Mass fluxes of xenobiotics below cities: challenges in urban hydrogeology     

Mario Schirmer  Frido Reinstorf  Sebastian Leschik  Andreas Musolff  Ronald Krieg  Gerhard Strauch  John W. Molson  Marion Martienssen  Kristin Schirmer 《Environmental Earth Sciences》2011,64(3):607-617

Urban areas are the focus of major ecological, social and economical activity. They are thus also prime locations of increasing conflict with regard to water use and water protection. As a direct and/or indirect consequence of urban land use and human activity, urban water systems are frequently polluted with organic contaminants including waste water-born xenobiotics such as pharmaceuticals, personal care products (collectively known as PPCPs) and endocrine-active substances. This study reviews new integrated methodologies including flux calculations as well as chemical investigations for determining the impact of human activities on urban water systems and on processes within the urban watershed. The use of indicator substances, representing different contaminant sources and pathways, integral pumping tests and mass balance approaches are suitable alternatives within these environments. The issues are explored using contaminant mass balance examples from Halle/Saale and Leipzig, Germany.  相似文献   

Dynamics of multiple intertidal bars over semi‐diurnal and lunar tidal cycles,North Lincolnshire,England     

Selma van Houwelingen  Gerhard Masselink  Joanna Bullard 《地球表面变化过程与地形》2008,33(10):1473-1490

Multiple intertidal bars are common features of wave‐dominated sandy beaches, yet their short‐term (<1 month) and small‐scale (<1 km) morphology and dynamics remain poorly understood. This study describes the morphodynamics of multiple intertidal bars in North Lincolnshire, England, during single and lunar tidal cycles under two contrasting conditions – first when significant wave height was <0·5 m and second when significant wave height frequently exceeded 1 m. The relative importance of swash, surf and shoaling processes in determining morphological change was examined using detailed field observations and a numerical model. The beach featured four intertidal bars and both cross‐shore and longshore bar morphology evolved during the field investigation, particularly under medium to high wave‐energy conditions. Numerical modelling suggests shoaling processes are most common on the seaward two bars under calm wave conditions (H_s < 0·5 m) and that surf zone processes become more common during neap tides and under more energetic (H_s < 0·5 m) conditions. Surf processes dominate the inner two bars, though swash influence increases in a landward direction. The numerical modelling results combined with low tide survey data and high‐resolution morphological measurements strongly suggest changes in the intertidal bar morphology are accomplished by surf zone processes rather than by shoaling wave or swash processes. This is because shoaling waves do not induce significant sediment transport to have any morphological effect, whereas swash action generally does not have enough scope to act as the swash zone is much narrower than the surf zone. It was found, however, that the absolute rate of morphological change under swash action and surfzone processes are of similar magnitudes and that swash action may induce a significant amount of local morphological change when the high tide mark is located on the upper bar, making this process important for bar morphodynamics. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Methane exchange between coal-bearing basins and the atmosphere: the Ruhr Basin and the Lower Rhine Embayment, Germany   总被引：1，自引：0，他引：1  

Thomas Thielemann  Andreas Lücke  Gerhard H. Schleser  Ralf Littke   《Organic Geochemistry》2000,31(12):121

A precise knowledge of methane exchange processes is required to fully understand the recent rise of atmospheric methane concentration. Three of these processes take place at the lithosphere/atmosphere boundary: bacterial consumption of methane and emission of bacterial or thermogenic methane. This study was initiated to quantify these processes on a regional scale in the Ruhr Basin and the Lower Rhine Embayment. Since these areas are subject to bituminous coal and lignite mining, natural and anthropogenically-induced methane exchange processes could be studied. The methane emission and consumption rates and their carbon isotope signal were measured at the lithosphere/atmosphere boundary using flux chambers. On most of the soils studied, methane consumption by bacteria was identified. Thermogenic methane was released only at some of the natural faults examined. In active and abandoned bituminous coal mining areas methane emissions were restricted to small areas, where high emission rates were measured. The carbon isotope composition of methane at natural faults and in mining subsidence troughs was typical of thermogenic methane (−45 to −32 ‰ δ¹³C). Methane exchange balancing revealed that natural methane emissions from these two basins represent no source of atmospheric importance. However, methane release by upcast mining shafts dominates the methane exchange processes and is by about two orders of magnitude greater than methane consumption by bacterial oxidation in the soils.  相似文献   

Stellar dynamics in the Galactic Centre: proper motions and anisotropy     

R. Genzel  C. Pichon  A. Eckart  O. E. Gerhard  T. Ott 《Monthly notices of the Royal Astronomical Society》2000,317(2):348-374

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Electrical conductivity of the earth's crust and upper mantle   总被引：1，自引：0，他引：1  

Gerhard Schwarz 《Surveys in Geophysics》1990,11(2-3):133-161

This review summarizes recent results of electrical resistivity studies of the earth's crust and upper mantle. Where available, the data are discussed in the context of further regional geophysical information. Electrical resistivity is very sensitive to a wide range of petrological and physical parameters, e.g., to carbon, fluids, volatiles and enhanced temperatures, making electrical resistivity methods a powerful tool in crust and upper mantle investigations. Yet, the general increase in resistivity data of the crust and mantle has not ended the battle of explanations for anomalous crustal conductivities.  相似文献   

岩石样品中低含量铂族元素和锇同位素比值的高精度测量方法   总被引：9，自引：1，他引：9  

杨竞红  GerharBRUGMANN 《岩石学报》2001,17(2):325-331

铂族元素（Os,Ir,Pt,Ru,Rh,Pd)具有强亲铁性和强亲铜性，为一组地球化学性质相近的相容元素，铂族元素包含两个同位素衰变体系（^190Pt-^186Os和^187Re-^187Os)。近年来，铂族元素和Re-Os同位素在研究各类不同地持作用过程中，尤其是在地幔岩石的研究中，作用独特，效果显著。由于地幔岩石的铂族元素含量较低，因此高精度，高灵敏度的分析测试方法的研究就显得十分重要。以往的分析方法（如常规的ICP－MS和中子活化分析方法），对含10^-9-10^012级低含量铂族元素的产品分析精度一般较差（＞15％－100％）。所采用的分析流程通常也无法同时获得样品的铂族元素含量和Os同位素比值。本文采用新的熔样方法（HAP－S高温高压釜酸溶法），新的化学流程（溶剂萃取和阴离子交换树脂柱）和新的分析仪器（多接收等离子体质谱MC－ICPMS和负离子热电离质谱N－TIMS）。用同位素稀释法对低含量地幔橄榄岩样品同时测定的铂族元素含量和Os同位素比值，获得了高精度的分析结果。对所分析的地橄榄样品中的铂族元素分配曲线和Os同位素组成的地质意义进行了初步探讨。  相似文献   

The source of oil pollution on the east frisian islands in october 1989 — an exemplary case     

Gerhard Dahlmann  Sylvin Müller-Navarra 《Ocean Dynamics》1997,49(1):35-43

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Fluid variability in 2 GPa eclogites as an indicator of fluid behavior during subduction   总被引：5，自引：0，他引：5  

Jane Selverstone  Gerhard Franz  Sabine Thomas  Stephen Getty 《Contributions to Mineralogy and Petrology》1992,112(2-3):341-357

Fluid activity ratios calculated between millimeter- to centimeter-scale layers in banded mafic eclogites from the Tauern Window, Austria, indicate that variations in a _{H 2 O} existed between layers during equilibration at P approximately equal to 2GPa and T approximately equal to 625°C, whereas a _{CO 2} was nearly constant between the same layers. Model calculations in the system H₂O–CO₂–NaCl show that these results are consistent with the existence of different saturated saline brines, carbonic fluids, or immiscible pairs of both in different layers. The data cannot be explained by the exisience of water-rich fluids in all layers. The model fluid compositions agree with fluid inclusion compositions from eclogite-stage veins and segregations that contain (1) saline brines (up to 39 equivalent wt. % NaCl) with up to six silicate, oxide, and carbonate daughter phases, and (2) carbonic fluids. The formation of crystalline segregations from fluid-filled pockets or hydrofractures indicates high fluid pressures at 2 GPa; the record of fluid variability in the banded eclogite host rocks, however, implies that fluid transport was limited to local flow along individual layers and that there was no large-scale mixing of fluids during devolatilization at depths of 60–70 km. The lack of evidence for fluid mixing may, in part, reflect variations in wetting behavior of fluids of different composition; nonwetting fluids (water-rich or carbonic) would be confined to intergranular pore spaces and would be essentially immobile, whereas wetting fluids (saline brines) could migrate more easily along an interconnected fluid network. The heterogeneous distribution of chemically distinct fluids may influence chemical transport processes during subduction by affecting mineral-fluid element partitioning and by altering the migration properties of the fluid phase(s) in the downgoing slab.  相似文献   

Low-temperature opal-CT precipitation in Antarctic deep-sea sediments: evidence from oxygen isotopes     

Reiner Botz  Gerhard Bohrmann   《Earth and Planetary Science Letters》1991,107(3-4)

Porcellanite has been found in Antarctic deep-sea sediments of shallow burial depth at four different sites in host sediments younger than 4 Ma. Oxygen isotope analysis shows that the opal-CT samples are extremely rich in¹⁸O (δ¹⁸O= 41.2to44.7‰ rel. SMOW). According to the quartz/water fractionation the calculated isotopic opal-CT formation temperature is in the range of 0 to 4°C. This agrees well with sediment temperature measurements. The low opal-CT precipitation temperature contrasts with current ideas about later diagenetic formation of opal-CT at higher temperatures of 18 to 56°C.  相似文献   

The professional image: Student,professor, practitioner     

Lee C. Gerhard 《Environmental Geology》1991,17(2):63-66

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