Intercomparison of measurements of stratospheric hydrogen fluoride     

William G. Mankin  M. T. Coffey  K. V. Chance  W. A. Traub  B. Carli  F. Mencaraglia  S. Piccioli  I. G. Nolt  J. V. Radostitz  R. Zander  G. Roland  Douglas W. Johnson  Gerald M. Stokes  C. B. Farmer  R. K. Seals 《Journal of Atmospheric Chemistry》1990,10(2):219-236

Observations of the vertical profile of hydrogen fluoride (HF) vapor in the stratosphere and of the vertical column amounts of HF above certain altitudes were made using a variety of spectroscopic instruments in the 1982 and 1983 Balloon Intercomparison Campaigns. Both emission instruments working in the far infrared spectral region and absorption instruments using solar occultation in the 2.5m region were employed. No systematic differences were seen in results from the two spectral regions. A mean profile from 20–45 km is presented, with uncertainties ranging from 20% to 50%. Total columns measured from ground and from 12 km are consistent with the profile if the mixing ratio for HF is small in the tropophere and low stratosphere.  相似文献   

H,O, Sr,Nd, and Pb isotope geochemistry of the Latir volcanic field and cogenetic intrusions,New Mexico,and relations between evolution of a continental magmatic center and modifications of the lithosphere   总被引：2，自引：0，他引：2  

Clark M. Johnson  Peter W. Lipman  Gerald K. Czamanske 《Contributions to Mineralogy and Petrology》1990,104(1):99-124

Over 200 H, O, Sr, Nd, and Pb isotope analyses, in addition to geologic and petrologic constraints, document the magmatic evolution of the 28.5–19 Ma Latir volcanic field and associated intrusive rocks, which includes multiple stages of crustal assimilation, magma mixing, protracted crystallization, and open- and closed-system evolution in the upper crust. In contrast to data from younger volcanic centers in northern New Mexico, relatively low and restricted primary ¹⁸O values (+6.4 to +7.4) rule out assimilation of supracrustal rocks enriched in ¹⁸O. Initial ⁸⁷Sr/⁸⁶Sr ratios (0.705 to 0.708), ¹⁸O values (-2 to-7), and ²⁰⁶Pb/²⁰⁴Pb ratios (17.5 to 18.4) of metaluminous precaldera volcanic rocks and postcaldera plutonic rocks suggest that most Latir rocks were generated by fractional crystallization of substantial volumes of mantle-derived basaltic magma that had near-chondritic Nd isotope ratios, accompanied by assimilation of crustal material in two main stages: 1) assimilation of non-radiogenic lower crust, followed by 2) assimilation of middle and upper crust by inter-mediate-composition magmas that had been contaminated during the first stage. Magmatic evolution in the upper crust peaked with eruption of the peralkaline Amalia Tuff (26 Ma), which evolved from metaluminous parental magmas. A third stage of late, roofward assimilation of Proterozoic rocks in the Amalia Tuff magma is indicated by trends in initial ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb ratios from 0.7057 to 0.7098 and 19.5 to 18.8, respectively, toward the top of the pre-eruptive magma chamber. Highly evolved postcaldera plutons are generally fine grained and are zoned in initial ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb ratios, varying from 0.705 to 0.709 and 17.8 to 18.6, respectively. In contrast, the coarser-grained Cabresto Lake (25 Ma) and Rio Hondo (21 Ma) plutons have relatively homogeneous initial ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb ratios of approximately 0.7053 and 17.94 and 17.55, respectively. ¹⁸O values for all the postcaldera plutons overlap those of the precaldera rocks and Amalia Tuff, except for those for two late-stage rhyolite dikes associated with the Rio Hondo pluton that have ¹⁸O values of-8.6 and-9.5; these dikes are the only Latir rocks which may be largely crustal melts.Chemical and isotopic data from the Latir field suggest that large fluxes of mantle-derived basaltic magma are necessary for developing and sustaining large-volume volcanic centers. Development of a detailed model suggests that 6–15 km of new crust may have been added beneath the volcanic center; such an addition may result in significant changes in the chemical and Sr and Nd isotopic compositions of the crust, although Pb isotope ratios will remain relatively unchanged. If accompanied by assimilation, crystallization of pooled basaltic magma near the MOHO may produce substantial cumulates beneath the MOHO that generate large changes in the isotopic composition of the upper mantle. The Latir field may be similar to other large-volume, long-lived intracratonal volcanic fields that fundamentally owe their origins to extensive injection of basaltic magma into the lower parts of their magmatic systems. Such fields may overlie areas of significant crustal growth and hybridization.  相似文献   

Insight into the structure of the Upper Rhine Graben and its basement from a new compilation of Bouguer Gravity     

Y. Rotstein  J.-B. Edel  G. Gabriel  D. Boulanger  M. Schaming  M. Munschy 《Tectonophysics》2006,425(1-4):55-70

A compilation of gravity data from the Upper Rhine Graben (URG) is presented that includes all the main data sources from its German and French parts. This data is used to show that the URG consists of, at least, two arc-shaped and asymmetric rift units that tectonically are the basic building blocks of the graben. In this sense the URG does not differ from other continental rifts, such as the African rifts. This division should replace the now classical geomorphologic division of the URG into three segments, based on their different trends. Moreover, the gravity suggests that the faults in the central and southern segments are continuous and have the same trend, appearing to respond as a single kinematic unit. Changes in the gravity field in the graben are shown to reflect not only the structure of the graben, but also the highly variable composition of the basement. In this respect, the URG is quite different from some other Tertiary continental rifts, where possible changes in the composition of the basement are mostly masked in the gravity field by the effect of the overlying low-density sediments. This characteristic is used to study the extent of some of the main basement units that underlie the graben.  相似文献   

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico   总被引：1，自引：1，他引：1  

E. Leticia Flores-Márquez  Gabriel Jiménez-Suárez  Raymundo G. Martínez-Serrano  René E. Chávez  Daniel Silva Pérez 《Hydrogeology Journal》2006,14(7):1216-1230

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.  相似文献   

The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl     

Geraldo Magela da Costa  Gabriel de Oliveira Polli  Márcio A. Kahwage  Eddy de Grave  Antônio Claret Soares Sabioni  Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.  相似文献   

Short‐term erosion rates from a 7Be inventory balance     

Christopher G. Wilson  Gerald Matisoff  Peter J. Whiting 《地球表面变化过程与地形》2003,28(9):967-977

Detailed soil erosion studies bene?t from the ability to quantify the magnitude of erosion over time scales appropriate to the process. An inventory balance for ⁷Be was used to calculate sediment erosion in a 30·73 m² plot during a series of runoff‐producing thunderstorms occurring over three days at the Deep Loess Research Station in Treynor, Iowa, USA. The inventory balance included determination of the pre‐ and post‐storm ⁷Be inventories in the soil, the atmospheric in?ux of ⁷Be during the event, and pro?les of the ⁷Be activity in the soil following the atmospheric deposition. The erosion calculated in the plot using the ⁷Be inventory balance was 0·058 g cm^?2, which is 23 per cent of the annual average erosion determined using ¹³⁷Cs inventories. The calculated erosion from the mass balance is similar to the 0·059 g cm^?2 of erosion estimated from the amount of sediment collected at the outlet of the 6 ha ?eld during the study period and the delivery ratio (0·64). The inventory balance of ⁷Be provides a new means for evaluating soil erosion over the time period most relevant to quantifying the prediction of erosion from runoff. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Platinum-group elements (PGE) and rhenium in marine sediments across the Cretaceous-Tertiary boundary: constraints on Re-PGE transport in the marine environment     

Cin-Ty Aeolus Lee  Gerald J. Wasserburg 《Geochimica et cosmochimica acta》2003,67(4):655-670

The nature of Re-platinum-group element (PGE; Pt, Pd, Ir, Os, Ru) transport in the marine environment was investigated by means of marine sediments at and across the Cretaceous-Tertiary boundary (KTB) at two hemipelagic sites in Europe and two pelagic sites in the North and South Pacific. A traverse across the KTB in the South Pacific pelagic clay core found elevated levels of Re, Pt, Ir, Os, and Ru, each of which is approximately symmetrically distributed over a distance of ∼1.8 m across the KTB. The Re-PGE abundance patterns are fractionated from chondritic relative abundances: Ru, Pt, Pd, and Re contents are slightly subchondritic relative to Ir, and Os is depleted by ∼95% relative to chondritic Ir proportions. A similar depletion in Os (∼90%) was found in a sample of the pelagic KTB in the North Pacific, but it is enriched in Ru, Pt, Pd, and Re relative to Ir. The two hemipelagic KTB clays have near-chondritic abundance patterns. The ∼1.8-m-wide Re-PGE peak in the pelagic South Pacific section cannot be reconciled with the fallout of a single impactor, indicating that postdepositional redistribution has occurred. The elemental profiles appear to fit diffusion profiles, although bioturbation could have also played a role. If diffusion had occurred over ∼65 Ma, the effective diffusivities are ∼10⁻¹³ cm²/s, much smaller than that of soluble cations in pore waters (∼10⁻⁶ cm²/s). The coupling of Re and the PGEs during redistribution indicates that postdepositional processes did not significantly fractionate their relative abundances. If redistribution was caused by diffusion, then the effective diffusivities are the same. Fractionation of Os from Ir during the KTB interval must therefore have occurred during aqueous transport in the marine environment. Distinctly subchondritic Os/Ir ratios throughout the Cenozoic in the South Pacific core further suggest that fractionation of Os from Ir in the marine environment is a general process throughout geologic time because most of the inputs of Os and Ir into the ocean have Os/Ir ratios ≥1. Mass balance calculations show that Os and Re burial fluxes in pelagic sediments account for only a small fraction of the riverine Os (<10%) and Re (<0.1%) inputs into the oceans. In contrast, burial of Ir in pelagic sediments is similar to the riverine Ir input, indicating that pelagic sediments are a much larger repository for Ir than for Os and Re. If all of the missing Os and Re is assumed to reside in anoxic sediments in oceanic margins, the calculated burial fluxes in anoxic sediments are similar to observed burial fluxes. However, putting all of the missing Os and Re into estuarine sediments would require high concentrations to balance the riverine input and would also fail to explain the depletion of Os at pelagic KTB sites, where at most ∼25% of the K-T impactor’s Os could have passed through estuaries. If Os is preferentially sequestered in anoxic marine environments, it follows that the Os/Ir ratio of pelagic sediments should be sensitive to changes in the rates of anoxic sediment deposition. There is thus a clear fractionation of Os and Re from Ir in precipitation out of sea water in pelagic sections. Accordingly, it is inferred here that Re and Os are removed from sea water in anoxic marine depositional regimes.  相似文献   

Foliation fields and 3D cartography in geology: Principles of a method based on potential interpolation   总被引：4，自引：0，他引：4  

Christian Lajaunie  Gabriel Courrioux  Laurent Manuel 《Mathematical Geology》1997,29(4):571-584

A modeling method that takes into account known points on a geological interface and plane orientation data such as stratification or foliation planes is described and tested. The orientations data do not necessarily belong to one of the interfaces but are assumed to sample the main anisotropy of a geological formation as in current geological situations. The problem is to determine the surfaces which pass through the known points on interfaces and which are compatible with the orientation data. The method is based on the interpolation of a scalar field defined in the space the gradient in which is orthogonal to the orientations, given that some points have the same but unknown scalar value (points of the same interface), and that scalar gradient is known on the other points (foliations). The modeled interfaces are represented as isovalues of the interpolated field. Preliminary two-dimensional tests carried-out with different covariance models demonstrate the validity of the method, which is easily transposable in three dimensions.  相似文献   

Sampling Fauna in Stream Sediments as well as Groundwater Using One Net Sampler     

Susanne I. Schmidt  Hans J. Hahn  Gerald D. Watson  Robert J. Woodbury  Thomas J. Hatton 《洁净——土壤、空气、水》2004,32(2):131-137

Groundwater bores act as traps. Net samplers are regularly used for sampling this type of trap for fauna. To enable direct comparisons of faunal communities in groundwater bores and stream sediments, stream sediment tubes were built similar to groundwater bores and were sampled with net samplers for fauna. These stream sediment tubes consisted of a tube anchored in the stream sediment, also called interstitial space. To test the efficacy of this trap method in stream sediments, it was compared to another type of trap, Hahn's trap. Faunal communities sampled by a net in the stream sediment tubes did not differ hugely from fauna in Hahn's trap samples. Physical and chemical factors of sampled water in both the stream sediment tubes, the surrounding interstitial sediments and the second type of traps, Hahn's traps, showed that water in both the tubes and Hahn's traps was closely related to interstitial water. The net sampler is inexpensive and easy to handle. It is suggested that sampling stream tubes with nets may be an appropriate method for long‐term monitoring studies.  相似文献   

Rivers turned to rock: Late Quaternary alluvial induration influencing the behaviour and morphology of an anabranching river in the Australian monsoon tropics     

Gerald C. Nanson  Brian G. Jones  David M. Price  Timothy J. Pietsch 《Geomorphology》2005,70(3-4):398

Late Quaternary alluvial induration has greatly influenced contemporary channel morphology on the anabranching Gilbert River in the monsoon tropics of the Gulf of Carpentaria. The Gilbert, one of a number of rivers in this region, has contributed to an extensive system of coalescing low-gradient and partly indurated riverine plains. Extensive channel sands were deposited by enhanced flow conditions during marine oxygen isotope (OI) Stage 5. Subsequent flow declined, probably associated with increased aridity, however, enhanced runoff recurred again in OI Stages 4–3 (65–50 ka). Aridity then capped these plains with 4–7 m of mud. A widespread network of sandy distributary channels was incised into this muddy surface from sometime after the Last Glacial Maximum (LGM) to the mid Holocene during a fluvial episode more active than the present but less so than those of OI Stages 5 and 3. This network is still partly active but with channel avulsion and abandonment now occurring largely proximal to the main Gilbert flow path.A tropical climate and reactive catchment lithology have enhanced chemical weathering and lithification of alluvium along the river resulting in the formation of small rapids, waterfalls and inset gorges, features characteristic more of bedrock than alluvial systems. Thermoluminescence (TL) and comparative optically stimulated luminescence (OSL) ages of the sediments are presented along with U/Th ages of pedogenic calcrete and Fe/Mn oxyhydroxide/ oxide accumulations. They show that calcrete precipitated during the Late Quaternary at times similar to those that favoured ferricrete formation, possibly because of an alternating wet–dry climate. Intense chemical alteration of the alluvium leading to induration appears to have prevailed for much of the Late Quaternary but, probably due to exceptional dryness, not during the LGM. The result has been restricted channel migration and a reduced capacity for the channel to adjust and accommodate sudden changes in bedload. Consequent avulsions have caused local stream powers to increase by an order of magnitude, inducing knickpoint erosion, local incision and the sudden influx of additional bedload that has triggered further avulsions. The Gilbert River, while less energetic than its Pleistocene ancestors, is clearly an avulsive system, and emphasizes the importance in some tropical rivers of alluvial induration for reinforcing the banks, generating nickpoints, reworking sediment and thereby developing and maintaining an indurated and anabranching river style.  相似文献