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61.
62.
Ground-water monitoring to delineate a contaminant plume in fluvial hydrostratigraphic units often is uncertain. Fluvial deposits consist typically of interbedded layers of sands, silts and clays, with buried stream channel deposits of sands or gravels. The channel deposits are often interpreted erroneously to be discontinuous between test holes and in cross section due to their sinuosity. Erroneous conclusions pertaining to the areal continuity of these geometrically complex deposits are inevitable unless the investigator thoroughly understands the depositional environment(s). The hydraulic conductivity of buried stream channel deposits may be several orders of magnitude higher than the matrix materials in which they are enclosed. The higher hydraulic conductivity of buried stream channel deposits has potentially significant ramifications with respect to ground-water monitoring to delineate the geometry of a contaminant plume migrating through these deposits. Ground-water monitoring at uranium mill waste disposal sites located in fluvial environments began on a significant scale in about 1977. A uranium mill tailing disposal site located in such an environment in central Wyoming is among the first sites monitored. Thirty-seven monitor wells were constructed at the site to delineate a seepage plume originating from one of the tailing ponds. This case history illustrates the need for a detailed under—standing of the hydrostratigraphy at a waste disposal site in order to interpret the meaning of ground-water quality data effectively. Water quality data from monitor wells located on a hit or miss basis often are misleading. The hydrostratigraphic horizon from which a water quality sample is collected must be well defined before the sample analyses can be interpreted quantitatively.  相似文献   
63.
Isoprenoid and other carbon skeletons that are formed in living organisms and preserved essentially intact in ancient sediments are often called biological markers. The purpose of this paper is to develop improved methods of using isoprenoid hydrocarbons to relate petroleum or shale oil to its source rock. It is demonstrated that most, but not all, of the isoprenoid hydrocarbon structures are chemically bonded in kerogen (or to minerals) in Green River oil shale. The rate constant for thermally producing isoprenoid, cyclic, and aromatic hydrocarbons is substantially greater than for the bulk of shale oil. This may be related to the substantial quantity of CO2 which is evolved coincident with the isoprenoid hydrocarbons but prior to substantial oil evolution. Although formation of isoprenoid alkenes is enhanced by rapid heating and high pyrolysis temperatures, the ratio of isoprenoid alkenes plus alkanes to normal alkenes plus alkanes is independent of heating rate. High-temperature laboratory pyrolysis experiments can thus be used to predict the distribution of aliphatic hydrocarbons in low temperature processes such as in situ shale oil production and perhaps petroleum formation. Finally, we demonstrate that significant variation in biological marker ratios occurs as a function of stratigraphy in the Green River formation. This information, combined with methods for measuring process yield from oil composition, enables one to relate time-dependent processing conditions to the corresponding time-dependent oil yield in a vertical modified-in situ retort even if there is a substantial and previously undetermined delay in drainage of shale oil from the retort.  相似文献   
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