Short-term changes in water chemistry in the Baccu Locci stream (Sardinia,Italy) affected by past mining     

Franco Frau  Rosa CiduCarla Ardau 《Applied Geochemistry》2012

Short-term changes in water chemistry, and especially in dissolved trace element concentrations, associated with diel cycles during base-flow conditions at a specific sampling station in the Baccu Locci stream draining the homonymous old mine area in Sardinia (Italy) were investigated. Diel fluctuations in pH and alkalinity were correlated with the temperature-dependent CO₂ solubility and the biologically-induced CO₂ production, both of which were higher during the night. Adsorption/desorption to/from streambed material, in particular ferrihydrite, is believed to be the main in-stream mechanism causing the observed diel variations in dissolved concentrations of As and Zn. Arsenic was mainly affected by the dual action of temperature and competing carbonate ions, whereas pH seemed less important. Temperature acted in accordance with the exothermic feature of anion sorption onto hydrous metal oxide surfaces; aqueous carbonate species exerted their competitive effect in relation to alkalinity variation. Zinc was primarily affected by temperature, in accordance with the endothermic feature of metal cation sorption onto hydrous metal oxide surfaces, and secondly by pH. Co-precipitation of As and Zn with calcite is another possible mechanism, which requires further investigation involving examination of inorganic and biological materials coating the streambed. All these processes potentially controlling the diel cycles of trace elements should be carefully considered to assess the effectiveness of remediation actions currently in progress at Baccu Locci. A normalization method for data from asynchronous sampling has been developed and proposed in order to eliminate or at least attenuate the effect of sampling time and provide an additional tool to identify the processes/mechanisms involved in trace element concentration fluctuations observed along a contaminated stream during base-flow conditions.  相似文献   

Geochemistry and geochronology of the volcanic rocks associated with the Dong'an adularia–sericite epithermal gold deposit,Lesser Hinggan Range,Heilongjiang province,NE China: Constraints on the metallogenesis     

Zhaochong Zhang  Jingwen Mao  Yanbin Wang  Franco Pirajno  Junlai Liu  Zhidan Zhao 《Ore Geology Reviews》2010,37(3-4):158-174

Late Mesozoic volcanism is widespread throughout NE China. On the basis of lithological associations and spatial relationships, the volcanic rocks in the Lesser Hinggan Range can be divided into two formations, i.e., felsic-dominant Fuminghe Formation and overlying mafic-dominant Ganhe Formation. The Dong'an gold deposit, a typical adularia–sericite epithermal system, is spatially closely associated with rhyolitic porphyry, which is a subvolcanic intrusion of the Fuminghe Formation. Total measured, indicated, and inferred resources for the Dong'an deposit are 70 tonnes (2.25 Moz) of gold with the grade of 5.04 g/t Au, making it one of the largest epithermal gold deposits in China.SHRIMP U–Pb zircon and ⁴⁰Ar/³⁹Ar geochronology applied to one rhyolitic porphyry sample and sericite separated from auriferous quartz veins of the main mineralization stage were carried out to constrain magmatic and hydrothermal events. The results suggest that the mineralization age of 107.2 ± 0.6 Ma overlaps with the age of the rhyolitic porphyry 108.1 ± 2.4 Ma. Our new age data indicate that there was a previously unrecognized mineralization event in NE China at 107–108 Ma.Systematic geochemical investigations on the volcanic rocks in the Lesser Hinggan Range show that both Fuminghe and Ganhe Formations are characterized by significant large ion lithophile elements (LILE) and light rare earth elements (LREE) enrichment coupled with high field strength elements (HFSE) depletion, but they have distinct Sr and Nd isotopic compositions. The Fuminghe Formation has relative high ⁸⁷Sr/⁸⁶Sr ratios of 0.707253 to 0.707373, and negative ε_Nd(t) values of ?2.78 to ?3.05 (t = 108 Ma), whereas the Ganhe Formation displays slightly lower ⁸⁷Sr/⁸⁶Sr range of 0.705434–0.705763 and positive ε_Nd(t) values of + 0.76 to +1.83. These geochemical data suggest that the rhyolitic magmas of the Fuminghe Formation probably represent the final differentiates of parental andesitic magmas, resulted from the partial melting of mafic lower crust, whereas the volcanic rocks of the Ganhe Formation were produced by fractionation of basaltic magmas generated from partial melting of a mixture of an incompatible element depleted anhydrous lherzolite asthenospheric mantle source and a hydrous enriched lithospheric mantle source in an extensional tectonic setting, in response to upwelling of asthenospheric mantle. The rhyolite porphyries of the Fuminghe Formation are inferred to have supplied heat that drove the convective hydrothermal system at Dong'an deposit, but also provided some of the fluid sources responsible for the development of the Dong'an epithermal system.  相似文献   

Seismogenic potential and earthquake hazard assessment in the Tell Atlas of Algeria   总被引：1，自引：0，他引：1  

A. Aoudia  F. Vaccari  P. Suhadolc  M. Meghraoui 《Journal of Seismology》2000,4(1):79-98

Seismotectonic zonation studies in the Tell Atlas of Algeria, a branch of the Africa-Eurasia plate boundary, provide a valuable input for deterministic seismic hazard calculations. We delineate a number of seismogenic zones from causal relationships established between geological structures and earthquakes and compile a working seismic catalogue mainly from readily available sources. To this catalogue, for a most rational and best-justified hazard analysis, we add estimates of earthquake size translated from active faulting characteristics. We assess the regional seismic hazard using a deterministic procedure based on the computation of complete synthetic seismograms (up to 1 Hz) by the modal summation technique. As a result, we generate seismic hazard maps of maximum velocity, maximum displacement, and design ground acceleration that blend information from geology, historical seismicity and observational seismology, leading to better estimates of the earthquake hazard throughout northern Algeria. Our analysis and the resulting maps illustrate how different the estimate of seismic hazard is based primarily on combined geologic and seismological data with respect to the one for which only information from earthquake catalogues has been used.  相似文献   

Interstellar Na i D lines towards the Southern Coalsack     

G. A. P. Franco 《Monthly notices of the Royal Astronomical Society》2000,315(3):611-621

The interstellar Na  i D absorption-line profiles observed for 15 stars with lines of sight towards the Southern Coalsack are analysed. The method of profile fitting was used in an attempt to determine column densities, linewidths and velocities for the individual interstellar clouds contributing to the observed absorption lines. In common, the observed spectra show a prominent component which is probably associated with the nearest absorbing material composing the Coalsack. The obtained spatial velocity distribution shows great similarity with earlier results from CO emission. In addition, the Na  i D data reveal evidence for the existence of two or three other structures with radial velocities of about −22, −33 and −40 km s⁻¹. Such components may be the counterparts of interstellar structures observed in diffuse H α and CO emission. The assumption that at least one of these components originated in the Carina arm imposes ∼0.9–1.0 kpc as the maximum distance to the near side of that arm.  相似文献   

Strömgren 4-Color Photometry of Very Metal-Poor Stars     

W.J. Schuster  L. Parrao  A. Franco  T.C. Beers  P.E. Nissen 《Astrophysics and Space Science》1999,265(1-4):183-184

Strömgren uvby photometry has been observed for an additional 140 very metal-poor stars from the survey of Beers et al. (1992). These Galactic stars of very-low metallicity provide crucial information for the investigation of the formation and evolution of the Galaxy, as well as on the nature of the early Universe. The Strömgren uvby-β system allows the measurement of stellar atmospheric parameters as a prelude to detailed abundance studies which will make use of high-resolution spectroscopy and the new generation of large telescopes. The photometric techniques developed by Schuster et al. (1996) are used not only to classify these very metal-poor stars but also to derive effective temperatures, surface gravities, and improved estimates for their interstellar reddenings. In particular, photometric diagrams such as [c ₁], [m ₁] and c ₀, (b-y)₀ are used to classify these stars, especially those near the main-sequence turnoff, where contamination from slightly-evolved subgiants, lower surface-gravity horizontal-branch stars, and even a few supergiant or AGB candidates is found.  相似文献   

Overtopping performance of different armour units for rubble mound breakwaters     

T. Bruce  J.W. van der Meer  L. Franco  J.M. Pearson 《Coastal Engineering》2009

This paper describes a major programme of small-scale physical model tests to establish better the influence of armour type and configuration on overtopping. Specifically, 179 tests determined the relative difference in overtopping behaviour for 13 types/configurations of armour. Roughness factors γ_f were determined for rock (two layers), cubes (single layer and two layers), Tetrapod, Antifer, Haro, Accropode, Core-Loc™ and Xbloc™. These roughness influence factors have been included in the CLASH database and are for use in the neural network prediction of overtopping. Individual wave-by-wave overtopping volumes were analysed and found to compare well with current prediction methods. Measured reflection coefficients for the different units are also presented and compared with recent formulae.  相似文献   

Multiscale Analysis of the Instantaneous Eccentricity Oscillations of the Planets of the Solar System from 13 000 BC to 17 000 AD     

Scafetta  Nicola  Milani  Franco  Bianchini  Antonio 《Astronomy Letters》2019,45(11):778-790

Astronomy Letters - The high-resolution Jet Propulsion Laboratory DE431 and DE432 planetary ephemeris are used to evaluate the instantaneous eccentricity functions of the orbits of the planets of...  相似文献