Oxygen budget of a perennially ice-covered Antarctic lake     

Wharton RA  McKay CP  Simmons GM  Parker BC 《Limnology and oceanography》1986,31(2):437-443

A bulk O2 budget for Lake Hoare, Antarctica, is presented. Five years of seasonal data show the lake to be persistently supersaturated with O2. Oxygen is carried into the lake in glacial meltstreams and is left behind when this water is removed as ice by ablation and sublimation. A diffusive loss of O2 from the lake through the summer moat is suggested. Measured values of the total O2 in the water column indicate that the time scale of O2 turnover is much longer than a year. Based on these results we suggest that the amount of O2 in the water does not change significantly throughout the year and that the lake is also supersaturated with N2.  相似文献   

A statistical riverine litter propagation model.     

C E Balas  A T Williams  S L Simmons  A Ergin 《Marine pollution bulletin》2001,42(11):1169-1176

A statistical riverine litter propagation (RLP) model based on importance sampling Monte Carlo (ISMC) simulation was developed in order to predict the frequency distribution of certain litter types in river reaches. The model was preliminarily calibrated for plastic sheeting by a pilot study conducted on the River Taff, Wales (UK). Litter movement was predominantly controlled by reach characteristics, such as vegetation overhang and water-course obstructions. These affects were modeled in the simulations, by utilizing geometric distributions of river reaches in the time domain. The proposed model satisfactorily simulated the dosing experiments performed at the River Taff. It was concluded from the preliminary calibrations that, the RLP model can be efficiently utilized to portray litter propagation at any arbitrarily selected river site, provided that the stream flows and reach characteristics are calibrated by representative probability distributions of similar sections. Therefore, the RLP model can be considered as a new statistical technique that can predict litter propagation in river sections.  相似文献   

Sr-Isotope record of Quaternary marine terraces on the California coast and off Hawaii     

Kenneth R. Ludwig  Daniel R. Muhs  Kathleen R. Simmons  James G. Moore 《Quaternary Research》1992,37(3)

Strontium-isotopic ratios of dated corals have been obtained from submerged reefs formed during Quaternary glacial periods off the Hawaiian islands. These data, combined with data from deep-sea sediments, tightly constrain the secular variation of marine ⁸⁷Sr/⁸⁶Sr for the past 800,000 yr. Although long-term trends are apparent, no significant (>0.02‰), rapid (<100,000 yr) excursions in ⁸⁷Sr/⁸⁶Sr were resolved nor did we observe any samples with ⁸⁷Sr/⁸⁶Sr greater than that of modern seawater. Strontium in mollusks from elevated marine terraces formed during interglacial periods on the southern California coast show resolvable and consistent variations in ⁸⁷Sr/⁸⁶Sr which, when compared to the trend of Quaternary marine ⁸⁷Sr/⁸⁶Sr, can be used to infer uplift rates and define approximate ages for the higher terraces. The Sr-isotope age estimates indicate that uplift rates vary among crustal blocks and were not necessarily constant with time. No contrast in Sr-isotopic ratios between similar-age Hawaiian and California fossils was observed, confirming that any change in marine ⁸⁷Sr/⁸⁶Sr from glacial to interglacial periods must be small. A realistic appraisal of the potential of Sr-isotope stratigraphy for chronometric applications in the Quaternary suggests that the technique will be limited to relatively coarse distinctions in age.  相似文献   

Partitioning of manganese,iron, copper,zinc, lead,cobalt, and nickel in black coatings on stream boulders in the vicinity of the Magruder mine,Lincoln Co., Georgia     

Robert H. Carpenter  Gene D. Robinson  Willis B. Hayes 《Journal of Geochemical Exploration》1978,10(1):75-89

Sequential digestions of Fe-Mn oxide coated boulders collected upstream and downstream from the Magruder mine, Lincoln Co., Georgia, indicate probable partitioning relationships for Zn, Cu, Pb, Co, and Ni with respect to Mn and Fe. Initial digestion with 0.1M hydroxylamine hydrochloride (Hxl) in 0.01M HNO₃ selectively dissolyes Mn oxides, whereas subsequent digestion with 1:4 HCl dissolves remaining Fe oxides.The results indicate that partitioning is not constant, but varies systematically with respect to the location of metal-rich waters derived from sulfide mineralization. Upstream from the mineralized zone Zn and Ni are distinctly partitioned to the Fe oxide component and Co and Cu are partitioned to the Mn oxide component. Immediately downstream from the mineralized zone, Mn oxides become relatively more enriched in Zn, whereas Fe oxides are relatively more enriched in Cu, Co, and Ni. Analytical precision for Pb is poor, but available data suggests it is more closely associated with Fe oxides.For routine geochemical surveys utilizing coated surfaces, a one-step digestion method is probably adequate. Parameters useful for detecting sulfide mineralization are metal concentrations normalized to surface area or various ratios (e.g. Zn/(Mn + Fe), Cu/Mn, Pb/Fe). Ratios can be obtained much faster, and at lower analytical costs than conventional analysis of stream sediment.  相似文献   

Biofouling confounds the uptake of trace organic contaminants by semi-permeable membrane devices (SPMDs)     

Richardson BJ  Lam PK  Zheng GJ  McClellan KE  De Luca-Abbott SB 《Marine pollution bulletin》2002,44(12):1372-1379

The outer layers of layflat, low density polyethylene plastic tubing (the principal component of semi-permeable membrane devices, SPMDs) were biofouled at a clean site in Hong Kong coastal waters for periods of 1–4 weeks. Following pre-fouling, triolein was added to the SPMDs and, along with control (unfouled) devices, they were exposed to a range of organochlorine pesticides (-HCH, aldrin, p,p^′-DDT) and PAHs (anthracene, fluoranthene and benzo(a)pyrene) under laboratory conditions. Results showed that the uptake of contaminants by SPMDs was severely reduced by as much as 50% under fouling conditions in comparison to unfouled controls. The ultimate utility of SPMDs as passive monitors is thus reduced, although alternative measures, such as the use of permeability reference compounds may compensate, and allow for realistic evaluations of dissolved environmental concentrations in aquatic environments. However, due to the complexities involved in such procedures––especially as they need to be conducted on a case-by-case basis––the utility of SPMDs appears to be limited for estimates of bioavailability unless necessary calibrations are undertaken within each environment that the sampler is used.  相似文献   

Groundwater flow and solute transport at the Mourquong saline-water disposal basin, Murray Basin, southeastern Australia   总被引：5，自引：0，他引：5  

Craig T. Simmons  Kumar A. Narayan  Juliette A. Woods  Andrew L. Herczeg 《Hydrogeology Journal》2002,10(2):278-295

Saline groundwater and drainage effluent from irrigation are commonly stored in some 200 natural and artificial saline-water disposal basins throughout the Murray-Darling Basin of Australia. Their impact on underlying aquifers and the River Murray, one of Australia's major water supplies, is of serious concern. In one such scheme, saline groundwater is pumped into Lake Mourquong, a natural groundwater discharge complex. The disposal basin is hydrodynamically restricted by low-permeability lacustrine clays, but there are vulnerable areas in the southeast where the clay is apparently missing. The extent of vertical and lateral leakage of basin brines and the processes controlling their migration are examined using (1) analyses of chloride and stable isotopes of water (²H/¹H and ¹⁸O/¹⁶O) to infer mixing between regional groundwater and lake water, and (2) the variable-density groundwater flow and solute-transport code SUTRA. Hydrochemical results indicate that evaporated disposal water has moved at least 100 m in an easterly direction and that there is negligible movement of brines in a southerly direction towards the River Murray. The model is used to consider various management scenarios. Salt-load movement to the River Murray was highest in a "worst-case" scenario with irrigation employed between the basin and the River Murray. Present-day operating conditions lead to little, if any, direct movement of brine from the basin into the river. Electronic Publication  相似文献   

Comparison of 15 evaporation methods applied to a small mountain lake in the northeastern USA   总被引：7，自引：0，他引：7  

Donald O. Rosenberry  Thomas C. Winter  Donald C. Buso  Gene E. Likens   《Journal of Hydrology》2007,340(3-4):149-166

Few detailed evaporation studies exist for small lakes or reservoirs in mountainous settings. A detailed evaporation study was conducted at Mirror Lake, a 0.15 km² lake in New Hampshire, northeastern USA, as part of a long-term investigation of lake hydrology. Evaporation was determined using 14 alternate evaporation methods during six open-water seasons and compared with values from the Bowen-ratio energy-budget (BREB) method, considered the standard. Values from the Priestley–Taylor, deBruin–Keijman, and Penman methods compared most favorably with BREB-determined values. Differences from BREB values averaged 0.19, 0.27, and 0.20 mm d⁻¹, respectively, and results were within 20% of BREB values during more than 90% of the 37 monthly comparison periods. All three methods require measurement of net radiation, air temperature, change in heat stored in the lake, and vapor pressure, making them relatively data intensive. Several of the methods had substantial bias when compared with BREB values and were subsequently modified to eliminate bias. Methods that rely only on measurement of air temperature, or air temperature and solar radiation, were relatively cost-effective options for measuring evaporation at this small New England lake, outperforming some methods that require measurement of a greater number of variables. It is likely that the atmosphere above Mirror Lake was affected by occasional formation of separation eddies on the lee side of nearby high terrain, although those influences do not appear to be significant to measured evaporation from the lake when averaged over monthly periods.  相似文献   

Programmable Hand Calculator Programs for Pumping and Injection Wells: I — Constant or Variable Pumping (Injection) Rate, Single or Multiple Fully Penetrating Wells     

Don L. Warner  M. Gene Yow 《Ground water》1979,17(6):532-537

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The effect of cracks on the thermal expansion of rocks     

H.W. Cooper  Gene Simmons 《Earth and Planetary Science Letters》1977,36(3):404-412

Thermal expansion during the first heating cycle at atmospheric pressure was measured in several directions in seven igneous rocks between 25° and 400°C at slow heating rates. The coefficient of thermal expansion measured under these conditions increases more rapidly as temperature is increased than the average thermal expansion coefficient of the constituent minerals. The “extra” expansion is attributed to the formation of cracks by differential expansion of mineral grains. The presence of such cracks in the rocks during the cooling part of the cycle and during any subsequent heating and cooling cycles will result in a substantial decrease in the coefficient of thermal expansion as compared to that measured during the first heating cycles. The effect of cracks initially present in a rock was studied by measuring the full tensor of the coefficient of thermal expansion on two rocks with anisotropic crack distributions. In these two rocks the coefficient of thermal expansion is least in the direction perpendicular to the plane of greatest crack concentration. The implication of our data is that thermal expansion depends greatly on the fracture state of the rock. Both the fractures in the rock and the boundary conditions on the rock are significant for the interpretation of thermal expansion measurements and for their application to other problems.  相似文献   

Armalcolite stability as a function of pressure and oxygen fugacity     

John J Friel  R.Ian Harker  Gene C Ulmer 《Geochimica et cosmochimica acta》1977,41(3):403-410

The stability of synthetic armalcolite of composition (Fe_0.5Mg_0.5Ti₂O₅ was studied as a function of total pressure up to 15 kbar and 1200°C and also as a function of oxygen fugacity (?O₂) at 1200°C and 1 atm total pressure. The high pressure experiments were carried out in a piston-cylinder apparatus using silver-palladium containers. At 1200°C, armalcolite is stable as a single phase at 10 kbar. With increasing pressure, it breaks down ($\text{dT}\text{dP}\text{= 20°C/}\text{kbar}$), to rutile, a more magnesian armalcolite, and ilmenite solid solution. At 14 kbar, this three-phase assemblage gives way ($\text{dT}\text{dP}\text{= 30°C/}\text{kbar}$) to a two-phase assemblage of rutile plus ilmenite solid solution.A zirconian-armalcolite was synthesized and analyzed; 4 wt % ZrO₂ appears to saturate armalcolite at 1200°C and 1 atm. The breakdown of Zr-armalcolite occurs at pressures of 1–2 kbar less than those required for the breakdown of Zr-free armalcolite. The zirconium partitions approximately equally between rutile and ilmenite phases.The stability of armalcolite as a function of ?O₂ was determined thermogravimetrically at 1200°C and 1 atm by weighing sintered pellets in a controlled atmosphere furnace. Armalcolite, (Fe_0.5Mg_0.5)-Ti₂O₅, is stable over a range ?O₂ from about 10^?9.5to 10^?10.5 atm. Below this range to at least 10^?12.8 atm, ilmenite plus a reduced armalcolite are formed. These products were observed optically and by Mössbauer spectroscopy, and no metallic iron was detected; therefore, some of the titanium must have been reduced to Ti³⁺. This reduction may provide yet another mechanism to explain the common association of ilmenite rims around lunar armalcolites.  相似文献