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71.
Martins CC Bícego MC Mahiques MM Figueira RC Tessler MG Montone RC 《Marine pollution bulletin》2011,63(5-12):452-458
Located in southeastern Brazil, the Santos Estuary has the most important industrial and urban population area of South America. Since the 1950's, increased urbanization and industrialization near the estuary margins has caused the degradation of mangroves and has increased the discharge of sewage and industrial effluents. The main objectives of this work were to determine the concentrations and sources of polycyclic aromatic hydrocarbons (PAHs) in sediment cores in order to investigate the input of these substances in the last 50 years. The PAHs analyses indicated multiple sources of these compounds (oil and pyrolitic origin), basically anthropogenic contributions from biomass, coal and fossil fuels combustion. The distribution of PAHs in the cores was associated with the formation and development of Cubat?o industrial complex and the Santos harbour, waste disposal, world oil crisis and the pollution control program, which results in the decrease of organic pollutants input in this area. 相似文献
72.
Traditionally, the application of stable isotopes in Carbon Capture and Storage (CCS) projects has focused on δ13C values of CO2 to trace the migration of injected CO2 in the subsurface. More recently the use of δ18O values of both CO2 and reservoir fluids has been proposed as a method for quantifying in situ CO2 reservoir saturations due to O isotope exchange between CO2 and H2O and subsequent changes in δ18OH2O values in the presence of high concentrations of CO2. To verify that O isotope exchange between CO2 and H2O reaches equilibrium within days, and that δ18OH2O values indeed change predictably due to the presence of CO2, a laboratory study was conducted during which the isotope composition of H2O, CO2, and dissolved inorganic C (DIC) was determined at representative reservoir conditions (50 °C and up to 19 MPa) and varying CO2 pressures. Conditions typical for the Pembina Cardium CO2 Monitoring Pilot in Alberta (Canada) were chosen for the experiments. Results obtained showed that δ18O values of CO2 were on average 36.4 ± 2.2‰ (1σ, n = 15) higher than those of water at all pressures up to and including reservoir pressure (19 MPa), in excellent agreement with the theoretically predicted isotope enrichment factor of 35.5‰ for the experimental temperatures of 50 °C. By using 18O enriched water for the experiments it was demonstrated that changes in the δ18O values of water were predictably related to the fraction of O in the system sourced from CO2 in excellent agreement with theoretical predictions. Since the fraction of O sourced from CO2 is related to the total volumetric saturation of CO2 and water as a fraction of the total volume of the system, it is concluded that changes in δ18O values of reservoir fluids can be used to calculate reservoir saturations of CO2 in CCS settings given that the δ18O values of CO2 and water are sufficiently distinct. 相似文献
73.
Kord Ernstson Werner Mayer Andreas Neumair Dirk Sudhaus 《Central European Journal of Geosciences》2011,3(4):385-397
Sudden collapse of the Quaternary soil to form sinkholes on the order of meters and tens of meters has been a geologic phenomenon within living memory in a localized area north of Lake Chiemsee in Southeast Germany. Failing a satisfying explanation, a relation with an undefined glaciation process has always been proposed. Excavations and geophysical measurements at three newly affected sites show underground features such as prominent sandy-gravelly intrusions and extrusions typical of rock liquefaction processes well known to occur during strong earthquakes. Since strong earthquakes can reasonably be excluded to have affected the area under discussion, it has been suggested that the observed widespread liquefaction is related with the recently proposed Holocene Chiemgau meteorite impact event. Except for one earlier proposed but unassertive relation between impact and liquefaction, the obviously direct association of both processes in the Chiemgau area emphasizes that observed paleoliquefaction features need not necessarily have originated solely from paleoseismicity but can provide a recognizable regional impact signature. 相似文献
74.
Allan T. Souza Martina I. Ilarri Joana Campos João C. Marques Irene Martins 《Estuarine, Coastal and Shelf Science》2011
The present study compared the carapace structure of Carcinus maenas in two nearby sites (2 km apart) within Minho estuary, submitted to different physicochemical and ecological conditions (water temperature, pH, crabs’ density and sex ratio). The carapace structure of the carapace and chelae of the crabs presented significant differences between sampling sites (t-test; p < 0.01). The SIMPER analysis revealed that the Weight/CW and Thickness/CW ratios explained all the dissimilarities found among sites. Overall, the male carapace was proportionally thicker at station 2 (t-test; p < 0.01), while the female carapace was proportionally thicker at station 1 (t-test; p < 0.001). A thicker carapace can be advantageous when competing for food or a sexual partner. We hypothetized that, since at station 2, the density of individuals was twice higher than at station 1, it is likely that agonistic encounters are more frequent, thus favouring a thicker carapace. 相似文献
75.
A model describing macroalgal early life stages and adult dynamics was used to quantify the effects of non-adult forms on the productivity of adult macroalgae in a eutrophic estuary. Predictions indicate that during years with mild winters and low rainfall, spring blooms will occur at the expense of the growth and reproduction of overwintering adults and without the contribution of the spore bank. In these circumstances, there is a positive correlation between the intensity of the blooms and the biomass of overwintering adults until a maximum threshold value. On the contrary, in years with high rainfall and low or inexistent biomass of overwintering adults, the onset of adult’s growth depends on the biomass of viable dormant spores, the growing season occurs later and adult productivity is very limited. Long-term predictions for climate change scenarios suggest that, in general, global warming will have adverse affects on Ulva intestinalis productivity, with the adults being more affected than the early life stages. 相似文献
76.
The two-dimensional barotropic, hydrodynamic and transport model MOHID is applied to the Patos Lagoon system using a nested modelling approach to reproduce both the lagoon and estuary hydrodynamics. A new Lagrangian oil spill model is presented and used to simulate a hypothetical oil spill in the estuary. Hydrodynamic fields are validated and used to force the oil model. Results show that the hydrodynamics of this system is mainly controlled by the wind and freshwater discharge. The dispersion, concentration and thickness evolution of the oil in the first day after the spill is determined by the equilibrium between these two factors. The freshwater discharge is the major factor controlling the oil dispersion for discharges greater than 5000 m3 while the wind assumes control for lower discharge amounts. The results presented are a first step toward a coastal management tool for the Patos Lagoon. 相似文献
77.
Martins CC Ferreira JA Taniguchi S Mahiques MM Bícego MC Montone RC 《Marine pollution bulletin》2008,56(7):1359-1363
78.
Todd A. Surovell Nicole M. Waguespack James H. Mayer Marcel Kornfeld George C. Frison 《Geoarchaeology》2005,20(6):627-649
Shallowly buried archaeological sites are particularly susceptible to surface and subsurface disturbance processes. Yet, because cultural deposition often operates on short time scales relative to geologic deposition, vertical artifact distributions can be used to clarify questions of site formation. In particular, patterns in artifact distributions that cannot be explained by occupation histories must be explained by natural processes that have affected sites. Buried only 10–50 cm beneath the ground surface for 10,450 14C yr, the Folsom component at Barger Gulch Locality B (Middle Park, Colorado) exhibits many signs of post‐depositional disturbance. Through examination of variation in the vertical distribution of the artifact assemblage, we are able to establish that only a Folsom component is present. Using vertical artifact distributions, stratigraphy, and radiocarbon dating, we are able to reconstruct the series of events that have impacted the site. The Folsom occupation (˜10,450 14C yr B.P.) was likely initially buried in a late‐Pleistocene eolian silt loam. Erosion brought the artifacts to rest on a deflation surface at some time prior to 9400 14C yr B.P. A mollic epipedon formed in sediments that accumulated between 9400 and 7000 14C yr B.P. Some time after 5200 14C yr B.P., this soil was partially truncated, and artifacts that had previously dispersed upward created a secondary lag at its upper contact. This surface was buried again and artifact dispersal continued. © 2005 Wiley Periodicals, Inc. 相似文献
79.
Nitrogen uptake and denitrification in restored and unrestored streams in urban Maryland, USA 总被引:2,自引:0,他引:2
Carolyn A. Klocker Sujay S. Kaushal Peter M. Groffman Paul M. Mayer Raymond P. Morgan 《Aquatic Sciences - Research Across Boundaries》2009,71(4):411-424
There is growing interest in rates of nitrate uptake and denitrification in restored streams to better understand the effects
of restoration on nitrogen processing. This study quantified nitrate uptake in two restored and two unrestored streams in
Baltimore, Maryland, USA using nitrate additions, denitrification enzyme assays, and a 15N isotope tracer addition in one of the urban restored streams, Minebank Run. Restoration included either incorporation of
stormwater ponds below a storm drain and catch basins to attenuate flow or hydrologic “reconnection” of a stream channel to
its floodplain. Stream restoration was conducted for restoring aging sanitary and bridge infrastructure and introducing some
stormwater management in watersheds developed prior to current regulations. Denitrification potential in sediments was variable
across streams, whereas nitrate uptake length appeared to be significantly correlated to surface water velocity, which was
low in the restored streams during summer baseflow conditions. Uptake length of NO3
−–N in Minebank Run estimated by 15N tracer addition was 556 m. Whole stream denitrification rates in Minebank Run were 153 mg NO3
−–N m−2 day−1, and approximately 40% of the daily load of nitrate was estimated to be removed via denitrification over a distance of 220.5 m
in a stream reach designed to be hydrologically “connected” to its floodplain. Increased hydrologic residence time in Minebank
Run during baseflow likely influenced rates of whole stream denitrification, suggesting that hydrologic residence time may
be a key factor influencing N uptake and denitrification. Restoration approaches that increase hydrologic “connectivity” with
hyporheic sediments and increase hydrologic residence time may be useful for stimulating denitrification. More work is necessary,
however, to examine changes in denitrification rates in restored streams across different seasons, variable N loads, and in
response to the “flashy” hydrologic flow conditions during storms common in urban streams. 相似文献
80.
Study of Metal Distribution in Raw and Screened Swine Manure 总被引:1,自引:0,他引:1
Ricardo Luís Radis Steinmetz Airton Kunz Valderi Luiz Dressler Érico Marlon de Moraes Flores Ayrton Figueiredo Martins 《洁净——土壤、空气、水》2009,37(3):239-244
The growth of industrial swine production over the last few years has led to a growth in concern over effluents generated by the activity. Several elements, mainly toxic metals, can be present in swine wastewater and can have a serious environmental impact. It is important, therefore, to know the metal concentration before the discharge of wastewater. In this work the temporal metal distribution in swine manure and its potential reduction using coarse (2 mm) and fine (<0.45 μm) liquid‐solid separation techniques were investigated. In order to do this, different swine manure sample preparation methods for Al, Ba, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr and Zn determination by Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES) were tested. The acid mixtures used to digest the manure sample significantly affected the metal recovery. Good analyte recoveries were observed with nitric acid/hydrogen peroxide mixtures or nitric acid/perchloric acid mixtures. Sulfuric acid/hydrogen peroxide mixtures produced inconsistent results and poor recoveries, mainly for Ba and Pb. It was observed that metal concentrations in swine manure varied greatly with time, up to one order of magnitude, due to changes in swine production such as feed and animal numbers. Metals concentrations observed in the raw wastewater exceeded Brazilian limits for discharge into water bodies and recommendations for agricultural use. Results obtained from the liquid‐solid separation study showed that metals in the raw swine manure were not removed with coarse screening. However, the major fraction of metals were removed by filtration (0.45 μm), with the exception of Na, K and Sr. Thus, the use of liquid‐solid separation techniques that capture the fine solid fractions (and associated metals) from raw manure can have a favorable impact on the environment and contribute to swine production wastewater treatment. 相似文献