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131.
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Abstract The north-east Australian margin is the largest modern example of a tropical mixed siliciclastic/carbonate depositional system, with an outer shelf hosting the Great Barrier Reef (GBR) and an inner shelf dominated by fluvially sourced siliciclastic sediment wedges. The long-term interplay between these sediment components and sea level is recorded in the Queensland Trough, a 1–2 km deep N–S elongate basin situated between the GBR platform and the Queensland Plateau. In this paper, 154 samples from 45 surface grabs and six well-dated piston cores were analysed for total carbonate content, carbonate mineralogy and Sr concentration to establish spatial and temporal patterns of carbonate accumulation in the Queensland Trough over the last 300 kyr. Surface carbonate contents are lowest on the inner-shelf (<5%) and in the trough axis (<60%) because of siliciclastic dilution. Carbonate on the shelf is mostly Sr-rich aragonite and high-Mg calcite (HMC), whereas that in the basin is mostly low-Mg calcite. Once normalized to remove the effects of siliciclastic dilution, surface Sr-rich aragonite and HMC abundances decrease linearly to background levels ≈ 100 km seaward of the shelf edge. Core samples show that, over time, normalized aragonite and Sr abundances are greatest during periods of shelf flooding and lowest when sea level drops below the shelf edge. This is consistent with changes in the production of coral and calcareous algae, and the shedding of their debris from the shelf. Interestingly, normalized HMC concentrations on the slope peak during periods of major transgression, perhaps because of maximum off-shelf transport from inter-reef areas or intermediate water dissolution. After accounting for siliciclastic dilution, there are strong similarities in both spatial and temporal patterns of carbonate minerals between slopes and basins of the north-east Australian margin and those of pure carbonate margins such as the Bahamas. A limited set of basic processes, including the formation and breakdown of carbonate on the shelf, the transport of carbonate off the shelf and eustatic sea level, probably controls carbonate accumulation in slope and basin settings of tropical environments, irrespective of proximal siliciclastic sediment sources.  相似文献   
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The potential for Mn oxides to modify the biogeochemical behavior of U during reduction by the subsurface bacterium Shewanella putrefaciens strain CN32 was investigated using synthetic Mn(III/IV) oxides (pyrolusite [β-MnO2], bixbyite [Mn2O3] and K+-birnessite [K4Mn14O27 · 8H2O]). In the absence of bacteria, pyrolusite and bixbyite oxidized biogenic uraninite (UO2[s]) to soluble U(VI) species, with bixbyite being the most rapid oxidant. The Mn(III/IV) oxides lowered the bioreduction rate of U(VI) relative to rates in their absence or in the presence of gibbsite (Al[OH]3) added as a non-redox-reactive surface. Evolved Mn(II) increased with increasing initial U(VI) concentration in the biotic experiments, indicating that valence cycling of U facilitated the reduction of Mn(III/IV). Despite an excess of the Mn oxide, 43 to 100% of the initial U was bioreduced after extended incubation. Analysis of thin sections of bacterial Mn oxide suspensions revealed that the reduced U resided in the periplasmic space of the bacterial cells. However, in the absence of Mn(III/IV) oxides, UO2(s) accumulated as copious fine-grained particles external to the cell. These results indicate that the presence of Mn(III/IV) oxides may impede the biological reduction of U(VI) in subsoils and sediments. However, the accumulation of U(IV) in the cell periplasm may physically protect reduced U from oxidation, promoting at least a temporal state of redox disequilibria.  相似文献   
135.
 Logarithmic sensitivities and plausible relative errors are studied in a simple no-crossflow model of a transient flowmeter test (TFMT). This model is identical to the model of a constant-rate pumping test conducted on a fully penetrating well with wellbore storage, surrounded by a thick skin zone, and situated in a homogeneous confined aquifer. The sensitivities of wellbore drawdown and wellface flowrate to aquifer and skin parameters are independent of the pumping rate. However, the plausible relative errors in the aquifer and skin parameters estimated from drawdown and wellface flowrate data can be proportionally decreased by increasing the pumping rate. The plausible relative errors vary by many orders of magnitude from the beginning of the TFMT. The practically important flowrate and drawdown measurements in this test, for which the plausible relative errors vary by less than one order of magnitude from the minimum plausible relative errors, can begin approximately when the dimensionless wellface flowrate exceeds q D =q/Q≈0.4. During most of this stage of the test, the plausible relative errors in aquifer hydraulic conductivity (K a ) are generally an order of magnitude smaller than those in aquifer specific storativity. The plausible relative errors in the skin hydraulic conductivity (K s ) are generally larger than the plausible relative errors in the aquifer specific storativity when the thick skin is normal (K s >K a ) and smaller when the thick skin is damaged (K s <K a ). The specific storativity of the skin zone would be so biased that one should not even attempt to estimate it from the TFMT. We acknowledge Wiebe H. van der Molen for recommending the De Hoog algorithm and sharing his code. This research was partially supported by the US Geological Survey, USGS Agreement #1434-HQ-96-GR-02689 and North Carolina Water Resources Research Institute, WRRI Project #70165.  相似文献   
136.
This paper examines the fieldwork undertaken by the distinguished French geographer Pierre Gourou (1900–99) in the Tonkin Delta (Red River Delta) of northern Vietnam in the 1920s and 1930s, and his wider configuration of “the tropical world” as a distinct space of knowledge and radical otherness. Gourou's fieldwork endeavours in French Indochina are interpreted in the light of recent work on “tropicality”: the idea that “the tropics” need to be understood as a western cultural construction and colonising discourse that essentialised the hot, wet regions of the world, and exalted the temperate world over its tropical counterpart. The paper focuses on Gourou's monumental 1936 study Les paysans du delta tonkinois, étude de géographie humaine. It is argued that in this study, and his later comparative work on the tropics, Gourou elaborated a distinct geographical variant of tropicality, but one that, ultimately, reinforced the essentialist logic and momentum of this discourse. Particular attention is paid to the geographical ideas, fieldwork techniques and discursive strategies that Gourou used in his 1936 study, and the French colonial context in which he worked. The article shows how Gourou appealed to western reason and science as tools of study, identified overpopulation as the key problem facing the Tonkin Delta, and suggested that colonial practices of modernisation had a limited place and ineffectual role in the rice plains of the region.  相似文献   
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Intermittently open/closed estuaries (IOCE) are a dynamic form of estuary characterised by periodic entrance closure to the ocean. Entrance closure is a function of the relative balance between on and offshore sediment transport with closures occurring during periods of low fluvial discharge whereby the estuary ebb‐tidal prism is reduced. Although the broad scale processes of entrance closure are becoming better understood, there remains limited knowledge on channel morphodynamics during an individual closure event. In this study, the entrance dynamics of three IOCE on the coast of Victoria, Australia, were monitored over a daily timescale following both artificial and natural openings. The influence of changing marine and fluvial conditions on the relative sedimentation rate within the entrance channel was examined. IOCE in Victoria showed two distinct modes of entrance closure: (a) lateral accretion, whereby the estuary gradually closes by longshore drift‐driven spit growth during low river flows; and (b) vertical accretion, where the channel rapidly aggrades under high (> 2 m), near‐normal waves. During storms, when fluvial discharge and wave heights simultaneously increase, large swells will not always close the mouth due to an increase in the ebb‐tidal prism. The estuary water depth and the maximum channel dimensions following opening were not proportional to the opening duration, with this being a function of the wave and fluvial conditions occurring following lagoon drainage. Based on the findings of this work, implementing a successful artificial entrance opening is dependent on reduced onshore sedimentation rates which occur when wave energy is low (< 2 m Hs) relative to river flow. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
139.
Peatlands provide a setting that is well suited for cranberry agriculture in the Northeastern United States. However, misconceptions exist about the amounts and forms of nitrogen (N) and phosphorus (P) export from cranberry farms. In this study, we report inorganic and organic forms of N and P export from five peatlands cultivated for cranberry production in southeastern, Massachusetts, United States. We then compare N loading rates among cranberry farms in southeastern Massachusetts, row crop farms in the Midwestern United States, and uncultivated peatlands in the United States and United Kingdom. Based on a fluvial mass balance analysis, we find that nonriparian cranberry farms export 2.56 kg of P ha−1 year−1of total P and 12.1 kg of N ha−1 year−1of total N. Total N export from riparian or “flow through” farms is two times higher than nonriparian farms due to less retention of N fertilizer in the vadose zone of riparian farms. Gross total N export from riparian and nonriparian cranberry farms consists of 35% particulate organic N, 26% dissolved organic N, 31% ammonium (NH4+), and 8% nitrate (NO3). The low proportions of NO3 export (13% of total dissolved N [TDN]) for cranberry farms differ from NO3 export for row crop farms (75% of TDN; p < .001) but not for uncultivated peatlands (17% of TDN; p = .61). Despite being highly modified by fertilizers and artificial drainage, low NO3 export (2.2 kg of N ha−1 year−1) from cranberry farms is consistent with field measurements of rapid N turnover in uncultivated peatlands. This finding suggests that state-funded wetland restoration efforts to restore denitrification in retired cranberry farms may be limited by NO3 rather than soil moisture or organic matter.  相似文献   
140.
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