Magmato-sedimentary Carboniferous to Jurassic evolution of the western Tauern window,Eastern Alps (constraints from U-Pb zircon dating and geochemistry)     

Veselá Petra  Söllner Frank  Finger Friedrich  Gerdes Axel 《International Journal of Earth Sciences》2011,100(5):993-1027

New geochronological U-Pb (LA-ICP-MS) zircon data and geochemical analyses from the Variscan orthogneisses and metavolcanic rocks in the western Tauern window are presented and used to reconstruct the pre-Alpine evolution of this area. The late- and post-Variscan stage in the Tauern window was characterised by distinct magmatic pulses accompanied by the formation of volcano-sedimentary basins. The magmatic activity started in the Visean (335.4 ± 1.5 Ma) with the intrusion of a K-rich, durbachitic biotite-granite (protolith of the Ahorn gneiss). Following a period of exhumation and erosion, Westfalian–Stefanian volcanics were deposited (Grierkar meta-rhyodacite: 309.8 ± 1.5 Ma; Venntal meta-rhyolite: 304.0 ± 3.0 Ma). A renewed magmatic pulse occurred in the Early Permian, producing large volumes of tonalites and granodiorites (Tux meta-granodiorite: 292.1 ± 1.9 Ma). The youngest magmatism is characterised by pyroclastic and tuffitic deposits (Pfitsch meta-rhyolite: 280.5 ± 2.6 Ma; Schönach valley meta-andesite: 279.0 ± 4.8 Ma). This volcanism was probably related to crustal extensional faulting within an intra-continental graben and horst setting, asthenospheric upwelling and heat flow increase due to the onset of the Permian rifting. The Permo-Triassic peneplanation and subsidence is documented by shallow marine and evaporitic deposits. Probably in the Middle Jurassic times, the area was flooded and in the Late Jurassic the whole area was covered by limestones, representing post-rift sediments on the southern European continental margin.  相似文献   

Long-term plankton studies at the lower Rhine/Germany     

Günther Friedrich  Marlies Pohlmann 《Limnologica》2009,39(1):14-39

The river Rhine has lain under considerable anthropogenic stress of its water quality for 100 years. As early as 1905 the first results of studies of the plankton in the Rhine were published. Due to the long residence time of the water a real potamoplankton can develop and at the end of the Lower Rhine it reaches its highest density. The paper consists of two parts. At first an overview is given about the history of plankton studies in the Rhine. The second part is the presentation of results from a monitoring at the Lower Rhine from 1979 to 2004.First systematic studies started at the beginning of the 20th century at the beginning of pollution. Our studies started during a phase of recreation from extreme pollution and eutrophication. Samples were taken at four stations: Bad Honnef, km 640, entrance to North Rhine-Westphalia, Düsseldorf, km 732, Duisburg, km 792 downstream large industrial effluents and big cities, Kleve-Bimmen, km 865 at the border to the Netherlands.In the 1970s nutrients were high, especially phosphate 0.65 mg PO₄-P L⁻¹ in 1979. After 1980 phosphate dropped to 0.11 mg PO₄-P L⁻¹ in 2004 (mean values of the growing season). Ammonia was reduced from about 0.52 (1979) to 0.02 (2004) mg NH₄-N L⁻¹. Nitrate remained between 3.72 (1989) and 2.26 (2004) mg NO₃-N L⁻¹ at a relatively high level. Oxygen concentrations were very low during the 1960s and 1970s, sometimes only 4 mg L⁻¹ O₂. During our studies the oxygen increased up to 9 mg L⁻¹ O₂ with a tendency to 11 mg L⁻¹ O₂ in the last years. Chlorophyll a was estimated to be between 59 (1979) and 31μg L⁻¹ (1986) with short peaks up to 170 μg L⁻¹ (1989). Since 1992 the mean values have varied between 30 (1993) and 21 μg L⁻¹ (2004).The floristic phytoplankton composition is characterised by the dominance of the centric diatom Stephanodiscus hantzschii. Other diatoms like Skeletonema subsalsum, Skeletonema potamos and Asterionella formosa were regularly present in smaller quantities. The second dominant group was coccale green algae. During the 1980s they formed up to 35% of the biomass. Since the 1990s their contribution to the phytoplankton became much smaller. This change corresponds with the increase of wastewater treatment and the diminution of nutrients. All the other groups of algae were present in minor quantities. During the time of higher trophy in the 1970s and 1980s the phytoplankton formed two peaks, in recent years only one peak has developed, depending on different flow conditions during the growing season and lower trophic state in the upstream parts of the river.Excellent correspondence exists between cell number, biovolume and chlorophyll a content and the results of delayed fluorescence (DF) measurement. The trophic status in the Lower Rhine may be estimated as (moderate) eutrophic. The ecological status of the phytoplankton is good based on the requirements of the European Water Framework Directive (WFD).The zooplankton consists mainly of rotatoria and larvs of Dreissena polymorpha. Grazing on phytoplankton seems to be mainly due to the large quantities of benthic Dreissena and the newly introduced mussel Corbicula.  相似文献   

Unusual exsolution phenomena in omphacite and partial replacement of phengite by phlogopite + kyanite in an eclogite from the Erzgebirge   总被引：4，自引：0，他引：4  

Esther Schmädicke  Wolfgang Friedrich Müller 《Contributions to Mineralogy and Petrology》2000,139(6):629-642

In the Erzgebirge Crystalline Complex, eclogites occur in three different high pressure (HP) units (1, 2 and 3) recording contrasting pressure (P)–temperature (T) conditions. Eclogites from HP-unit 1 experienced peak metamorphic conditions in the coesite stability field at about 33 kbar/850 °C. Commonly, these eclogites from HP-unit 1 are all very similar, with an eclogitic peak assemblage of omphacite–garnet–coesite–K-feldspar, rarely accompanied by kyanite, and omphacites systematically deviating from a stoichiometric composition. In contrast, an eclogite recently found near Blumenau, is mineralogically and geochemically different from the typical eclogites of HP-unit 1. This unusual eclogite reveals the eclogitic equilibrium assemblage omphacite–garnet–coesite–phengite–phlogopite–kyanite, and yields metamorphic peak conditions of 870 °C and >29 kbar. There is clear textural evidence of the formation of phlogopite and kyanite under partial consumption of phengite and garnet. Moreover, the omphacite is stoichiometric and contains abundant exsolution lamellae, the thickest of which were identified as quartz by the electron microprobe. The finer lamellae were studied by transmission electron microscopy (TEM). Oligoclase was identified as an exsolution phase. Other lamellae proved to consist of K-white mica, also interpreted as exsolution. Prior to exsolution, the omphacite composition must have been cation-deficient, as that of the other, common HP-unit 1 eclogites. These non-stoichiometric compositions are ascribed to partial substitution by the Ca-Eskola pyroxene component, which calculates to an average of 8 mol% for omphacite in HP-unit 1 eclogites. According to experiments, this substitution becomes significant at P > 30 kbar. Exsolution of K-white mica may indicate hydroxyl defects in the original omphacite, also favoured by high pressure. Oligoclase and K-white mica exsolution from Ca-Eskola-rich clinopyroxene has not previously been reported. The omphacite has a disordered C2/c structure; and in just one case very small (a few tens of nanometres) antiphase domains, resulting from the C2/c to P2/n transformation, are present. These features may indicate a brief thermal history and rapid tectonic processes. Received: 4 January 1999 / Accepted: 20 April 2000  相似文献   

Effect of polychromatic X‐ray microtomography imaging on the amino acid content of the Murchison CM chondrite     

Jon M. Friedrich  Hannah L. McLain  Jason P. Dworkin  Daniel P. Glavin  W. Henry Towbin  Morgan Hill  Denton S. Ebel 《Meteoritics & planetary science》2019,54(1):220-228

X‐ray microcomputed tomography (μCT) is a useful means of characterizing cosmochemical samples such as meteorites or robotically returned samples. However, there are occasional concerns that the use of μCT may be detrimental to the organic components of a chondrite. Small organic compounds such as amino acids comprise up to ~10% of the total solvent extractable carbon in CM carbonaceous chondrites. We irradiated three samples of the Murchison CM carbonaceous chondrite under conditions akin to and harsher than those typically used during typical benchtop X‐ray μCT imaging experiments to determine if detectable changes in the amino acid abundance and distribution relative to a nonexposed Murchison control sample occurred. After subjecting three meteorite samples to ionizing radiation dosages between ~300 Gray (Gy) and 3 kGy with bremstrahlung X‐rays, we analyzed the amino acid content of each sample. Within sampling and analytical errors, we cannot discern differences in the amino acid abundances and amino acid enantiomeric ratios when comparing the control samples (nonexposed Murchison) and the irradiated samples. We conclude that a polychromatic X‐ray μCT experiment does not alter the abundances of amino acids to a degree greater than how well those abundances are measured with our techniques and therefore any damage to amino acids is minimal.  相似文献   

Editorial     

Friedrich Seifert 《Physics and Chemistry of Minerals》1985,12(6):315-315

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NOBLE GASES AND THE CLASSIFICATION OF BRACHINA     

Ulrich Ott  Hans-Peter Lhr  Friedrich Begemann 《Meteoritics & planetary science》1985,20(1):69-78

Noble-gas systematics show that Brachino is not a member of the SNC-group of meteorites. The whole-rock K-Ar gas retention age is (3.11 ± 0.07) AE as compared to the 1.3 AE solidification ages of SNCs; the content of radiogenic¹²⁹ Xe* of (3.47 ±. 15) × 10^?10 cm³ STP/g is about two orders of magnitude higher, and the¹²⁹ Xe/¹³² Xe ratio (11.0), the ratio of radiogenic¹²⁹ Xe* to fissiogenic¹³⁶ Xe_f (300), and the ratio³⁶ Ar/¹³² Xe in the trapped gases are about one order of magnitude higher than observed for SNCs. The same evidence argues strongly against any simple genetic relationship with eucrites. The noble-gas abundance pattern resembles closely that in silicate inclusions from the iron meteorites Campo del Cielo and Udei Station. Abundances of cosmic-ray produced³ He and²¹ Ne (5.7 and. 99 × 10^?8 cm³ STP/g, resp.) indicate an exposure age of ～ 2.4 Ma. Irradiation conditions appear to have been perfectly normal except for an unaccountably low content of spallogenic ³⁸Ar. Losses by diffusion of radiogenic⁴ He are severe; they must have occurred at or before the onset of the exposure of the meteoroid to the cosmic radiation.  相似文献   

Reply to the comments on “The biosphere: A homogenizer of Pb-isotope signals” by Richard Bindler and William Shotyk     

Clemens Reimann  Belinda Flem  Arnold Arnoldussen  Peter Englmaier  Tor Erik Finne  Friedrich Koller   ystein Nordgulen 《Applied Geochemistry》2008,23(8):2527-2535

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The biosphere: A homogeniser of Pb-isotope signals     

Clemens Reimann  Belinda Flem  Arnold Arnoldussen  Peter Englmaier  Tor Erik Finne  Friedrich Koller  Øystein Nordgulen 《Applied Geochemistry》2008

Rock, soil, and plant (terrestrial moss, European mountain ash leaves, mountain birch leaves, bark and wood, and spruce needles and wood) samples, collected at 3 km intervals along a 120 km long transect (40 sites) cutting the city of Oslo, Norway, were analysed for their Pb concentration and Pb-isotope ratios. A general decrease in ²⁰⁶Pb/²⁰⁷Pb, ²⁰⁸Pb/²⁰⁷Pb and ²⁰⁶Pb/²⁰⁸Pb ratios, with a characteristic low variability in all plant materials and the plant-derived O-horizon of soil profiles, compared to rocks and mineral soils, is observed along the transect. It is demonstrated that minerogenic and biogenic sample materials belong to two different spheres, the lithosphere and biosphere, and that geochemical processes determining their chemical and isotopic compositions differ widely. Background variation for both sample materials needs to be established and documented at the continental and global scale before the anthropogenic influence on the geochemistry of the earth’s surface can be reliably estimated.  相似文献   

The use of remote sensing in coastal research     

Friedrich Wieneke Dr. 《GeoJournal》1991,24(1):71-76

Coastal research is structured here according to its main topics, and remote sensing systems are valued accordingto their usefulness for these different topics. Mainly, coastal research requires a high spatial resolution in combination with a high temporal resolution power. Therefore, satellite-borne systems are less suited than airborne systems. High altitude photography combines advantages of both systems, but substances may best be detected by non-photographic techniques.  相似文献   

Micrometeorite craters and related features on lunar rock surfaces     

Friedrich H  rz  Jack B. Hartung  Donald E. Gault 《Earth and Planetary Science Letters》1971,10(4):381-386

Craters in the 0.4 mm and larger size class were observed on six Apollo 12 whole rock surfaces (12017, 12021, 12038, 12047, 12051 and 12073). Craters on crystalline surfaces are characterized by a central, glass-lined cavity, a concentric zone of shock fractured, high albedo material and a concentric spallation area. The crater geometries observed are similar to craters produced on glasses and crystalline materials in the laboratory with projectile velocities exceeding 10 km/sec. The high projectile velocities required and the presence of a distinct demarcation line between cratered and uncratered surfaces on individual rocks indicate that most of the microcraters are produced by primary cosmic particles. These discrete impact events account for most of the erosion and fragmentation of lunar surface rocks.  相似文献