at 4 locations, each with distinct compositional characteristics, suggesting different crystallization histories, different sources and/or significant post-magmatic disturbance. The geochemistry of mélange blocks and the identical U–Pb zircon ages suggest that the block-matrix associations on Tinos and Syros can be grouped together. On a broader regional scale, there seem to be similarities between some meta-igneous rocks from Tinos and Evvia. Field relationships indicate that the mélanges occurring in southern Andros and northern Tinos can be correlated, but supporting geochemical and/or geochronological evidence for this interpretation could not be established. Previously published Jurassic ages for mafic and felsic mélange blocks from Andros suggest a genetic relationship to the ophiolite occurrences exposed in the larger Balkan region. A similar regional correlation is also considered likely for the Cretaceous meta-gabbros from Tinos and Syros, but cannot be documented with certainty.  相似文献   
89.
Zusammenfassung Die wenig bekannte Cordillera Claudio Gay ist ein Teil der Vorkordillere in Nordchile. Ihr Unterbau besteht aus Tiefengesteinskörpern des PalÄozoikums und einer Sedimentserie, die von sauren Ergu\gesteinen durchbrochen wird. Die petrologische Zusammensetzung der Sedimente und ihre metamorphe überprÄgung werden speziell behandelt. Da keine Fossilien vorliegen, kann das Alter der Sedimente nur auf eine Zeitspanne zwischen Devon und Perm eingeengt werden.
The little-known Cordillera Claudio Gay is part of the Pre-Cordillera in Northern Chile. Its basement consists of plutonic rocks of the Paleozoics and of a sediment series which is penetrated by acid effusive rocks. The petrological composition of low grade metamorphosed sediments is separately dealt with. No fossils being available, the age of the sediments can only be defined as belonging to the period between Devonian and Permian time.

Resumen La poco conocida Cordillera Claudio Gay es una parte de la Precordillera en Chile septentrional. Su base se compone de masas intrusivas paleozóicas y de una serie sedimentaria cortada por rocas efusivas ácidas. La composición petrológica de los sedimentos y su cambio metamórfico son investigados en forma especial. La edad de los sedimentos solo puede ser calculada por la falta de fósiles entre el Devónico y el Pérmico.

, Claudio Gay, . - , , . . , .
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90.
Summary On the initiative of ProfessorR. Roelofs of the Delft Technological University and the financial support of the ‘Delft's Hogeschoolfonds’, a study was undertaken by the author concerning the reception and the use of radio time signals for the precise determination of the chronometer correction. As a result of this study an entirely new method featuring visual presentation and electronic enlargement of second ticks as transmitted by radio station WWV, was developed. Owing to the international importance of the problem, further development and actual construction of the necessary electronic equipment were carried out under the auspices of the Netherlands National Geodetic Committee, resulting in the Time Signal Oscillograph (TSO), which has now been in experimental use at the Geodetic Institute of the Delft Technological University since August 1953. The accuracy achieved by the new method is of the order of 1/1000 second, while errors and uncertainties due to atmospheric and/or man-made interference with the reception of the radio time signals have been practically eliminated. Operation of the instrument can be carried out by technically non-skilled persons, and direct reading of the chronometer correction in milleseconds is obtained. No identification is given of any particular second tick; however, this can be readily obtained by means of the standard tone modulation periods of the WWV radio station.  相似文献   
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