In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O     

Gennaro Ventruti  Giancarlo Della Ventura  Nicola Corriero  Daniele Malferrari  Alessandro F. Gualtieri  Umberto Susta  Maria Lacalamita  Emanuela Schingaro 《Physics and Chemistry of Minerals》2016,43(8):587-595

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   

Bioeconomic model for a three-zone Marine Protected Area: a case study of Medes Islands (northwest Mediterranean)     

Merino  Gorka; Maynou  Francesc; Boncoeur  Jean 《ICES Journal of Marine Science》2009,66(1):147-154

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The response of ostracod shell chemistry to seasonal change in a Mediterranean freshwater spring environment     

Guy Wansard  Francesc Mezquita 《Journal of Paleolimnology》2001,25(1):9-16

We established the relationships between water chemistry changes in a pool fed by a permanent spring and seasonal variations in trace-element contents (Sr & Mg) in the shells of the ostracod species Herpetocypris intermedia, based on monthly collections of ostracod and water samples. The water chemistry of the investigated pool (Maïques, Valëncia, Spain) was dominated by calcium and bicarbonate, and showed marked seasonal variation in alkalinity, Ca²⁺ content, Sr/Ca and Mg/Ca ratios. Although the variability in the water chemistry was relatively low (~10% relative standard deviation over the entire period), the trace-element contents in the ostracod shells tracked the seasonal change in the water chemistry of Maïques pool. Moreover, due to the rapid renewal of H. intermedia population, this species is able torecord in its shells the evolution of the water chemistry at a monthly time scale. Our results also showed that, in the Maïques pool system, ostracod Sr/Ca and Mg/Ca ratios increased with the decrease in water salinity.To our knowledge, this is the first geochemical study of ostracods dwelling in spring environments. The results of this study may be applied to paleohydrological reconstruction using ostracods preserved in sediments deposited around springs (i.e. travertine and tufa deposits).  相似文献   

Life history of the bathyal octopus Pteroctopus tetracirrhus (Mollusca,Cephalopoda) in the Mediterranean Sea     

Antoni Quetglas  Francesc Ordines  María González  Ignacio Franco 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(8):1379-1390

The life cycle of the deep-sea octopus Pteroctopus tetracirrhus was studied from monthly samples obtained throughout the year in different areas of the western Mediterranean (mainly around the Balearic Islands and along the coast of the Iberian Peninsula). A total of 373 individuals (205 females, 168 males) were analyzed; females ranged from 4.5 to 14.0 cm mantle length (ML) and males from 4.5 to 11.5 cm ML. There were few small-sized octopuses (<7 cm ML) in the samples, which might indicate that these individuals inhabit rocky grounds that are not accessible to trawlers or waters deeper than the maximum depth sampled (800 m). The species occurred more frequently around the Balearic Islands than along the Iberian Peninsula as they appeared in 20% and 7%, respectively, of the hauls in these areas. The octopus inhabits the lower continental shelf and upper slope in both areas, primarily between 200 and 500 m depth. Modal lengths were followed from autumn, when recruits were caught by trawlers, to summer, when reproduction took place. Females grew from 8 to 10 cm ML from winter to spring, but this modal size did not increase further in summer; males grew from 7 to 9 cm ML from winter to spring. The total disappearance of large individuals after summer suggests a life cycle lasting a single year. The evolution of the monthly mean sizes showed that the growth was best described by log-linear functions in both sexes. The length at first maturity was clearly higher in females (12 cm ML) than in males (8 cm ML). A total of 30 different prey items, belonging to four major taxonomic groups (crustaceans, osteichthyes, cephalopods and gastropods), were identified in the stomach contents. The diet of the octopus was based on crustaceans and teleosts, which accounted for 75% and 23% of the prey items, respectively. Cephalopods and gastropods were accessory prey as they only represented 1.6% and 0.7%, respectively, of the total. The octopus showed a marked preference for the benthic fish Symphurus nigrescens and the endobenthic crustacean Alpheus glaber. The bathymetric distribution of P. tetracirrhus coincides with those of these two main prey, which suggests that the distribution of the octopus might be strongly linked to its trophic resources.  相似文献   

Application of the SHETRAN basin‐scale,landslide sediment yield model to the Llobregat basin,Spanish Pyrenees     

James C. Bathurst  Aidan Burton  Barry G. Clarke  Francesc Gallart 《水文研究》2006,20(14):3119-3138

The first application of the SHETRAN basin‐scale, landslide erosion and sediment yield model is carried out for a major landsliding event in the upper 505 km² of the Llobregat basin, in the eastern Spanish Pyrenees, in November 1982. The model simulates the spatial distribution of shallow landslides and their sediment yield. Acknowledging uncertainty in the model parameter evaluation, the aim of the application was not to reproduce the observed occurrence of landslides as accurately as possible with one simulation, but to bracket the observed pattern with several simulations representing uncertainty in the key input conditions. Bounds on the landslide simulations were thus determined as a function of uncertainty in the vegetation root cohesion (used in the model factor of safety calculations). The resulting upper bound considerably overestimates the observed pattern (17 000 landslides compared with an observation of around 700), but it reproduces several of the principal clusters in the observed pattern. The lower bound contains around 500 landslides. The sediment yield estimates (2670–14 630 t km^?2) are comparable to measurements elsewhere in the Pyrenees for extreme events. The results demonstrate an ability to simulate the basin‐scale landslide response to a rainfall event and the resulting sediment yield. They also highlight the need for further research in setting the uncertainty bounds and in avoiding large overestimates of landslide occurrence arising in part from a current inability to model small‐scale controls for a basin of the given size. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

The role of the equation of state in models of very low-mass stars     

Marcella Di Criscienzo  Paolo Ventura  Francesca D’Antona 《Astrophysics and Space Science》2010,328(1-2):167-169

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The role of lithology,catchment size and the alluvial zone on the hydrogeochemistry of two intermittent Mediterranean streams     

Susana Bernal  Francesc Sabater 《水文研究》2008,22(10):1407-1418

Hydrology and solute concentrations of two intermittent Mediterranean streams draining two nested catchments were compared. The two catchments were mainly underlain by granitic rocks and different types of sericitic schists. Only the lowland catchment had an alluvial zone and a well‐developed riparian forest. The rainfall–runoff relationship and the correlation between daily flow concentrations showed that hydrological behaviour was similar at both sites during most of the year. However, reverse fluxes were detected during the wetting and drying up periods only in the stream with an alluvial zone. The intermittence in stream flow also had effects on absolute solute concentrations, temporal solute dynamics and streamwater stoichiometry. Streamwater chemistry was not affected by drainage area, except for cations produced mainly by bedrock dissolution (i.e. calcium and magnesium) that increased with increasing catchment size. Differences in the relationship among cations and anions were detected between the two streams, which could be attributed to biogeochemical processes occurring in the alluvial zone. The multivariate model used in this study showed that stoichiometry was more useful than absolute concentrations when analyzing the influence of different lithologies on streamwater chemistry. Such differences were amplified in autumn, likely due to a low hydrological connectivity between the two nested catchments. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Restrictions on the short time constant astrophysics     

G. Cavallo  A. Ventura 《Astrophysics and Space Science》1972,19(2):431-439

The comparatively new field of short time-constant astrophysics is investigated with the aim of checking the statement that there is a maximum amount of electromagnetic energy which can be radiated at a frequencev _m by an object whose size isL and during a time Δτ. Such limits are found under the assumptions that the emission is isotropic, thatL?cΔτ, and for the following four radiation mechanisms: incoherent synchrotron radiation, synchrotron maser, antenna radiation and for one simple case of radiation by a turbulent plasma. These limits are compared and found to be consistent with experimental data referring to the Sun, the pulsar NP 0532, the Quasar 3C 273 and the Seyfert galaxy NGC 4151. The main conclusion is that extragalactic radio astronomy at the present sensitivity level of observations is not likely to allow for the detection of pulses lasting less than 0.1 s.  相似文献   

Quantum theory of the dielectric constant of a magnetized plasma and astrophysical applications     

V. Canuto  J. Ventura 《Astrophysics and Space Science》1972,18(1):104-120

A quantum mechanical treatment of an electron plasma in a constant and homogeneous magnetic field is considered, with the aim of (a) defining the range of validity of the magnetoionic theory (b) studying the deviations from this theory, in applications involving high densities, and intense magnetic field. While treating the magnetic field exactly, a perturbation approach in the photon field is used to derive general expressions for the dielectric tensor . The properties of are explored in the various limits. Numerical estimates on the range of applicability of the magnetoionic theory are given for the case of the one-dimensional electron gas, where only the lowest Landau level is occupied.  相似文献   

Diffuse CO<Subscript>2</Subscript> degassing at Vesuvio,Italy   总被引：1，自引：0，他引：1  

Francesco?FrondiniEmail author  Giovanni?Chiodini  Stefano?Caliro  Carlo?Cardellini  Domenico?Granieri  Guido?Ventura 《Bulletin of Volcanology》2004,66(7):642-651

At Vesuvio, a significant fraction of the rising hydrothermal–volcanic fluids is subjected to a condensation and separation process producing a CO₂–rich gas phase, mainly expulsed through soil diffuse degassing from well defined areas called diffuse degassing structures (DDS), and a liquid phase that flows towards the outer part of the volcanic cone. A large amount of thermal energy is associated with the steam condensation process and subsequent cooling of the liquid phase. The total amount of volcanic–hydrothermal CO₂ discharged through diffuse degassing has been computed through a sequential Gaussian simulation (sGs) approach based on several hundred accumulation chamber measurements and, at the time of the survey, amounted to 151 t d^–1. The steam associated with the CO₂ output, computed assuming that the original H₂O/CO₂ ratio of hydrothermal fluids is preserved in fumarolic effluents, is 553 t d^–1, and the energy produced by the steam condensation and cooling of the liquid phase is 1.47×10¹² J d^–1 (17 MW). The location of the CO₂ and temperature anomalies show that most of the gas is discharged from the inner part of the crater and suggests that crater morphology and local stratigraphy exert strong control on CO₂ degassing and subsurface steam condensation. The amounts of gas and energy released by Vesuvio are comparable to those released by other volcanic degassing areas of the world and their estimates, through periodic surveys of soil CO₂ flux, can constitute a useful tool to monitor volcanic activity.Editorial responsibility: H. Shinohara  相似文献