Multi-methodological investigation of kunzite, hiddenite, alexandrite, elbaite and topaz, based on laser-induced breakdown spectroscopy and conventional analytical techniques for supporting mineralogical characterization     

Manuela Rossi  Marcella Dell’Aglio  Alessandro De Giacomo  Rosalba Gaudiuso  Giorgio Saverio Senesi  Olga De Pascale  Francesco Capitelli  Fabrizio Nestola  Maria Rosaria Ghiara 《Physics and Chemistry of Minerals》2014,41(2):127-140

Gem-quality alexandrite, hiddenite and kunzite, elbaite and topaz minerals were characterized through a multi-methodological investigation based on EMPA-WDS, LA-ICP-MS, and laser-induced breakdown spectroscopy (LIBS). With respect to the others, the latter technique enables a simultaneous multi-elemental composition without any sample preparation and the detection of light elements, such as Li, Be and B. The criteria for the choice of minerals were: (a) the presence of chromophore elements in minor contents and/or as traces; (b) the presence of light lithophile elements (Li, Be and B); (c) different crystal chemistry complexity. The results show that LIBS can be employed in mineralogical studies for the identification and characterization of minerals, and as a fast screening method to determine the chemical composition, including the chromophore and light lithophile elements.  相似文献   

Time-course evaluation of ROS-mediated toxicity in mussels, Mytilus galloprovincialis, during a field translocation experiment     

Giada Frenzilli  Raffaella Bocchetti  Massimiliano Pagliarecci  Marco Nigro  Francesca Annarumma  Vittoria Scarcelli  Daniele Fattorini  Francesco Regoli   《Marine environmental research》2004,58(2-5):609

Harbours can be considered as model environments for developing and validating field monitoring procedures and to investigate mechanistic relationships between different biological responses. In this study several biomarkers were investigated in marine mussels caged for 4 weeks (June–July 2001) into an industrialized harbour of NW Italy. Organisms were collected at different time-intervals to better characterize the sensitivity, temporal variations and interactions of analysed responses. Besides single antioxidants the total oxyradical scavenging capacity (TOSC) assay was used to analyse the capability of the whole antioxidant system to neutralize specific forms of radicals: these data were further integrated by measurement of DNA integrity, oxidized bases and the impairment of lysosomal membrane stability in haemocytes. Results showed a biphasic trend for single antioxidants and TOSC, with an increase during the first 2 weeks of exposure to the polluted site followed by a progressive decrease up to a severe depletion in the final part of the experiment.  相似文献   

Rhythms of feeding activity and food consumption of two Mediterranean burrowing fishes: Gnathophis mystax (Delaroche) and Chlopsis bicolor Rafinesque     

Paolo Carpentieri  Francesco Colloca  & Giandomenico Ardizzone 《Marine Ecology》2007,28(4):487-495

Data on the food consumption, feeding activity and periodicity of two burrowing fish, the congrid eel Gnathophis mystax (Delaroche, 1809) and the false moray Chlopsis bicolor Rafinesque, 1810 are presented. In all, 455 specimens were collected by bottom trawl in the central Mediterranean Sea at depths ranging from 140 to 160 m during four 24‐h day–night sampling cycles. The diet of G. mystax and C. bicolor was investigated by means of stomach content analysis. Diet varied significantly with length and maturity stage. During ontogenetic development G. mystax occupied different trophic levels: diet shifted from amphipods, predominantly in the smaller congrid eels [<25 cm total length (TL)] to fish in the larger individuals (>30 cm TL). Before the transition to the icthyophagous phase, the congrid eel showed a more generalistic foraging behaviour where decapods (Solenocera membranacea, Parapenaeus longirostris, Alpheus glaber), cephalopods (Sepiola spp. and Alloteuthis media), benthic (Gobiidae, Callionymus maculatus, Arnoglossus laterna) and benthopelagic fish (Argentina sphyraena) dominated the diet. Smaller C. bicolor (<25 cm TL) fed primarily on amphipods and cephalopods; bigger specimens fed also on decapods both natantian (A. glaber, Processa canaliculata) and reptantian (Medorippe lanata, Goneplax rhomboides). Daily ration values, computed from the Eggers method, ranged from 2.48% to 2.99% wet body weight for C. bicolor and G. mystax, respectively. Diel patterns in stomach fullness and the trophic niche overlap between the two species were also discussed.  相似文献   

Characterization of the atmosphere above a site for millimeter wave astronomy     

Francesco Tony Nasir  Franco Buffa  Gian Luigi Deiana 《Experimental Astronomy》2011,29(3):207-225

The Sardinia Radio Telescope (SRT) is a challeging scientific project managed by the National Institute for Astrophysics (INAF), it is being developed at 30 km North of the city of Cagliari, Italy. The goal of the SRT project is to build a general purpose, fully steerable, 64 m diameter radio telescope, capable of operating with high efficiency in the centimeter and millimeter frequency range (0.3–100 GHz). In portions of this frequency range, especially towards the high end, astronomical observations can be heavily deteriorated by non-optimal atmospheric conditions, especially by water vapor content. The water molecule permanent electric dipole in fact, leads to pressure broadened rotational transitions around the 22.23 GHz spectral line. Furthermore, water vapor’s continuum absorption and emission may influence higher frequency observations too. To a lower degree, cloud liquid black body radiation can also affect centimeter and millimeter observations. In addition to this, inhomogeneities in water vapor distributions can cause signal phase errors which introduce a great amount of uncertainty to VLBI mode observations. The Astronomical Observatory of Cagliari (OA-CA) has obtained historical timeseries of radiosonde profiles conducted at the airport of Cagliari. Through the radiosonde measurements and an appropriate radiative transfer model, we have performed a statistical analysis of the SRT site’s atmosphere which accounts for atmospheric opacity at different frequencies, integrated water vapor (IWV), integrated liquid water (ILW) and cloud cover distributions during the year. This will help to investigate in which period of the year astronomical observations at different frequencies should be performed preferably. The results show that, at the SRT site, K-band astronomical observations are possible all year round, the median opacity at 22.23 GHz is 0.10 Np in the winter (Dec-Jan-Feb) and 0.16 Np in the summer (Jun-Jul-Aug). Integrated water vapor during winter months ranges, on average, between 7 and 15 mm. Cloud cover is usually not present for more than 36% of the time during the year. The atmospheric opacity study indicates that observations at higher frequencies (50–100 GHz) may be performed usefully: the median opacity at 100 GHz is usually below or equal to 0.2 Np in the period that ranges from January to April.  相似文献   

COCHISE: the first light of the Italian millimetre telescope at Concordia (Dome C, Antarctica)     

Lucia Sabbatini  Francesco Cavaliere  Giorgio Dall’Oglio  Antonio Miriametro  Licia Pizzo  Dario Mancini  Guido Torrioli 《Experimental Astronomy》2011,31(2-3):199-214

COCHISE (Cosmological Observations at Concordia with High-sensitivity Instrument for Source Extraction) is a 2.6 m telescope located on the high Antarctic Plateau near the Italian–French Concordia Base. The telescope is mainly devoted to Cosmological observations, able to operate between 200 μm and 3 mm of wavelength. In this paper we describe the main characteristics of the instrument. We also report on the first light, obtained during summer 2010–2011: this result marks the beginning of millimetre astrophysical observations at Concordia. Responsivity, noise equivalent temperature and field of view of the instrument are reported. At present COCHISE is the largest telescope located at Concordia. Beside the scientific expectations, the use of this kind of instrument in the Antarctic environment poses technological aspects of relevant interest: thus COCHISE can be considered as a pathfinder for future Antarctic telescopes.  相似文献   

Photometric study and preliminary elements of the low-mass ratio W UMa system ASAS 021209+2708.3     

Francesco Acerbi  Carlo Barani  Massimiliano Martignoni 《中国天文和天体物理学报》2011,(7)

We present CCD B and V light curves,obtained in the year 2006,and a photometric solution of the low-mass ratio contact binary ASAS 021209+2708.3. With our data we were able to determine six new times of minimum light and refine the orbital period of the system to 0.3181963 days.The light curves are analyzed using the 2003 version of the Wilson-Devinney program and the analysis was performed with and without adding a spot on the surface of one star because the light curves appear to exhibit a typical O’Conne...  相似文献   

Trends and variability of ocean waves under RCP8.5 emission scenario in the Mediterranean Sea     

De Leo  Francesco  Besio  Giovanni  Mentaschi  Lorenzo 《Ocean Dynamics》2021,71(1):97-117

Ocean Dynamics - Wind-generated ocean waves are key inputs for several studies and applications, both near the coast (coastal vulnerability assessment, coastal structures design, harbor...  相似文献   

Redistribution of riverine and rainfall freshwater by the Bay of Bengal circulation     

Chaitanya  Akurathi Venkata Sai  Vialard  Jérôme  Lengaigne  Matthieu  d’Ovidio  Francesco  Riotte  Jean  Papa  Fabrice  James  Rathinam Arthur 《Ocean Dynamics》2021,71(11-12):1113-1139

Ocean Dynamics - We use satellite-derived currents and a Lagrangian approach to investigate the redistribution of the precipitation minus evaporation (P-E) and river freshwater inputs into Bay of...  相似文献   

Dielectric constant estimation of the uppermost Basal Unit layer in the martian Boreales Scopuli region     

Sebastian E. Lauro  Elisabetta Mattei  Francesco Soldovieri  Elena Pettinelli  Roberto Orosei  Giuliano Vannaroni 《Icarus》2012,219(1):458-467

An electromagnetic inversion model has been applied to echoes from the subsurface sounding Shallow Radar (SHARAD) to retrieve the dielectric properties of the uppermost Basal Unit (BU) beneath the North Polar Layered Deposits of Mars. SHARAD data have been carefully selected to satisfy the assumption of the inversion model which requires a stratigraphy consisting of mostly plane parallel layers. The resulting values of the dielectric constant have been interpreted in terms of a variable percentage of dust in an ice–dust mixture through the use of a mixing model for dielectric properties. The resulting dust content exceeds 65%, reaching perhaps 95%, depending on the permittivity values assumed for the dust. Such a concentration is higher than that obtained by Selvans et al. (Selvans, M.M., Plaut, J.J., Aharonson, O. [2010]. J. Geophys. Res, 115, E09003). This discrepancy could be justified considering that our observations refer to the uppermost BU layer, whereas Selvans et al. (Selvans, M.M., Plaut, J.J., Aharonson, O. [2010]. J. Geophys. Res, 115, E09003) probed the BU full thickness. Moreover, if the BU is considered spatially inhomogeneous, with very different dust content and thickness (Tanaka, K.L., Skinner, J.A., Fortezzo, C.M., Herkenhoff, K.E., Rodriguez, J.A.P., Bourke, M.C., Kolb, E.J., Okubo, C.H. [2008]. Icarus, 196, 318–358), the discrepancy could be furtherly reconciled.  相似文献   

Refractory Metal Nuggets – Formation of the first condensates in the Solar Nebula     

Kurt Liffman  Francesco C. Pignatale  Sarah Maddison  Geoffrey Brooks 《Icarus》2012,221(1):89-105

As gas flowed from the solar accretion disk or Solar Nebula onto the proto-Sun, magnetic pressure gradients in the solar magnetosphere and the inner Solar Nebula provided an environment where some of this infalling flow was diverted to produce a low pressure, high temperature, gaseous, “infall” atmosphere around the inner Solar Nebula. The pressure in this inner disk atmosphere was mainly dependant on the accretion flow rate onto the star. High flow rates implied relatively high pressures, which decreased over time as the accretion rate decreased.In the first hundred thousand years after the formation of the Solar Nebula, accretional flow gas pressures were high enough to create submicron-sized Refractory Metal Nuggets (RMNs) – the precursors to Calcium Aluminum Inclusions (CAIs). Optimal temperatures and pressures for RMN formation may have occurred between 20,000 and 100,000 years after the formation of the Solar Nebula. It is possible that conditions were conducive to RMN/CAI formation over an 80,000 year timescale. The “infall” atmosphere and the condensation of refractory particles within this atmosphere may be observable around the inner disks of other protostellar systems.The interaction of forces from magnetic fields with the radiation pressure from the proto-Sun and the inner solar accretion disk potentially produced an optical-magnetic trap above and below the inner Solar Nebula, which provided a relatively stable environment in which the RMNs/proto-CAIs could form and grow. These RMN formation sites only existed during accretion events from the proto-solar disk onto the proto-Sun. As such, the formation and growth time of a particular RMN was dependent on the timescale of its nascent accretion event.Observational evidence suggests that RMNs were the nucleation particles for CAIs. As a consequence, the observed bimodal distribution of ²⁶Al in CAIs, where some CAIs have ²⁶Al while others do not, is probably due to the injection ²⁶Al during the short CAI formation period, where ²⁶Al was not present when the first CAIs were formed.  相似文献