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Climate change threatens water resources in snowmelt‐dependent regions by altering the fraction of snow and rain and spurring an earlier snowmelt season. The bulk of hydrological research has focused on forecasting response in streamflow volumes and timing to a shrinking snowpack; however, the degree to which subsurface storage offsets the loss of snow storage in various alpine geologic settings, i.e. the hydrogeologic buffering capacity, is still largely unknown. We address this research need by assessing the affects of climate change on storage and runoff generation for two distinct hydrogeologic settings present in alpine systems: a low storage granitic and a greater storage volcanic hillslope. We use a physically based integrated hydrologic model fully coupled to a land surface model to run a base scenario and then three progressive warming scenarios, and account for the shifts in each component of the water budget. For hillslopes with greater water retention, the larger storage volcanic hillslope buffered streamflow volumes and timing, but at the cost of greater reductions in groundwater storage relative to the low storage granite hillslope. We found that the results were highly sensitive to the unsaturated zone retention parameters, which in the case of alpine systems can be a mix of matrix or fracture flow. The presence of fractures and thus less retention in the unsaturated zone significantly decreased the reduction in recharge and runoff for the volcanic hillslope in climate warming scenarios. This approach highlights the importance of incorporating physically based subsurface flow in to alpine hydrology models, and our findings provide ways forward to arrive at a conceptual model that is both consistent with geology and hydrologic principles. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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Clay minerals, although ubiquitous on the ancient terrains of Mars, have not been observed in Martian meteorite Allan Hills (ALH) 84001, which is an orthopyroxenite sample of the early Martian crust with a secondary carbonate assemblage. We used a low‐temperature (20 °C) one‐dimensional (1‐D) transport thermochemical model to investigate the possible aqueous alteration processes that produced the carbonate assemblage of ALH 84001 while avoiding the coprecipitation of clay minerals. We found that the carbonate in ALH 84001 could have been produced in a process, whereby a low‐temperature (~20 °C) fluid, initially equilibrated with the early Martian atmosphere, moved through surficial clay mineral and silica‐rich layers, percolated through the parent rock of the meteorite, and precipitated carbonates (thereby decreasing the partial pressure of CO2) as it evaporated. This finding requires that before encountering the unweathered orthopyroxenite host of ALH 84001, the fluid permeated rock that became weathered during the process. We were able to predict the composition of the clay minerals formed during weathering, which included the dioctahedral smectite nontronite, kaolinite, and chlorite, all of which have been previously detected on Mars. We also calculated host rock replacement in local equilibrium conditions by the hydrated silicate talc, which is typically considered to be a higher temperature hydrothermal phase on Earth, but may have been a common constituent in the formation of Martian soils through pervasive aqueous alteration. Finally, goethite and magnetite were also found to precipitate in the secondary alteration assemblage, the latter associated with the generation of H2. Apparently, despite the limited water–rock interaction that must have led to the formation of the carbonates ~ 3.9 Ga ago, in the vicinity of the ALH 84001 source rocks, clay formation would have been widespread.  相似文献   
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Physical processes are at the root of determining hydrologic response at all scales. Here, the physical mechanisms linking (1) subsurface heterogeneities to soil moisture and (2) resulting land-surface energy feedbacks to the atmosphere, are examined at the hillslope scale using a fully coupled surface-subsurface-land-surface model, ParFlow. A hillslope with a heterogeneous subsurface and uniform topography was modeled numerically using summer atmospheric conditions and a single precipitation event under controlled boundary conditions in order to isolate the contribution of hydraulic conductivity to land-surface hydrological processes and energy interactions. Patterns of subsurface hydraulic conductivity are shown to govern soil-moisture distribution at the hillslope scale following precipitation. This variability in soil moisture is closely linked to the variability in land-surface energy feedbacks. The role that vegetation plays in subsurface soil moisture and land energy communications is also examined. Results show that hillslope soil moisture variation is first established by patterns in vertical hydraulic conductivity, while later on in the dry-down period, vegetation exerts greater control on the land-surface energy fluxes and controls the rate of hillslope dry down. Furthermore, as compared to bare-soil simulations, grass-cover simulations show an increase in near-surface soil moisture despite water up-take along the rooting depth.  相似文献   
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We present a diatom record from a sediment core taken in Lake Fryxell, Taylor Valley, Antarctica. Six zones were defined using diatom assemblage changes that indicate varying limnological conditions. The early lake stage, ca. 35,000 cal years BP, is characterized by Mayamea atomus f. permitis, a species rarely reported in modern Antarctic Dry Valley environments. An extended period from ca. 35,000 to 19,000 cal years BP is characterized by low diatom abundance, with dominant taxa Luticola spp., Muelleria spp., and Diadesmis contenta. The modern assemblage was established ca. 13,000 cal years BP, after two relatively brief transitional stages. One key species for this recent period, Navicula lineola var. perlepida, is absent in surface sediments and the modern environment, indicating an environmental change within the last several centuries. The diatom assemblage is compared to modern diatom communities in Dry Valley streams, which provide the most complete information on diatom distributions in this region. Although precise environmental interpretation of the core is hampered by limited knowledge of environmental constraints on many of the diatom taxa present in the lake core, the data provide important new insights into the history of Glacial Lake Washburn.  相似文献   
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