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221.
Eleonora Braschi Lorella Francalanci Georges E. Vougioukalakis 《Bulletin of Volcanology》2012,74(5):1083-1100
Based on detailed field, petrographic, chemical, and isotopic data, this paper shows that the youngest magmas of the active Nisyros volcano (South Aegean Arc, Greece) are an example of transition from rhyolitic to less evolved magmas by multiple refilling with mafic melts, triggering complex magma interaction processes. The final magmatic activity of Nisyros was characterized by sub-Plinian caldera-forming eruption (40?ka), emplacing the Upper Pumice (UP) rhyolitic deposits, followed by the extrusion of rhyodacitic post-caldera domes (about 31–10?ka). The latter are rich in magmatic enclaves with textural and compositional (basaltic–andesite to andesite) characteristics that reveal they are quenched portions of mafic magmas included in a cooler more evolved melt. Dome-lavas have different chemical, isotopic, and mineralogical characteristics from the enclaves. The latter have lower 87Sr/86Sr and higher 143Nd/144Nd values than dome-lavas. Silica contents and 87Sr/86Sr values decrease with time among dome-lavas and enclaves. Micro-scale mingling processes caused by enclave crumbling and by widespread mineral exchanges increase from the oldest to the youngest domes, together with enclave content. We demonstrate that the dome-lavas are multi-component magmas formed by progressive mingling/mixing processes between a rhyolitic component (post-UP) and the enclave-forming mafic magmas refilling the felsic reservoir (from 15?wt.% to 40?wt.% of mafic component with time). We recognize that only the more evolved enclave magmas contribute to this process, in which recycling of cumulate plagioclase crystals is also involved. The post-UP end-member derives by fractional crystallization from the magmas leftover after the previous UP eruptions. The enclave magma differentiation develops mainly by fractional crystallization associated with multiple mixing with mafic melts changing their composition with time. A time-related picture of the relationships between dome-lavas and relative enclaves is proposed, suggesting a delay between a mafic magma input and the relative dome outpouring. We also infer that the magma viscosity reduction by re-heating allows dome extrusion without explosive activity. 相似文献
222.
Ayman Georges Awadallah Abdelrahman Younis Elsayed Ahmed Mohammed Abdelbaky 《Arabian Journal of Geosciences》2017,10(20):456
The temporal distribution of the design storm is an important input in hydrological models. This research aims to develop design storm profiles representative of arid and hyper-arid areas based on actual storm recordings. Two hundred thirty-six rainfall storms were collected from seventeen rainfall gauges that cover the coastal zone of Oman for the period from 1993 to 2007. Storms were classified into four categories according to their total durations. Design storm hyetographs were derived from raw rainfall records for all four categories using the Alternating Block Method (ABM) and were also computed by ABM applied on the Intensity-Duration-Frequency (IDF) curves. Both design storm profiles were compared and it was found that the ABM_IDF storm profiles were equivalent to the four ABM_Storms profiles from a practical point of view as they produce similar peak discharges. The storm profiles developed in the current research were also compared to the commonly used Soil Conservation Service (SCS) dimensionless distributions and the UK50 storm profiles. The results showed that the most conservative commonly used SCS type II and the UK50 summer profiles are not safe to be used in design purposes in arid and hyper arid regions, despite their wide utilization in many codes of practice in these regions. The study recommends using the newly developed dimensionless storm profiles derived from the actual records. 相似文献
223.
Georges Durry Alain Hauchecorne Joelle Ovarlez Henri Ovarlez Ivan Pouchet Virginie Zeninari Bertrand Parvitte 《Journal of Atmospheric Chemistry》2002,43(3):175-194
Telecommunication laser diodes emitting near 1.39 m and 1.65 m in combination with direct-differential absorption spectroscopy are efficient tools to monitor in situ stratospheric H2O andCH4 with a good precision error (a few percents), a high temporal resolution (ranging from 10 ms to 1 s), a large dynamic range in the concentration measurements (four orders of magnitude) and a high selectivity in the analyte species. To illustrate the capability of laser probing technique, we report balloonborne H2Oand CH4 simultaneous measurements obtained on October 2001 atmidlatitudes (43° N). The H2O vertical profile achieved with the lasersensor in the lower stratosphere is compared with the H2O data yielded by a balloonborne frost-point hygrometer. The total hydrogen mixing ratio in the lower stratosphere, 2[CH4] + [H2O], appears to beconstant at 7.5 ± 0.1 ppmv. Nevertheless, an unexpected largedehydration of 0.5 ppmv was detected by both the laser sensor and thehygrometer between 16 km and 23 km. We suspect the occurrence of a tropicalair intrusion into mid-latitudes. We support this interpretation using a high-resolution advection model for potential vorticity. 相似文献
224.
The method applied since 1996 for the analysis of the orbital residuals of the LAGEOS satellites in order to measure the Lense-Thirring effect has been the subject of the present work. This method, based on the difference between the orbital elements of consecutive arcs, is explained and analysed also from the analytical point of view. It is proved that this “difference method” works well for the determination of the secular effects, as in the case of the relativistic precession induced by the Earth's angular momentum, but also very useful for the determination and study of the long-term periodic effects. Indeed, the only limitation in the determination of the periodic effects is the possibility of the reduction of their amplitude by a factor which depends from the periodicity of the given perturbation and from the orbital arc length chosen for the satellite during the data analysis. In the case of the Yarkovsky-Schach effect, the main non-gravitational perturbation seen in the LAGEOS satellites orbital residuals, in particular in its perigee rate and eccentricity vector excitation residuals, we show that the “difference method” is quite good also for the determination of the long-period perturbations induced by this subtle non-conservative force. 相似文献
225.
Maresca J. Jr. Georges T. Carlson C. Riley J. 《Oceanic Engineering, IEEE Journal of》1986,11(2):180-186
An estimate of the coverage efficiency of a high-frequency (HF) skywave (ionospheric) radar for mapping ocean wave height and surface wind direction at ranges between 1000 and 3000 km was made for two different but common operational ocean-monitoring applications. In the first test, three days in duration, wind direction and wave height were mapped over the entire coverage area. In the second test, four days in duration, wind direction was mapped over the entire coverage area and wave height was mapped at preselected small regions within the coverage area. On-line quality assessment and real-time ionospheric diagnostics helped select space-time-frequency windows with low ionospheric distortion. Wind direction over the 4 000 000-km2coverage area was mapped every day with the Wide Aperture Research Facility (WARF) skywave radar in about 1 h. For large-area wave-height mapping, 6 h was allowed, and for the coverage of a smaller grid, 3 h was allowed. Within these time windows, high-confidence wave-height measurements were obtained at 59 percent of the locations attempted, using on-line processing for both tests. When postexperiment processing was included, the coverage efficiency increased to 74 percent. Greater efficiencies would be possible operationally with more experience and more sophisticated radars. Eliminating the First day's results from the statistics shows the effects of increased operating experience. Then the overall on-line efficiency increases to 69 percent, and the off-line increases to 82 percent for the six days of the two tests. 相似文献
226.
Etienne Balan Thierry Allard Madeleine Sélo François Chabaux Georges Calas 《Geochimica et cosmochimica acta》2005,69(9):2193-2204
The content of radiation-induced defects (RIDs) in kaolinite samples originating from lateritic soils and continental detritic sediments of the middle Amazon Basin (Brazil) is investigated using electron paramagnetic resonance. The paleodose registered by kaolinites ranges from 80 to 900 kGy. Present-day dose rates of radiation, determined from the whole-rock U and Th content, range between 4000 and 40,000 mGy/ka. In most samples, U and Th concentrations are correlated, suggesting that U has not been remobilized by lateritization. This observation is consistent with the fact that ∼80% of the total U content is incorporated in resistant minerals, such as zircon and Ti oxides. The heterogeneous distribution of U, observed by induced fission tracks mapping, makes it possible to neglect the α-radiation contribution of the U decay chains in the dose-rate calculation. The interpretation of the measured content of RIDs in kaolinite is then performed using the calculated present-day dose rate and assuming equilibrium in the radioactive decay chains. For the sedimentary samples, the amount of RIDs is broadly correlated to the dose rate and provides apparent absolute ages older than 20 Ma. The RID contents in kaolinites from the lateritic soils provide apparent ages ranging from 10 to 6 Ma. The high RID content of these lateritic kaolinites shows that their chemical, isotopic, and crystallographic properties are not representative of present-day weathering conditions. Models assuming the “dynamical equilibrium” of kaolinites with local physical-chemical conditions prevailing in lateritic soils are thus questionable. Alternatively, our findings bring strong support for the use of the isotopic composition of kaolinites to decipher continental paleo-climates. 相似文献
227.
228.
Stable and radiogenic isotope composition of stratiform Cu–Co–Zn mineralization and associated sedimentary rocks within the Boléo district of the Miocene Santa Rosalía basin, Baja California Sur, constrains the evolution of seawater and hydrothermal fluids and the mechanisms responsible for sulfide and oxide deposition. Stable isotope geochemistry of limestone and evaporite units indicates a strong paleogeographic influence on the chemistry of the water column. Near-shore limestone at the base of the Boléo Formation is characterized by modified marine carbon (δ
13CPDB=−6.0 to +4.4‰) and oxygen (δ
18OSMOW=+19.5 to +26.2‰) isotope composition due to the influx of 13C- and 18O-depleted fluvial water. Sulfate sulfur isotope composition (δ
34SCDT=+17.21 to +22.3‰ and δ
18OSMOW=+10.7 to +13.1‰) for basal evaporite and claystone facies are similar to Miocene seawater. Strontium isotopes are less radiogenic than expected for Miocene seawater due to interaction with volcanic rocks. Low S/C ratios, high Mn contents and sedimentological evidence indicate the basin water column was oxidizing. The oxygenated basin restricted sulfide precipitation to within the sedimentary pile by replacement of early diagenetic framboidal pyrite and pore-space filling by Cu–Co–Zn sulfides to produce disseminated sulfides. Quartz–Mn oxide oxygen isotope geothermometry constrains mineralization temperature between 18 and 118°C. Sulfur isotopes indicate the following sources of sulfide: (1) bacterial sulfate reduction within the sedimentary pile produced negative δ
34S values (<−20‰) in framboidal pyrite; and (2) bacterial sulfate reduction at high temperature (80–118°C) within the sedimentary pile during the infiltration of the metal-bearing brines produced Cu–Co–Zn sulfides with negative, but close to 0‰, δ
34S values. Isotope modeling of fluid-rock reaction and fluid mixing indicates: (1) sedimentary and marine carbonates (δ
13C=−11.6 to −3.2‰ and δ
18O=+19.0 to +21.8‰) precipitated from basin seawater/pore water that variably mixed with isotopically depleted meteoric waters; and (2) hydrothermal calcite (δ
13C=−7.9 to +4.3‰ and δ
18O=+22.1 to +25.8‰) formed by dissolution and replacement of authigenic marine calcite by downward-infiltrating metalliferous brine and brine-sediment exchange, that prior to reaction with calcite, had mixed with isotopically depleted pore water. The downward infiltration of metalliferous brine is inferred from lateral and stratigraphic metal distributions and from the concentration of Cu sulfides along the upper contact of pyrite-bearing laminae. The co-existence and textural relationships among framboidal pyrite, base metal sulfides, carbonate and Mn–Fe oxides (including magnetite) within mineralized units are consistent with carbonate replacement and high-temperature bacterial reduction within the sedimentary pile occurring simultaneously below a seawater column under predominantly oxygenated conditions. 相似文献
229.
Huguette C. Emvoutou Béatrice Ketchemen Tandia Suzanne Ngo Boum Nkot Rodrigue C. S. Ebonji Yvon B. Nlend Georges E. Ekodeck Christine Stumpp Piotr Maloszewski Serigne Faye 《Environmental Earth Sciences》2018,77(5):219
Douala city, located in the littoral province of Cameroon, receives abundant rainfall quantities due to its geographical position in the Gulf of Guinea and bears considerable surface water and groundwater resources. Due to socioeconomic development and rapid demographic growth in the city and its consequences of unplanned urbanization and improper sanitation system, these water resources are poorly protected and managed. Streams in the Wouri watershed receive large amounts of wastewater discharge, and hundreds of boreholes have been drilled into the aquifer system without any management plan. A detailed hydrodynamic and hydrogeochemistry study in Douala town and its environs was conducted to get a better insight into the groundwater system functioning in order to provide information for the sustainable management and protection of the groundwater resource. Two field campaigns were carried out with 187 samples collected and analyzed for major ions, stable isotopes (18O, 2H), and tritium 3H. The results of the sampling have shown that the weathering of silicate minerals is the dominant geochemical process affecting groundwater chemistry in this system. However, acid rainfall in the humid climate has also caused carbonate mineral dissolution, amorphous silica deposition, and ion exchange reactions to occur in aquifers in the region. The various water types identified were categorized into four major clusters C1 to C4, based on the major ion composition and the local hydrogeological conditions. Environmental isotope data reveal that modern-to-submodern waters occur in the phreatic Quaternary/Mio-Pliocene and Oligocene/Upper Eocene aquifers, respectively. These results corroborate with the conceptual model built where modern groundwater types indicated silicate mineral weathering and calcite dissolution (C1 and C2), whereas submodern groundwater mostly showed silica deposition, ion exchange, and, to a lesser extent, carbonate mineral dissolution (C3 and C4). This improved understanding of the aquifer system functioning is essential to provide a reasonable basis for effective control measures and sustainable water management. 相似文献
230.
Philippe Blanc Hélène Gailhanou Jacques Rogez Georges Mikaelian Hitoshi Kawaji Fabienne Warmont Stéphane Gaboreau Sylvain Grangeon Jean-Marc Grenèche Philippe Vieillard Claire I. Fialips Eric Giffaut Eric C. Gaucher F. Claret 《Physics and Chemistry of Minerals》2014,41(8):603-615
In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al0.975FeIII0.182FeII1.422Mg0.157Li0.035Mn0.002)(Si1.332Al0.668)O5(OH)4] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si2.633Al1.367)(Al1.116FeIII0.215Mg2.952FeII1.712Mn0.012Ca0.011)O10(OH)8]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature. 相似文献