Distribution patterns and stable carbon isotopic composition of alkanes and alkan-1-ols from plant waxes of African rain forest and savanna C3 species     

Angela Vogts  Heiko Moossen  Florian Rommerskirchen  Jürgen Rullkötter 《Organic Geochemistry》2009,40(10):1037-1054

Leaf wax components of terrestrial plants are an important source of biomass in the geological records of soils, lakes and marine sediments. Relevant to the emerging use of plant wax derived biomarkers as proxies for past vegetation composition this study provides key data for C₃ plants of tropical and subtropical Africa. We present analytical results for 45 savanna species and 24 rain forest plants sampled in their natural habitats. Contents and distribution patterns of long chain n-alkanes (n-C₂₅ to n-C₃₅) and n-alkan-1-ols (n-C₂₄ to n-C₃₄) as well as bulk and molecular carbon isotopic data are presented. The variations of the analysed parameters among different growth forms (herb, shrub, liana and tree) are small within the vegetation zones, whereas characteristic differences occur between the signatures of rain forest and savanna plants. Therefore, we provide averaged histogram representations for rain forest and savanna C₃ plants.The findings were compared to previously published data of typical C₄ grass waxes of tropical and subtropical Africa. Generally, trends to longer n-alkane chains and less negative carbon isotopic values are evident from rain forest over C₃ savanna to C₄ vegetation. For n-alkanols of rain forest plants the maximum of the averaged distribution pattern is between those of C₃ savanna plants and C₄ grasses. The averaged presentations for tropical and subtropical vegetation and their characteristics may constitute useful biomarker proxies for studies analysing the expansion and contraction of African vegetation zones.  相似文献   

Contrasting fluid evolution of granulite-facies marbles: implications for a high-T intermediate-P terrain in the Famatinian Range, San-Juan, Argentina     

Florian Gallien  Aberra Mogessie  Ernesto Bjerg  Sergio Delpino  Brigida Castro de Machuca 《Mineralogy and Petrology》2009,95(1-2):135-157

High-temperature, intermediate-pressure calc-silicate marbles occur in the granulite-facies terrain of the La Huerta Range in the Province of San Juan, NW-Argentina, in three bulk-compositional varieties: Type (1) dolomite-absent scapolite-wollastonite-grandite-clinopyroxene-quartz—calcite marbles; Type (2) diopside-forsterite-spinel-corundum—calcite marbles with dolomite exolution lamellae in calcite; Type (3) serpentinized forsterite-spinel-dolomite marbles. An isobaric cooling path from peak-metamorphic conditions of 860°C to 750°C at 6.5 kbar is inferred from scapolite-wollastonite-grandite reaction textures in Type (1) and is consistent with cooling after an advective heat input from related gabbroic and tonalitic intrusive bodies. Stable carbon and oxygen isotope geochemistry was used to decipher the fluid/rock evolution of the three marble types. An interpreted four-stage temperature-time-fluid flow path comprises: (1) infiltration of pre-peak-metamorphic fluids, depleted in δ¹⁸O, that caused a shift of primary sedimentary δ¹⁸O ratios to lower values (19.6–20.0); (2) syn-metamorphic fluid liberation from Type (1) marbles with evidence for processes close to batch devolatilization that caused a weak coupled ¹³C and ¹⁸O depletion during prograde metamorphism. A different devolatilization behaviour, close to Rayleigh fractionation, texturally associated with fold settings indicates that granulite-facies fluid flow was focused rather than pervasive; (3) H₂O-absent conditions were dominant when coronal grandite formed during incipient high-temperature isobaric cooling at the expense of scapolite and wollastonite in the Type (1) marbles; (4) intense post-peak- hydration of Type (2) and Type (3) marbles is the last recognizable metasomatic event. In combination, the three marble types record fluid infiltration both before and after the metamorphic peak.  相似文献   

Textural, chemical, and isotopic effects of late-magmatic carbonatitic fluids in the carbonatite–syenite Tamazeght complex, High Atlas Mountains, Morocco     

Michael A. W. Marks  Florian Neukirchen  Torsten Vennemann  Gregor Markl 《Mineralogy and Petrology》2009,97(1-2):23-42

Carbonatites of the Eocene Tamazeght complex, High Atlas Mountains, Morocco, consist of calciocarbonatites (alvikite and sövite dykes) and magnesiocarbonatites (diatreme breccias and dykes rocks). These are associated with ultramafic, shonkinitic, gabbroic to monzonitic and various foid syenitic silicate units. Stable and radiogenic isotope compositions for carbonatites and silicate rocks indicate that they share a common source in the mantle, although for some carbonatitic samples contamination with sedimentary rocks seems important. The observed isotopic heterogeneity is mainly attributed to source characteristics, fractional crystallization (accompanied by various degrees of assimilation), and late- to post-magmatic fluid–rock interaction. During the late fluid–rock interaction, Sr, Mn, and possibly also Fe were mobilized and redistributed to form secondary carbonate minerals in carbonatites. These fluids also penetrated into the adjacent syenitic rocks, causing enrichment in the same elements.  相似文献   

Variability and alterations of water temperatures across the Elbe and Danube River Basins     

Danijela Markovic  Ulrike Scharfenberger  Stefan Schmutz  Florian Pletterbauer  Christian Wolter 《Climatic change》2013,119(2):375-389

Climate change is predicted to be a major threat to river ecosystems in the 21st century, but long-term records of water temperature in streams and rivers are rare. This study uses long-term water temperature series from the Elbe and the Danube River Basin to quantify the variability, magnitude, and extent of temperature alterations at different time scales. The observed patterns in monthly and daily water temperatures have been successfully described through statistical models based on air temperature, river discharge and the North Atlantic Oscillation Index. These models reveal that air temperature variability describes more than 80 % of the total water-temperature variability, linking anticipated changes in water temperature mainly to those in air temperature. The North Atlantic Oscillation effect deteriorates with decreasing latitude, while the discharge effect becomes more important and increases with the increase in discharge amount. The detected water temperature alterations include a phase shift in spring warming of almost 2 weeks, an increase in the number of days with temperatures above 25 °C and an increase in the duration of summer heat stress. These findings underline a significant risk for fundamental changes in river ecosystems, specifically in disruption of established patterns in food-web synchrony, and may lead to significant distortions in community structure and composition.  相似文献   

Fast and easy method for seagrass monitoring: application of acoustic telemetry to precision mapping of Posidonia oceanica beds     

Descamp P  Holon F  Ballesta L  Guilbert A  Guillot M  Boissery P  Raimondino V  Deter J 《Marine pollution bulletin》2011,62(2):284-292

Posidonia oceanica is an endemic seagrass from the Mediterranean Sea. It is an indicator of water quality and of the ecological state of coastal ecosystems. The aim of this paper is to test acoustic telemetry for monitoring the position of P. oceanica meadow limits with varied types. After evaluating the accuracy of the system, we present results from a spatiotemporal survey of P. oceanica meadows on nine sites located on the French coast. The method has been demonstrated to be highly efficient for high precision underwater mapping regardless of meadow type, with 1 cm accuracy for a distance of 40 m between the base and the pointer. A temporal survey led at Cerbere-Banyuls shows a weak global progression of 4 m² (progression of 26 m² - regression of 22 m²) between 2006 and 2010. Finally, we discuss the cost and efficiency of this method, and wether it should be generalized for further studies.  相似文献   

Experimental identification of Ca isotopic fractionations in higher plants     

Florian Cobert  Pascale Bourgeade  Pierre-Marie Badot  Peter Stille 《Geochimica et cosmochimica acta》2011,75(19):5467-5482

Hydroponic experiments have been performed in order to identify the co-occurring geochemical and biological processes affecting the Ca isotopic compositions within plants. To test the influence of the Ca concentration and pH of the nutritive solution on the Ca isotopic composition of the different plant organs, four experimental conditions were chosen combining two different Ca concentrations (5 and 60 ppm) and two pHs (4 and 6). The study was performed on rapid growing bean plants in order to have a complete growth cycle. Several organs (root, stem, leaf, reproductive) were sampled at two different growth stages (10 days and 6 weeks of culture) and prepared for Ca isotopic measurements.The results allow to identify three Ca isotopic fractionation levels. The first one takes place when Ca enters the lateral roots, during Ca adsorption on cation-exchange binding sites in the apoplasm. The second one takes place when Ca is bound to the polygalacturonic acids (pectins) of the middle lamella of the xylem cell wall. Finally, the last fractionation occurs in the reproductive organs, also caused by cation-exchange processes with pectins. However, the cell wall structures of these organs and/or number of available exchange sites seem to be different to those of the xylem wall. These three physico-chemical fractionation mechanisms allow to enrich the organs in the light ⁴⁰Ca isotope. The amplitude of the Ca isotopic fractionation within plant organs is highly dependent on the composition of the nutritive solution: low pH (4) and Ca concentrations (5 ppm) have no effect on the biomass increase of the plants but induce smaller fractionation amplitudes compared to those obtained from other experimental conditions. Thus, Ca isotopic signatures of bean plants are controlled by the external nutritive medium. This study highlights the potential of Ca isotopes to be applied in plant physiology (to identify Ca uptake, circulation and storage mechanisms within plants) and in biogeochemistry (to identify Ca recycling, Ca content and pH evolutions in soil solutions through time).  相似文献   

Earthquakes in Switzerland and surrounding regions during 2010     

Nicholas Deichmann  John Clinton  Stephan Husen  Benjamin Edwards  Florian Haslinger  Donat Fäh  Domenico Giardini  Philipp Kästli  Urs Kradolfer  Stefan Wiemer 《Swiss Journal of Geoscience》2011,104(3):537-547

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2010. During this period, 407 earthquakes and 85 quarry blasts were detected and located in the region under consideration. With a total of only 19 events with M_L ≥ 2.5, the seismic activity in the year 2010 was below the average over the previous 35 years. The two most noteworthy earthquakes were the M_L 3.4 Barrhorn event near Sankt Niklaus (VS) and the M_L 3.0 event of Feldkirch, both of which produced shaking of intensity IV.  相似文献   

The metamorphic complex of Beloretzk, SW Urals, Russia — a terrane with a polyphase Meso- to Neoproterozoic thermo-dynamic evolution     

U. A. Glasmacher  W. Bauer  U. Giese  P. Reynolds  B. Kober  V. Puchkov  L. Stroink  A. Alekseyev  A. P. Willner 《Precambrian Research》2001,110(1-4)

An integrated geological study of the tectono-metamorphic evolution of the metamorphic complex of Beloretzk (MCB) which is part of the eastern Bashkirian mega-anticlinorium (BMA), SW Urals, Russia shows that the main lithological units are Neoproterozoic (Riphean and Vendian age) siliciclastic to carbonate successions. Granitic, syenitic and mafic intrusions together with subaerial equivalents comprise the Neo- and Mesoproterozoic magmatic rocks. The metamorphic grade ranges from diagenetic and very low grade in the western BMA to high-grade in the MCB. The N–S trending Zuratkul fault marks the change in metamorphic grade and structural evolution between the central and eastern BMA. Structural data, Pb/Pb-single zircon ages, ⁴⁰Ar/³⁹Ar cooling ages and the provenance signature of Riphean and Vendian siliciclastic rocks in the western BMA give evidence of Mesoproterozoic (Grenvillian) rifting, deformation and eclogite-facies metamorphism in the MCB and a Neoproterozoic (Cadomian) orogenic event in the SW Urals. Three pre-Ordovician deformation phases can be identified in the MCB. The first SSE-vergent, isoclinal folding phase (D₁) is younger than the intrusion of mafic dykes (Pb/Pb-single zircon: 1350 Ma) and older than the eclogite-facies metamorphism. High P/low T eclogite-facies metamorphism is bracketed by D₁ and the intrusion of the Achmerovo granite (Pb/Pb-single zircon: ≤970 Ma). An extensional, sinistral, top-down-to-NW directed shearing (D₂) is correlated with the first exhumation of the MCB. E-vergent folding and thrusting (D₃) occurred at retrograde greenschist-facies metamorphic conditions. The tremolite ⁴⁰Ar/³⁹Ar cooling age (718±5 Ma) of amphibolitic eclogite and muscovite ⁴⁰Ar/³⁹Ar cooling ages (about 550 Ma) of mica schists indicate that a maximum temperature of 500±50 °C was not reached during the Neoproterozoic orogeny. The style and timing of the Neoproterozoic orogeny show similarities to the Cadomian-aged Timan Range NW of the Polar Urals. Geochronological and thermochronological data together with the abrupt change in structural style and metamorphism east of the Zuratkul fault, suggest that the MCB is exotic with respect to the SE-margin of the East European Platform. Thus, the MCB is named the ‘Beloretzk Terrane’. Recognition of the ‘Beloretzk Terrane’ and the Neoproterozoic orogeny at the eastern margin of Baltica has important implications for Neoproterozoic plate reconstruction and suggests that the eastern margin of Baltica might have lain close to the Avalonian–Cadomian belt.  相似文献   

Age of intrusion and rapid cooling of the Frankenstein gabbro (Odenwald,SW-Germany) evidenced by40Ar/39Ar and single-zircon207Pb/206Pb measurements     

Herbert Kirsch Dipl.-Geol.  Dr. Bernd Kober  Prof. Dr. Hans Joachim Lippolt 《International Journal of Earth Sciences》1988,77(3):693-711

The Frankenstein gabbro complex in the northern Odenwald/FR Germany is one of the Hercynian plutonic bodies of the Saxothuringian zone in the Variscan belt.⁸⁷Sr/⁸⁶Sr isotopic investigations on pyroxene,⁴⁰Ar/³⁹Ar age determinations on hornblendes, plagioclases, biotites and pyroxenes and²⁰⁷Pb/²⁰⁶Pb dating on single zircon crystals have been carried out. The⁸⁷Sr/⁸⁶Sr initial ratio of the gabbro (0.70380) indicates uncontaminated derivation of the magma from the mantle. The results on hornblendes, plagioclases and zircons establish the isotopic age of intrusion and the mode of cooling. Pyroxene and biotite data indicate disturbed K-Ar systems of these minerals. The average ages of the hornblendes (363±7 Ma), of the plagioclases (359±3 Ma) and of the zircons (362 ±9 Ma) agree within the 1-sigma levels and constrain the early history of the plutonic intrusion at the turn from Devonian to Carboniferous times. These minerals must have been cooled below their closure temperatures within a time-interval shorter than the error margins of 10 Ma. The ages therefore are, unlike those of the neighbouring Bergsträßer Odenwald, not long-time cooling ages due to largescale and slow geological uplift of the crustal segment. Instead, they will closely estimate the time of intrusion of the Frankenstein pluton into a shallow crustal level. The hiatus of about 20 Ma compared to the average ages of the crystalline rocks of the Bergsträßer Odenwald in the south characterizes the mafic Frankenstein pluton as a separated unit of the Odenwald crystalline, and underlines the importance of the Carboniferous tectonic fault zone in-between. The present data set clearly demonstrates the importance of the applied combination of methods and techniques to constrain the history of intrusion and cooling of mafic plutonic rocks.  相似文献   

Empirical assessment of obstruction adaptive elevation masks to mitigate site-dependent effects     

Zimmermann  Florian  Eling  Christian  Kuhlmann  Heiner 《GPS Solutions》2017,21(4):1695-1706

GPS Solutions - Site-dependent effects are accuracy-limiting factors in static and kinematic GNSS-based positioning applications since they cannot be minimized using differential techniques. In...  相似文献