Isotopic fractionation of Cu in tektites   总被引：1，自引：0，他引：1  

Frederic Moynier  Christian Koeberl  Fred Jourdan 《Geochimica et cosmochimica acta》2010,74(2):799-271

Tektites are terrestrial natural glasses of up to a few centimeters in size that were produced during hypervelocity impacts on the Earth’s surface. It is well established that the chemical and isotopic composition of tektites is generally identical to that of the upper terrestrial continental crust. Tektites typically have very low water content, which has generally been explained by volatilization at high temperature; however, the exact mechanism is still debated. Because volatilization can fractionate isotopes, comparing the isotopic composition of volatile elements in tektites with those of their source rocks may help to understand the physical conditions during tektite formation.Interestingly, volatile chalcophile elements (e.g., Cd and Zn) seem to be the only elements for which isotopic fractionation is known so far in tektites. Here, we extend this study to Cu, another volatile chalcophile element. We have measured the Cu isotopic composition for 20 tektite samples from the four known different strewn fields. All of the tektites (except the Muong Nong-types) are enriched in the heavy isotopes of Cu (1.98 < δ⁶⁵Cu < 6.99) in comparison to the terrestrial crust (δ⁶⁵Cu ≈ 0) with no clear distinction between the different groups. The Muong Nong-type tektites and a Libyan Desert Glass sample are not fractionated (δ⁶⁵Cu ≈ 0) in comparison to the terrestrial crust. To refine the Cu isotopic composition of the terrestrial crust, we also present data for three geological reference materials (δ⁶⁵Cu ≈ 0).An increase of δ⁶⁵Cu with decreasing Cu abundance probably reflects that the isotopic fractionation occurred by evaporation during heating. A simple Rayleigh distillation cannot explain the Cu isotopic data and we suggest that the isotopic fractionation is governed by a diffusion-limited regime. Copper is isotopically more fractionated than the more volatile element Zn (δ^66/64Zn up to 2.49‰). This difference of behavior between Cu and Zn is predicted in a diffusion-limited regime, where the magnitude of the isotopic fractionation is regulated by the competition between the evaporative flux and the diffusive flux at the diffusion boundary layer. Due to the difference of ionic charge in silicates (Zn²⁺ vs. Cu⁺), Cu has a diffusion coefficient that is larger than that of Zn by at least two orders of magnitude. Therefore, the larger isotopic fractionation in Cu than in Zn in tektites is due to the significant difference in their respective chemical diffusivity.  相似文献   

Geophysical and Geoarchaeological Investigations at Aganoa Beach,American Samoa: An Early Archaeological Site in Western Polynesia     

Frederic B. Pearl  William A. Sauck 《Geoarchaeology》2014,29(6):462-476

Archaeological investigations at Aganoa, a coastal site in American Samoa, western Polynesia, revealed a marine resources exploitation base for the early inhabitants of the island. A series of 19 radiocarbon age determinations indicates the principal period of site utilization began no later than 570 B.C., and probably earlier, and lasted for about 300 years. This site is squarely in the phase identified by previous scholars as “ancestral Polynesian.” Geophysical survey in the form of long, shore‐perpendicular transects showed the accretionary history of this beach and ridge area. Surprisingly, it revealed that the earlier ridges were directly below the modern ridge (i.e., progradation of this geomorphic feature had not occurred). The survey revealed a buried paleosol with little or no disturbance, which yielded a well‐preserved assemblage of plain and decorated ceramics, stone artifacts, fishhooks, and archaeofauna. No evidence of archaeological continuity was seen between the end of the terminal Lapita occupation and the later reoccupation of the site after about A.D. 700. This study demonstrates the utility and feasibility of using ground‐penetrating radar for the discovery of deeply buried coastal sites.  相似文献   

High resolution simulation of the South Asian monsoon using a variable resolution global climate model   总被引：2，自引：1，他引：1  

T. P Sabin  R. Krishnan  Josefine Ghattas  Sebastien Denvil  Jean-Louis Dufresne  Frederic Hourdin  Terray Pascal 《Climate Dynamics》2013,41(1):173-194

This study examines the feasibility of using a variable resolution global general circulation model (GCM), with telescopic zooming and enhanced resolution (~35 km) over South Asia, to better understand regional aspects of the South Asian monsoon rainfall distribution and the interactions between monsoon circulation and precipitation. For this purpose, two sets of ten member realizations are produced with and without zooming using the LMDZ (Laboratoire Meteorologie Dynamique and Z stands for zoom) GCM. The simulations without zoom correspond to a uniform 1° × 1° grid with the same total number of grid points as in the zoom version. So the grid of the zoomed simulations is finer inside the region of interest but coarser outside. The use of these finer and coarser resolution ensemble members allows us to examine the impact of resolution on the overall quality of the simulated regional monsoon fields. It is found that the monsoon simulation with high-resolution zooming greatly improves the representation of the southwesterly monsoon flow and the heavy precipitation along the narrow orography of the Western Ghats, the northeastern mountain slopes and northern Bay of Bengal (BOB). A realistic Monsoon Trough (MT) is also noticed in the zoomed simulation, together with remarkable improvements in representing the associated precipitation and circulation features, as well as the large-scale organization of meso-scale convective systems over the MT region. Additionally, a more reasonable simulation of the monsoon synoptic disturbances (lows and disturbances) along the MT is noted in the high-resolution zoomed simulation. On the other hand, the no-zoom version has limitations in capturing the depressions and their movement, so that the MT zone is relatively dry in this case. Overall, the results from this work demonstrate the usefulness of the high-resolution variable resolution LMDZ model in realistically capturing the interactions among the monsoon large-scale dynamics, the synoptic systems and the meso-scale convective systems, which are essential elements of the South Asian monsoon system.  相似文献   

Post‐orogenic sediment drape in the Northern Pyrenees explained using a box model     

Thomas Bernard  Hugh D. Sinclair  Mark Naylor  Frdric Christophoul  Mary Ford 《Basin Research》2021,33(1):118-137

The transition to a post‐orogenic state in mountain ranges has been identified by a change from active subsidence to isostatic rebound of the foreland basin. However, the nature of the interplay between isostatic rebound and sediment supply, and their impact on the topographic evolution of a range and foreland basin during this transition, has not been fully investigated. Here, we use a box model to explore the syn‐ to post‐orogenic evolution of foreland basin/thrust wedge systems. Using a set of parameter values that approximate the northern Pyrenees and the neighbouring Aquitaine foreland basin, we evaluate the controls on sediment drape over the frontal parts of the retro‐wedge following cessation of crustal thickening. Conglomerates preserved at approximately 600‐m elevation, which is ~ 300 m above the present mountain front in the northern Pyrenees are ca. 12 Ma, approximately 10 Myrs younger than the last evidence of crustal thickening in the wedge. Using the model, this post‐orogenic sediment drape is explained by the combination of a sustained, high sediment influx from the range into the basin relative to the efflux out of the basin, combined with cessation of the generation of accommodation space through basin subsidence. Post‐orogenic sediment drape is considered a generic process that is likely to be responsible for elevated low‐gradient surfaces and preserved remnants of continental sedimentation draping the outer margins of the northern Pyrenean thrust wedge.  相似文献   

Intensity measures for probabilistic assessment of non‐structural components acceleration demand          下载免费PDF全文

Marco De Biasio  Stephane Grange  Frederic Dufour  Frederic Allain  Ilie Petre‐Lazar 《地震工程与结构动力学》2015,44(13):2261-2280

A fundamental issue in the framework of seismic probabilistic risk analysis is the choice of ground motion intensity measures (IMs). Based on the floor response spectrum method, the present contribution focuses on the ability of IMs to predict non‐structural components (NSCs) horizontal acceleration demand. A large panel of IMs is examined and a new IM, namely equipment relative average spectral acceleration (E‐ASA_R), is proposed for the purpose of NSCs acceleration demand prediction. The IMs efficiency and sufficiency comparisons are based on (i) the use of a large dataset of recorded earthquake ground motions; (ii) numerical analyses performed on three‐dimensional numerical models, representing actual structural wall and frame buildings; and (iii) systematic statistical analysis of the results. From the comparative study, the herein introduced E‐ASA_R shows high efficiency with respect to the estimation of maximum floor response spectra ordinates. Such efficiency is particularly remarkable in the case of structural wall buildings. Besides, the sufficiency and the simple formulation allowing the use of existing ground motion prediction models make the E‐ASA_R a promising IMs for seismic probabilistic risk assessment. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Multiple time-scale modelling of the circulation in Torres Strait—Australia     

Frederic Saint-Cast 《Continental Shelf Research》2008

Ocean circulation influences nearly all aspects of the marine ecosystem. This study describes the water circulation patterns on time scales from hours to years across Torres Strait and adjacent gulfs and seas, including the north of the Great Barrier Reef. The tridimensional circulation model incorporated realistic atmospheric and oceanographic forcing, including winds, waves, tides, and large-scale regional circulation taken from global model outputs. Simulations covered a hindcast period of 8 years (i.e. 01/03/1997–31/12/2004), allowing the tidal, seasonal, and interannual flow characteristics to be investigated. Results indicated that the most energetic current patterns in Torres Strait were strongly dominated by the barotropic tide and its spring-neap cycle. However, longer-term flow through the strait was mainly controlled by prevailing winds. A dominant westward drift developed in summer over the southeasterly trade winds season, which then weakened and reversed in winter over the northwesterly monsoon winds season. The seasonal flow through Torres Strait was strongly connected to the circulation in the north of the Great Barrier Reef, but showed little connectivity with the coastal circulation in the Gulf of Papua. Interannual variability in Torres Strait was highest during the monsoon period, reflecting variability in wind forcing including the timing of the monsoon. The characteristics of the circulation were also discussed in relation to fine sediment transport. Turbidity level in Torres Strait is expected to peak at the end of the monsoon, while it is likely to be at a low at the end of the trade season, eventually leading to a critically low bottom light level which constitutes a severe risk of seagrass dieback.  相似文献   

Identification of a meteoritic component using chromium isotopic composition of impact rocks from the Lonar impact structure,India     

Berengere Mougel  Frederic Moynier  Christian Koeberl  Daniel Wielandt  Martin Bizzarro 《Meteoritics & planetary science》2019,54(10):2592-2599

The existence of mass‐independent chromium isotope variability of nucleosynthetic origin in meteorites and their components provides a means to investigate potential genetic relationship between meteorites and planetary bodies. Moreover, chromium abundances are depleted in most surficial terrestrial rocks relative to chondrites such that Cr isotopes are a powerful tool to detect the contribution of various types of extra‐terrestrial material in terrestrial impactites. This approach can thus be used to constrain the nature of the bolide resulting in breccia and melt rocks in terrestrial impact structures. Here, we report the Cr isotope composition of impact rocks from the ~0.57 Ma Lonar crater (India), which is the best‐preserved impact structure excavated in basaltic target rocks. Results confirm the presence of a chondritic component in several bulk rock samples of up to 3%. The impactor that created the Lonar crater had a composition that was most likely similar to that of carbonaceous chondrites, possibly a CM‐type chondrite.  相似文献   

Increased benthic grazing: An alternative explanation for low phytoplankton biomass in northern San Francisco Bay during the 1976–1977 drought     

Frederic H. Nichols 《Estuarine, Coastal and Shelf Science》1985,21(3):379-388

Among the consequences of extremely low river flow into northern San Francisco Bay during a two-year drought were (1) a gradual increase in salinity, (2) an unusual decline in chlorophyll a concentration, and (3) the upstream migration of estuarine benthic invertebrates to the normally brackish area of the bay. Total abundance in the benthos at a shallow monitoring site increased from a normal 2000 to greater than 20 000 individuals m^?2 during the summer of 1977, presumably in response to the increased salinity. Estimated filtration rates derived from equations in the literature for one of the species, the suspended-feeding bivalve Mya arenaria ranged from 1 to 4 m³ m^?2 day^?1 during 1977 depending on abundance and mean size on sampling dates. Because water depth at this site is less than 2 m, Mya could have filtered all of the particles (including diatoms) from the water column on the order of once per day. Several other immigrant species undoubtedly contributed to the removal of particles from the near-bottom water as well. Increased benthic grazing, therefore, could have accounted for the anomalously low phytoplankton biomass observed during the drought. These results suggest that during periods of prolonged low river flow and increased salinity benthic food webs could become more important than planktonic food webs in the upper part of the estuary.  相似文献   

    

Frederic W. Darling 《Journal of Geodesy》1948,22(4):356-357

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Lateral terminations of salt walls and megaflaps: An example from Gypsum Valley Diapir,Paradox Basin,Colorado, USA     

Frederic O. Escosa  Mark G. Rowan  Katherine A. Giles  Kyle T. Deatrick  Allison M. Mast  Richard P. Langford  Thomas E. Hearon  Eduard Roca 《Basin Research》2019,31(1):191-212

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