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131.
Bernard Henry Grobéty 《Contributions to Mineralogy and Petrology》1997,127(3):237-247
Anthophyllite crystals found in ultramafic lenses of the Lepontine Alps (Switzerland) contain coherent, submicroscopic intergrowths
of ordered and disordered biopyribole polysomes. The chain width distributions of disordered polysomes were analyzed using
high resolution transmission electron microscopy (HRTEM). Chains wider than triple were interpreted as intermediate products
in the transformation of anthophyllite to the triple chain silicate jimthompsonite. The concentration of individual chain
types is strongly correlated with the reaction progress. Based on observed zipper terminations and the transformation rules
given by Veblen and Buseck (1980) a scheme of possible reaction paths leading from anthophyllite to jimthomp sonite is proposed.
The reaction scheme and a simple kinetic model for elementary reactions allow modeling of the observed chain width distributions.
The model suggests that the complex reaction paths involving steps with increasing and decreasing chain width are more important
in the formation of jimthompsonite than the direct transformation from anthophyllite. The wide chains (>triple) occurring
as intermediate products of the multi-step paths are structurally closer to talc than jimthompsonite. The back-transformation
of these wide chains to triple chains is, therefore, a strong argument that jimthompsonite is a stable phase and not only
a metastable intermediate product in the transformation of anthophyllite to talc.
Received: 8 July 1996 / Accepted: 13 December 1996 相似文献
132.
Thierry Rolland Stéphanie Fayolle Arlette Cazaubon Stéphane Pagnetti 《Aquatic Sciences - Research Across Boundaries》1997,59(1):57-73
In a sub-alpine river, the Asse, with an unpredictable discharge regime, chlorophyll, density and taxonomic diversity of both
drifting and periphytic communities were studied from a methodical approach. The investigations based on stamping two close
cross-sections to know their spatial distributions in a heterogeneous bed substrate showed a heterogeneous pattern of colonization
mainly influenced by hydrological variables as the current velocity, the size of the substrata (gravel-pebble-boulder). For
the drifting algae, mainly composed with benthic species temporarily unhooked to the substrata, the heterogeneity of the distribution
was reduced in fast flow which induced a mixing of the whole mass of water.
For the periphyton, some results indicated that the greatest diversity and the highest chlorophyll concentration were found
on pebble substratum where the current velocity was moderate. These results have also shown that the classical methods used
to day for investigations were inadequate for most Mediterranean rivers.
It was really difficult to estimate the water quality from classical index created for use in regular large plain rivers. 相似文献
133.
Nils-Otto Kitterrød Lars Gottschalk 《Stochastic Environmental Research and Risk Assessment (SERRA)》1997,11(6):459-482
Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function.
This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients
from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance
model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns
out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of
eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the
2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance
function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields
with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial
interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the
predefined covariance functions are evaluated. 相似文献
134.
135.
Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function.
This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients
from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance
model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns
out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of
eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the
2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance
function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields
with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial
interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the
predefined covariance functions are evaluated. 相似文献
136.
Eric Barthélemy 《Surveys in Geophysics》2004,25(3-4):315-337
Ocean waves entering the near-shore zone undergo nonlinear and dispersive processes. This paper reviews nonlinear models, focusing on the so-called Serre equations. Techniques to overcome their limitations with respect to the phase speed are presented. Nonlinear behaviours are compared with theoretical results concerning the properties of Stokes waves. In addition, the models are tested against experiments concerning periodic wave transformation over a bar topography and of the shoaling of solitary waves on a beach. 相似文献
137.
Lake Fertõ/Neusiedler See is a steppe lake situated on the Hungarian-Austrian border with a surface area of 309 km2. It is an extremely shallow lake with regulated outflow. 54% of the whole lake and 85% of the Hungarian part (75 km2) is covered by reed. There are numerous reedless areas (inner ponds) of variable size within the reed belt, which is enmeshed with canals connecting the inner ponds with the open water areas. Fundamental differences were recorded in the water chemistry of the three water type areas, open water, canals and inner ponds. The degree of these differences is basically determined by the distance from the open water areas and the water level of the actual years. An extremely high, an average and an extremely low water level year was examined, in order to present the spatial and temporal differences in the water chemistry of the investigated water bodies. Differences due to the water level fluctuation between years in the three different water types are discussed on the basis of electrical conductivity, cation, and anion concentration changes of the water. Our results support the concept of high instability of Lake Fertõ and describe habitats with remarkable temporal and spatial variability. The high influence of water level on habitat conditions at different sites of the lake recommend a carefull water level regulation strategy. 相似文献
138.
We give some results obtained for the Couplex test cases proposed by the ANDRA. In this paper our aim is twofold. Firstly, to compute the release of nuclides out of the repository by concentrating on the 3D near field (Couplex 2). The simulation of the transport phenomena takes into account the dissolution of the glass containers and congruent emissions of the radio-nuclides including filiation chains and some simplified chemistry. Secondly, it is to use the near field computations in order to simulate the nuclide migrations in a 2D far field (Couplex 3). Coupling in between the two simulations takes into consideration the periodicity of the disposal modules and the geometry of the repository described in Couplex 1. The mixed finite element and discontinuous Galerkin methods are used to solve the convection–diffusion equations. In order to handle the nonlinear precipitation/dissolution term, we developed a new iterative technique that combines Picard and Newton–Raphson methods. 相似文献
139.
The COUPLEX1 Test case (Bourgeat et al., 2003) is devoted to the comparison of numerical schemes on a convection–diffusion–reaction problem. We first show that the results of the simulation can be mainly predicted by a simple analysis of the data. A finite volume scheme, with three different treatments of the convective term, is then shown to deliver accurate and stable results under a low computational cost. 相似文献
140.
Nicolas Domange Caroline Grégoire Véronique Gouy Michèle Tremolières 《Comptes Rendus Geoscience》2004,336(1):49-58
The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004). 相似文献