Abiotic formation of hydrocarbons under hydrothermal conditions: Constraints from chemical and isotope data   总被引：1，自引：0，他引：1  

Qi Fu  Barbara Sherwood Lollar  Georges Lacrampe-Couloume 《Geochimica et cosmochimica acta》2007,71(8):1982-1998

To understand reaction pathways and isotope systematics during mineral-catalyzed abiotic synthesis of hydrocarbons under hydrothermal conditions, experiments involving magnetite and CO₂ and H₂-bearing aqueous fluids were conducted at 400 °C and 500 bars. A robust technique for sample storage and transfer from experimental apparatus to stable isotope mass spectrometer provides a methodology for integration of both carbon and hydrogen isotope characterization of reactants and products generated during abiogenic synthesis experiments. Experiments were performed with and without pretreatment of magnetite to remove background carbon associated with the mineral catalyst. Prior to experiments, the abundance and carbon isotope composition of all carbon-bearing components were determined. Time-series samples of the fluid from all experiments indicated significant concentrations of dissolved CO and C₁-C₃ hydrocarbons and relatively large changes in dissolved CO₂ and H₂ concentrations, consistent with formation of additional hydrocarbon components beyond C₃. The existence of relatively high dissolved alkanes in the experiment involving non-pretreated magnetite in particular, suggests a complex catalytic process, likely involving reinforcing effects of mineral-derived carbon with newly synthesized hydrocarbons at the magnetite surface. Similar reactions may be important mechanisms for carbon reduction in chemically complex natural hydrothermal systems. In spite of evidence supporting abiotic hydrocarbon formation in all experiments, an “isotopic reversal” trend was not observed for ¹³C values of dissolved alkanes with increasing carbon number. This may relate to the specific mechanism of carbon reduction and hydrocarbon chain growth under hydrothermal conditions at elevated temperatures and pressures. Over time, significant ¹³C depletion in CH₄ suggests either depolymerization reactions occurring in addition to synthesis, or reactions between the C₁-C₃ hydrocarbons and carbon species absorbed on mineral surfaces and in solution.  相似文献   

A continuum-based model on axial pile-head dynamic impedance in inhomogeneous soil     

Qu  Liming  Yang  Changwei  Ding  Xuanming  Kouroussis  Georges  Zheng  Changjie 《Acta Geotechnica》2021,16(10):3339-3353

Acta Geotechnica - This paper presents a closed-form solution on the steady dynamic response of circular piles embedded in inhomogeneous soil. The soil is modeled as a viscoelastic continuum, and...  相似文献   

Active hydrothermal fluids circulation triggering small-scale collapse events: the case of the 2001–2002 fissure in the Lakki Plain (Nisyros Island,Aegean Sea,Greece)     

Stefania Venturi  Franco Tassi  Orlando Vaselli  Georges E. Vougioukalakis  Heba Rashed  Christos Kanellopoulos  Chiara Caponi  Francesco Capecchiacci  Jacopo Cabassi  Andrea Ricci  Luciano Giannini 《Natural Hazards》2018,90(2):601-621

Rip currents are fast moving, offshore flows that have the ability to move even the strongest swimmers into deeper waters. Miami Beach, Florida is one of the most visited beaches in the USA and a sought after destination for citizens and international tourists alike. It is also known to be a rip current “hot spot.” These factors greatly increase the risk of drowning; however, no previous research has focused on beachgoer perception of rip-related risks in South Florida. Over a 12-month period, 203 public surveys were collected to determine the rip current knowledge of beachgoers at Miami Beach based on factors such as swimming ability and frequency of beach visits. The responses were analyzed by constructing a normalized component factor to determine the respondent’s comprehensive knowledge of rips, and multiple regression models were used to assess the net influences of sociodemographic and behavioral characteristics on the responses. A significant proportion of the survey respondents showed insufficient knowledge, indicating they are at risk of drowning in a rip current. Frequent beachgoer’s exposure to the beach environment, maturation, and nativity is identified as the main contributors to knowledge net of other sociodemographic compositions. The most at-risk groups were determined to be young adults, foreign tourists, poor swimmers, and those who infrequently visited the beach. Miami Beach needs to initiate a rip current safety campaign to target these at-risk beachgoers, where interventions beyond familial and educational institutions should be introduced.  相似文献   

Did the massive magnetite “lava flows” of El Laco (Chile) form by magmatic or hydrothermal processes? New constraints from magnetite composition by LA-ICP-MS   总被引：2，自引：0，他引：2  

Sarah?A.?S.?DareEmail author  Sarah-Jane?Barnes  Georges?Beaudoin 《Mineralium Deposita》2015,50(5):607-617

The El Laco magnetite deposits consist of more than 98 % magnetite but show field textures remarkably similar to mafic lava flows. Therefore, it has long been suggested that they represent a rare example of an effusive Fe oxide liquid. Field and petrographic evidence, however, suggest that the magnetite deposits represent replacement of andesite flows and that the textures are pseudomorphs. We determined the trace element content of magnetite by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) from various settings at El Laco and compared them with magnetite from both igneous and hydrothermal environments. This new technique allows us to place constraints on the conditions under which magnetite in these supposed magnetite “lava flows” formed. The trace element content of magnetite from the massive magnetite samples is different to any known magmatic magnetite, including primary magnetite phenocrysts from the unaltered andesite host rocks at El Laco. Instead, the El Laco magnetite is most similar in composition to hydrothermal magnetite from high-temperature environments (>500 °C), such as iron oxide-copper-gold (IOCG) and porphyry-Cu deposits. The magnetite trace elements from massive magnetite are characterised by (1) depletion in elements considered relatively immobile in hydrothermal fluids (e.g. Ti, Al, Cr, Zr, Hf and Sc); (2) enrichment in elements that are highly incompatible with magmatic magnetite (rare earth elements (REE), Si, Ca, Na and P) and normally present in very low abundance in magmatic magnetite; (3) high Ni/Cr ratios which are typical of magnetite from hydrothermal environments; and (4) oscillatory zoning of Si, Ca, Mg, REE and most high field strength elements, and zoning truncations indicating dissolution, similar to that formed in hydrothermal Fe skarn deposits. In addition, secondary magnetite in altered, brecciated host rock, forming disseminations and veins, has the same composition as magnetite from the massive lenses. Euhedral magnetite lining both open-spaced veins in the brecciated host rock and along the walls of large, hollow chimneys in the massive magnetite lenses also displays oscillatory zoning and most likely formed by fluctuating composition and/or physio-chemical conditions of the fluid. Thus, the chemical fingerprint of magnetite from the supposed El Laco magnetite lava flows supports the hydrothermal model of metasomatic replacement of andesite lava flows, by dissolution and precipitation of magnetite from high-temperature fluids, rather than a magmatic origin from an effusive Fe oxide liquid.  相似文献   

50 years Mineralium Deposita     

Bernd Lehmann  Georges Beaudoin 《Mineralium Deposita》2015,50(1):1-3

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Mineralogy and geochemistry of pozzolans from the Tombel Plain,Bamileke Plateau,and Noun Plain monogenetic volcanoes in the central part of the Cameroon Volcanic Line     

Fulbert  Mbowou Ngantche Igor  Sébastien  Owona  Boris  Chako Tchamabe  Justin  Lissom  Bruno  Lanson  Emmanuel  Ekodeck Georges 《中国地球化学学报》2020,39(6):830-861

Acta Geochimica - Pozzolans from the Tombel Plain, Bamileke Plateau, and Noun Plain, 3 monogenetic volcanic fields in the central part of the Cameroon Volcanic Line (the Tombel Plain, Bamileke...  相似文献   

Correction to: Using Causal Inference in Field Development Optimization: Application to Unconventional Plays     

Bertoncello  Antoine  Oppenheim  Georges  Cordier  Philippe  Gourvénec  Sébastien  Mathieu  Jean-Philippe  Chaput  Eric  Kurth  Tobias 《Mathematical Geosciences》2020,52(5):637-637

Mathematical Geosciences - Unfortunately, in the original version of the article the first and second name of the fourth author were wrong.  相似文献   

Farewell to Harry M. Parker (1946–2019)     

Searston  Stella  Smith  Larry B.  Verly  Georges 《Mathematical Geosciences》2020,52(4):447-450

Mathematical Geosciences -  相似文献   

Simulation of subcritical flow at open-channel junction     

Georges Kesserwani  Rabih Ghostine  José Vazquez  Robert Mosé  Maher Abdallah  Abdellah Ghenaim 《Advances in water resources》2008

The spectrum of this survey turns on the evaluation of various existing theoretical combining models, when invoked within the internal boundary condition management at a junction. Based on the assumption that: when the Froude number is low (i.e. the flow is subcritical), the energy equation at the junction can be approximated by the stages heads equality. Actual literature and many commercial packages rather use this concept for the treatment of the junction’s internal boundary handling because it is easy to implement and it avoids the solving of nonlinear equations. In the last decade, many nonlinear combining models, based on the momentum conservation through the junction, have been reported. However, using them to operate within the internal boundary condition treatment of an open-channel confluence has not yet been investigated. Hence, this research focuses on studying the practical aspect of several combining models, once applied within the junction’s internal boundary management. Therefore, the recent nonlinear models of Gurram, Hsu and Shabayek have been briefly detailed together with the traditional concept of assuming water stages equality at the junction. Subsequently, an experimental examination was performed according to available experiments as mean to pre-evaluate (separately at the junction) the four junction models in the steady state. Moreover, according to the latter inspection the attention was constrained to study the effect of high/low subcritical Froude number at the junction. Finally, two hypothetical hydraulic problems were defined and computed in order to exhibit the performance of these junction models when used to contend the junction’s internal boundary handling. The problems involved: (a) steady and transient flows; (b) high and low (subcritical) Froude number at the junction. Supported by the experimental and numerical investigations, it can be concluded that even while the Froude number spectrum is subcritical, precautions have to be taken when dealing with the concept of energy heads equality, notably for a Froude higher than 0.35 at the junction.  相似文献   

On the Mass Balance of Low Latitude Glaciers with Particular Consideration of the Peruvian Cordillera Blanca   总被引：1，自引：0，他引：1  

Georg Kaser  & Christian Georges 《Geografiska Annaler: Series A, Physical Geography》1999,81(4):643-651

Glacier mass balance studies in the low latitudes are rare and glaciological methods and terminology are basically adapted from mid- and high latitude conditions. The low latitudes are considered to be the tropics and, to some extent, the adjoining dry subtropics. The outer tropics are proposed as an intermediate zone with tropical character during the humid season and subtropical character during the dry season. Delimitations as well as respective climate and glacier regimes are discussed in order to distinguish them from each other and from the mid-latitudes. Different sensitivities of the glaciers can be expected and promise, in turn, a complex climatological interpretation of glacier fluctuations. For this, detailed mass balance studies on low latitude glaciers are required. The respective discussion is concentrated on the Peruvian Cordillera Blanca whose topographical setting provides both spatial and temporal subdivisions in humid and dry regimes in one region. However, theoretical considerations and field experience show problems for the determination of mass balance variables in the Cordillera Blanca and the low latitudes in general. The absence of annual temperature variations hinders the development of impermeable layers which can be identified as annual reference layers and which prevent meltwater from percolating into the firn body. Thus, a combination of ablation measurements and the application of the flux divergence method for the determination of accumulation is proposed.  相似文献