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51.
Geographic signatures are physical, chemical, biotic, and human-induced characteristics or processes that help define similar or unique features of estuaries along latitudinal or geographic gradients. Geomorphologically, estuaries of the northeastern U.S., from the Hudson River estuary and northward along the Gulf of Maine shoreline, are highly diverse because of a complex bedrock geology and glacial history. Back-barrier estuaries and lagoons occur within the northeast region, but the domiant type is the drowned-river valley, often with rocky shores. Tidal range and mean depth of northeast estuaries are generally greater when compared to estuaries of the more southern U.S. Atlantic coast and Gulf of Mexico. Because of small estuarine drainage basins, low riverine flows, a bedrock substrate, and dense forest cover, sediment loads in northeast estuaries are generally quite low and water clarity is high. Tidal marshes, seagrass meadows, intertidal mudflats, and rocky shores represent major habitat types that fringe northeast estuaries, supporting commercially-important fauna, forage nekton and benthos, and coastal bird communities, while also serving as links between deeper estuarine waters and habitats through detritus-based pathways. Regarding land use and water quality trends, portions of the northeast have a history of over a century of intense urbanization as reflected in increased total nitrogen and total phosphorus loadings to estuaries, with wastewater treatment facilities and atmospheric deposition being major sources. Agricultural inputs are relatively minor throughout the northeast, with relative importance increasing for coastal plain estuaries. Identifying geographic signatures provides an objective means for comparing the structure, function, and processes of estuaries along latitudinal gradients.  相似文献   
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This study examined the effects of watershed development on macrobenthic communities in tidal creeks of Charleston Harbor, South Carolina, U.S. Two types of creeks were evaluated: upland creeks which drained watersheds consisting of at least 15% terrestrial land cover, and salt marsh creeks which drained no upland habitat (i.e., only intertidal habitat). Samples of macrobenthic organisms were taken along the longitudinal axis of twenty-three primary (first order) tidal creeks. Water and sediment quality data were also collected including measurements of dissolved oxygen, salinity, temperature, sediment characteristics, and toxic chemicals in the creek sediments. Hypoxic conditions occurred more than 15% of the time in both reference and developed creeks and were a natural attribute of these systems. The most severe and frequent hypoxia occurred in impacted salt marsh creeks. Salinity fluctuations were the greatest in developed upland creeks and salinity range was identified as a potentially reliable indicator of the degree to which watershed development has altered hydrodynamic processes. The creeks draining urban and industrial watersheds were degraded environments characterized by watersheds with high (>50%) levels of impervious surface, broad fluctuations in salinity, severe hypoxia, and potentially toxic levels of chemicals in the sediment. These creeks had low macrobenthic diversity and abundance and were numerically dominated by the oligochaeteMonopylephorus rubroniveus in mud sediments, and the polychaeteLaeoreis culveri in sand sediments. Suburban watersheds had 15–35% impervious surface and creeks draining them were exposed to frequent hypoxia and broad salinity fluctuations. The levels of chemical contaminants in sediments of suburban and impacted salt marsh creeks were generally not different from the levels in reference creeks. Macrobenthic diversity and abundance were higher for suburban and impacted salt marsh creeks than for urban and industrial creeks. However, suburban and salt marsh impacted creeks were numerically dominated by a few pollution indicative species including the oligochaetesM. rubroniveus andTubificoides brownae and the polychaeteL. culveri. These creeks appear to be exhibiting early signs of degradation (e.g., a simplified food web). Two promising community-level macrobenthic metrics for assessing environmental quality were identified: the proportional abundance of pollution indicative taxa, and the proportional abundance of pollution sensitive taxa. These indicators were significantly (p<0.05) correlated with the salinity range, the level of chemical contaminants in sediments, and amount of impervious surface in the watershed.  相似文献   
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Considering heterogeneity in porous media pore size and connectivity is essential to predicting reactive solute transport across interfaces. However, exchange with less‐mobile porosity is rarely considered in surface water/groundwater recharge studies. Previous research indicates that a combination of pore‐fluid sampling and geoelectrical measurements can be used to quantify less‐mobile porosity exchange dynamics using the time‐varying relation between fluid and bulk electrical conductivity. For this study, we use macro‐scale (10 s of cm) advection–dispersion solute transport models linked with electrical conduction in COMSOL Multiphysics to explore less‐mobile porosity dynamics in two different types of observed sediment water interface porous media. Modeled sediment textures contrast from strongly layered streambed deposits to poorly sorted lakebed sands and cobbles. During simulated ionic tracer perturbations, a lag between fluid and bulk electrical conductivity, and the resultant hysteresis, is observed for all simulations indicating differential loading of pore spaces with tracer. Less‐mobile exchange parameters are determined graphically from these tracer time series data without the need for inverse numerical model simulation. In both sediment types, effective less‐mobile porosity exchange parameters are variable in response to changes in flow direction and fluid flux. These observed flow‐dependent effects directly impact local less‐mobile residence times and associated contact time for biogeochemical reaction. The simulations indicate that for the sediment textures explored here, less‐mobile porosity exchange is dominated by variable rates of advection through the domain, rather than diffusion of solute, for typical low‐to‐moderate rate (approximately 3–40 cm/day) hyporheic fluid fluxes. Overall, our model‐based results show that less‐mobile porosity may be expected in a range of natural hyporheic sediments and that changes in flowpath orientation and magnitude will impact less‐mobile exchange parameters. These temporal dynamics can be assessed with the geoelectrical experimental tracer method applied at laboratory and field scales.  相似文献   
54.
Bathymetric mapping of lakes with sonar is essentially limited to the ice-free summer months. Recent developments in ground-penetrating radar technology have greatly increased its portability and capabilities for imaging through fresh water. The suitability of a backpack portable ground-penetrating radar (GPR) system for bathymetric mapping of ice-covered Arctic lakes was investigated by performing grid surveys on three lakes with water depths up to 19 m. It was demonstrated that GPR can now be used to quickly produce high quality bathymetric maps and sub-bottom profiles showing sediment type and lacustrine sediment thickness. While water depths were measured with a precision of ±3%, lacustrine sediment thickness measurements (up to 5 m) had an estimated precision of ±15%.  相似文献   
55.
The mass of nutrients (nitrogen, phosphorus, potassium, and calcium) imported during 1984 and 1985 to the North. Inlet Estuary, Georgetown County, South Carolina, by precipitation and runoff was compared with that imported by a colonial-nesting wading bird, the white ibis (Eudocimus albus). From late March through late June of both years, breeding ibises imported nutrients to the North Inlet Estuary study site from freshwater bottomland forest swamps, where they fed on crayfishes (Procambaridae). Although 1984 was a relatively wet year, in 1985 the ibis breeding season was preceded by a severe winter-spring drought. In 1984 ibises nested in higher numbers, had higher per-pair breeding success, and imported 11 times more nutrients than in 1985. Nutrient input from atmospheric sources was substantially lower in 1984 than in 1985. The 1984 ibises imported 9% as much nitrogen, 33% as much phosphorus, 0.4% as much potassium, and 0.3% as much calcium to the estuary as did atmospheric sources. In 1985 nutrient input from ibises amounted to only 0.2% of the nitrogen, 2.9% of the phosphorus, and ?1% of the potassium and calcium imported by atmospheric sources. Our results show that nutrient inputs to estuaries from colonial-nesting wading birds can be substantial when compared, with those from atmospheric sources and can vary considerably among years. They also suggest that nutrient regimes in estuaries with large assemblages of wading birds may differ significantly from those lacking such colonies. *** DIRECT SUPPORT *** A01BY058 00006  相似文献   
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The partitioning of Gd in the experimental system diopside-aqueous vapor as a function of temperature, pressure, composition of the phases, time, grain size, solid-liquid ratio and Gd concentration has been investigated. A radioactive tracer measurement was used to determine Gd concentration in the separated phases. Diposides were reacted with aqueous vapor containing tracer Gd and reversibility was tested by reacting Gd-doped diopsides with pure aqueous vapor. Equilibration of Gd between the bulk of the diopside and the liquid was found to be limited by the slow rate of Gd diffusion in diopside, maximum value of D = 2 × 10?15cm2sec?1 at 800°C and 1 kb. Depending on whether the diopside was previously synthesized or synthesized from an oxide mix during the experiment, Gd concentrations were zoned in the crystal such that higher concentrations existed at the edges or center, respectively. Equilibrium is difficult to achieve in these experiments, but at the optimum experimental conditions for equilibration, the Gd diopside-aqueous vapor distribution coefficient is 20 ± 6 (800°C, 1 kb) in approximate agreement with previous results of 55 ± 23. Changing the composition of the aqueous vapor indicated that possible mechanisms for Gd substitution included coupling of Gd3+ with H+ or Na+ replacing 2Ca2+, or substitution of 2Gd3+ for 3Ca2+ with formation of a cation vacancy.  相似文献   
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