Schallausbreitung im Schlick     

Dipl.-Phys. Florian Schirmer 《Ocean Dynamics》1970,23(1):24-30

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Calcium isotope fractionation in calcite and aragonite   总被引：1，自引：0，他引：1  

Nikolaus Gussone  Florian Böhm  Martin Dietzel  Barbara M.A. Teichert  Gert Wörheide 《Geochimica et cosmochimica acta》2005,69(18):4485-4494

Calcium isotope fractionation was measured on skeletal aragonite and calcite from different marine biota and on inorganic calcite. Precipitation temperatures ranged from 0 to 28°C. Calcium isotope fractionation shows a temperature dependence in accordance with previous observations: 1000 · ln(α_cc) = −1.4 + 0.021 · T (°C) for calcite and 1000 · ln(α_ar) = −1.9 + 0.017 · T (°C) for aragonite. Within uncertainty the temperature slopes are identical for the two polymorphs. However, at all temperatures calcium isotopes are more fractionated in aragonite than in calcite. The offset in δ^44/40Ca is about 0.6‰. The underlying mechanism for this offset may be related to the different coordination numbers and bond strengths of the calcium ions in calcite and aragonite crystals, or to different Ca reaction behavior at the solid-liquid interface. Recently, the observed temperature dependence of the Ca isotope fractionation was explained quantitatively by the temperature control on precipitation rates of calcium carbonates in an experimental setting (Lemarchand et al., 2004). We show that this mechanism can in principle also be applied to CaCO₃ precipitation in natural environments in normal marine settings. Following this model, Ca isotope fractionation in marine Ca carbonates is primarily controlled by precipitation rates. On the other hand the larger Ca isotope fractionation of aragonite compared to calcite can not be explained by different precipitation rates. The rate control model of Ca isotope fractionation predicts a strong dependence of the Ca isotopic composition of carbonates on ambient CO₃²⁻ concentration. While this model is in general accordance with our observations in marine carbonates, cultured specimens of the planktic foraminifer Orbulina universa show no dependence of Ca-isotope fractionation on the ambient CO₃²⁻ concentration. The latter observation implies that the carbonate chemistry in the calcifying vesicles of the foraminifer is independent from the ambient carbonate ion concentration of the surrounding water.  相似文献   

Wide-angle observations of ALP 2002 shots on the TRANSALP profile: Linking the two DSS projects     

Florian Bleibinhaus  Ewald Brückl  ALP Working Group 《Tectonophysics》2006,414(1-4):71

Dynamite shots of the crustal-scale refraction seismic project ALP 2002 were recorded by an array of 40 seismological three-component stations on the TRANSALP profile. These observations provide a direct link between the two deep seismic projects. We report preliminary results obtained from these data. In a first approach, we verified the TRANSALP refraction seismic velocity model computing travel times for several shots and comparing them to the new observations. The results generally confirm this model. Significant first-break travel time differences in and near the Tauern Window are explained by anisotropy. Large-scale features of the model, particularly the Moho structure, seem to be continuous towards the east. Travel time residuals of wide-angle reflections indicate a slight eastward dip component of the Adriatic Moho.  相似文献   

Lateral variations in sediment composition and bedding in Middle Triassic interplatform basins (Buchenstein Formation, southern Alps, Italy)     

Florian Maurer  Wolfgang Schlager 《Sedimentology》2003,50(1):1-22

ABSTRACT Hemipelagic deposits are widespread in Triassic sequences of the Alpine belt and provide important data for stratigraphy and the study of bedding rhythms. The area of the western and central Dolomites of northern Italy escaped strong alpidic deformation and preserves such deposits in their original palaeogeographic setting. The Buchenstein Formation, the object of this study, was deposited in up to 1000 m deep, Middle Triassic interplatform basins, which extend over an area of 500 km² within the Dolomites. Excellent outcrops and volcaniclastic markers allow a detailed correlation of the formation in both laminated (anoxic) and bioturbated facies down to a bed scale, and show its relationship to coeval carbonate platforms. Correlation of lithostratigraphically well‐constrained intervals in the bioturbated facies reveal that lateral thickening and thinning of the deposits depends on the amount of shallow‐water debris in the succession and is a function of the distance to coeval carbonate platform sources. In the laminated background deposit, thickness variations in limestones and marls parallel the thickness variations in ash layers, and were caused by local redeposition of sediment on the basin floor. Lateral persistence of laminae indicates that bottom currents were weak in the Buchenstein basin, but were able to redeposit mud in a significant way. In the area around Seceda and Geisler (western Dolomites), a lateral transition from dark‐grey laminated to grey bioturbated to red bioturbated facies is observed, which is probably linked to local relief with different oxygenation conditions on the sea floor. A comparison shows that decimetre‐scale bedding is preserved in all facies types and that the bedding rhythm is partly the result of different cementation of the sediment during early diagenesis. Correlation of individual layers in the bioturbated facies reveals that beds are thicker and enriched in lime mud in the western part of the basin, and decrease in thickness and contain less micrite towards the east, further away from the main shallow‐water areas. Nearslope calciturbidites change gradually from distinct layers into lateral arrays of micrite nodules and bands further out in the basin. These observations point to a platform source of lime mud in the Buchenstein basin.  相似文献   

Stable isotope indicators of movement and residency for brown shrimp (<Emphasis Type="Italic">Farfantepenaeus aztecus</Emphasis>) in coastal Louisiana marshscapes     

Brian Fry  Donald M. Baltz  Mark C. Benfield  John W. Fleeger  Arian Gace  Heather L. Haas  Zoraida J. Quiñones-Rivera 《Estuaries and Coasts》2003,26(1):82-97

Brown shrimp (Farfantepenaeus aztecus) are an important commercial aquatic species experiencing loss of inshore marsh nursery habitat in coastal Louisiana. To study inshore brown shrimp movements and identify aspects of essential habitat important for sustaining brown shrimp populations, we collected juvenile brown shrimp in April and May 2000, the time of annual maximum brown shrimp abundance, in a small 1-km² marsh area on the central Louisiana coast. Drop sampling showed average shrimp densities of 1.6–2.4 m⁻² in shallow marsh ponds and seining indicated lower densities of 0.5–0.9 m⁻² in nearby shallow channel and open bay sites. Smaller shrimp (< 50 mm) fed disproportionately on benthic diatoms and small harpacticoid copepods, while large shrimp fed more frequently on larger-bodied amphipods and tanaids. We developed novel chemical approaches to estimate patterns of shrimp residency and movement using carbon and nitrogen stable isotopic determinations. Resident shrimp had isotopic values similar to average foods and showed consistent isotopic spacings between fast and slow turnover tissues. Residency was highest (47–55%) in ponds and shallow channel habitats and much less in open bays and deep channels (4–27%). There was sparse evidence for dietary specialization among individull shrimp. The results support the view that small 10–20 mm postlarval and juvenile brown shrimp arriving in estuaries from offshore waters continue movement through sub-optimal habitats (deep channels and open bays), but exhibit much less movement once an optimal habitat (marsh ponds or shallow channel margins) is reached. This study also indicated that combining estimates of shrimp densities, residency, growth rate, and mortality allows evaluation of the importance of different habitat types for shrimp production. Shallow ponds that in many ways resemble fertile aquaculture ponds appear to be hot spots for brown shrimp production, and coastal preservation and restoration efforts should focus on these areas as important for sustaining shrimp fisheries.  相似文献   

Uncertainties in Facies Proportion Estimation I. Theoretical Framework: The Dirichlet Distribution     

André Haas  Philippe Formery 《Mathematical Geology》2002,34(6):679-702

To simulate geological models comprising several litho-types—or facies—we need first to estimate their proportions, which are often poorly known. The corresponding uncertainties can be modelled using a Bayesian approach for inverting the multinomial distribution. The result obtained is known as the Dirichlet distribution. It can be simulated by decomposition into independent conditional distributions. Application of the model is extended to the case of nonstationary proportions and, with some approximation, to the case of correlated spatial data. The mathematical developments presented in the appendices provide a more precise and general definition of the distribution, several decomposition formulae into independent variables, the determination of remarkable stability properties, and the resulting consequences for the conditional and marginal distributions.  相似文献   

Designing Monitoring Programs to Effectively Evaluate the Performance of Natural Attenuation     

Todd H. Wiedemeier  Patrick E. Haas 《Ground Water Monitoring & Remediation》2002,22(3):124-135

Natural attenuation processes affect the fate and transport of organic compounds in many hydrologic systems. Over the last several years, regulatory agencies and environmental professionals have come to recognize the importance of these natural processes in effecting contaminant attenuation. When they are shown to be protective of human health and the environment, and when a well-designed monitoring program is in place to document the efficiency of these processes, they can be a valuable component of site remediation strategies.  相似文献   

Variations in organic geochemistry and lithology of a carbonate sequence deposited in a backplatform basin (Triassic, Hungary)     

Magdolna Hetnyi  Alice Brukner-Wein  Csand Sajg  Jnos Haas  Mria Hmor-Vid  Zsuzsanna Sznt  Mria Tth 《Organic Geochemistry》2002,33(12)

The variations in the organic matter quantity and quality were studied with respect to the mineral composition of the carbonate sequences accumulated on a gentle slope (Zl-1 well) and at the toe of the slope (Rzt-1 well) located between a Late Triassic carbonate platform and a backplatform basin. Parallel variations observed in mineral composition and organic geochemical features of the successions appeared to be controlled by the change in climate and by sea-level fluctuations. The repetitive sea-level changes resulted in a variation in the carbonate-rich basin facies and in the mineralogically heterogenous slope and toe-of-slope ones. According to Rock Eval pyrolysis, organic petrography and carbon isotope ratios, the immature organic matter is of predominantly marine origin and composed of mainly liptinites in both of the studied boreholes. The results of the GC and GC/MS analyses of the saturated hydrocarbon fractions of bitumens together with the composition of kerogen pyrolysates reveal a predominant algal input with a minor variable bacterial and subordinate terrestrial contribution for the Rzt-1 borehole. In the Zl-1 borehole a significantly higher proportion of the bacterial biomass contributed to the organic precursors. The δ¹³C values and the composition of the kerogen pyrolysates together with the results of the maceral analysis and GC data suggest a relatively higher, but moderate, higher plant derived contribution in the slope facies and at the top of the toe-of-slope facies. The elementary composition of kerogens and Rock Eval data display type II-S kerogen in the basin and the slope facies, and type I-II-S one in the toe-of-slope facies. Variations in the hydrogen content of the organic matter mainly reflect variations in the preservation conditions and in primary productivity. The presence of the 2,6,10,15,19-pentamethyleicosane and the extremely low pristane/phytane ratios indicate a relatively high methanogenic bacterial activity and strongly anoxic depositional conditions in the Rzt-1 well, especially in two most organic-rich toe-of-slope facies.  相似文献   

Estimation of phase center corrections for GLONASS-M satellite antennas   总被引：3，自引：3，他引：0  

Florian Dilssner  Tim Springer  Claudia Flohrer  John Dow 《Journal of Geodesy》2010,84(8):467-480

Driven by the comprehensive modernization of the GLONASS space segment and the increased global availability of GLONASS-capable ground stations, an updated set of satellite-specific antenna phase center corrections for the current GLONASS-M constellation is determined by processing 84 weeks of dual-frequency data collected between January 2008 and August 2009 by a worldwide network of 227 GPS-only and 115 combined GPS/GLONASS tracking stations. The analysis is performed according to a rigorous combined multi-system processing scheme providing full consistency between the GPS and the GLONASS system. The solution is aligned to a realization of the International Terrestrial Reference Frame 2005. The estimated antenna parameters are compared with the model values currently used within the International GNSS Service (IGS). It is shown that the z-offset estimates are on average 7 cm smaller than the corresponding IGS model values and that the block-specific mean value perfectly agrees with the nominal GLONASS-M z-offset provided by the satellite manufacturer. The existence of azimuth-dependent phase center variations is investigated and uncertainties in the horizontal offset estimates due to mathematical correlations and yaw-attitude modeling problems during eclipse seasons are addressed. Finally, it is demonstrated that the orbit quality benefits from the updated GLONASS-M antenna phase center model and that a consistent set of satellite antenna z-offsets for GPS and GLONASS is imperative to obtain consistent GPS- and GLONASS-derived station heights.  相似文献   

Landslides and increased debris-flow activity: A systematic comparison of six catchments in Switzerland     

Florian Frank  Christian Huggel  Brian W. McArdell  Andreas Vieli 《地球表面变化过程与地形》2019,44(3):699-712

An increase in debris-flow frequency is expected in steep Alpine catchments after the occurrence of a large landslide, such as a rock avalanche. Herein we describe changes in debris-flow activity following increases in sediment availability due to landslides, or accelerated rock-glacier movement, for five catchments in the Swiss Alps, the Spreitgraben, Schipfenbach, Bondasca, Riascio, and Dorfbach catchments. Documentation on debris-flow activity is available from both before and after the landslide that generated the new sediment deposits. Data from nearby meteorological stations were used to explore possible changes in rainfall activity, and how the intensity and duration of rainfall events may have changed. In all cases there was a considerable increase in debris-flows frequency for one to eight years following the landslide. The annual number of days with debris-flow activity following the landslide was similar to that observed for the Illgraben catchment, where many such landslides occur annually. No clear change in precipitation totals preceding debris flows was apparent for the Riascio catchment, suggesting that the increase in frequency of debris flows is related to the increase in the amount of sediment that can be readily mobilized. In the two cases where rainfall data were available on an hourly basis, no systematic changes in the intensity or duration of rainfall related to debris-flow triggering were apparent, as shown by the close-clustering of storms on the intensity-duration plots. Following the sediment-generating event, an initial and sudden increase of the sediment yield was observed, followed by a decrease over time towards pre-disturbance values. The response of the catchments appears to be related to the amount of debris-flow activity prior to the landslide: sediment yield from catchments with frequent debris flows prior to the landslide activity did not increase as dramatically as in catchments where debris-flow activity was less common prior to the landslide. © 2018 John Wiley & Sons, Ltd.  相似文献