Sensitive Ion‐Flotation Separation of Ag(I) Traces Using 2‐(2‐Methoxyphenyl)benzimidazole before Flame Atomic Absorption Spectrometric Determination in Water     

Hossein Tavallali  Shahram Lalehparvar  Abdo‐Reza Nekoei  Maryam Ghane Jahromi  Khodabakhsh Niknam 《洁净——土壤、空气、水》2012,40(6):640-647

A sensitive, reliable, and environmentally friendly method for simple separation and preconcentration of Ag(I) traces in aqueous samples is presented prior to their flame atomic absorption spectrometric determinations. At pH 7.0, Ag(I) was separated with 2‐(2‐methoxyphenyl)benzimidazole (MPBI) as a new complexing agent and floated after adding sodium dodecyl sulfate (SDS) as a foaming reagent. The floated layer was then dissolved in proper amount of concentrated nitric acid in methanol and introduced to the flame atomic absorption spectrometer (FAAS). The effects of pH, concentration of MPBI, type and amount of surfactant as the floating agent, type and amount of eluting agent, and influence of foreign ions on the recovery of the analyte ion were investigated. Also, using a nonlinear curve fitting method, the formation constant of 1.62 × 10⁶ was obtained for Ag(I)–MPBI complex. The analytical curve was linear in the range of 1.8 × 10^?7–1.7 × 10^?6 mol/L for determination of Ag(I). The relative standard deviation (RSD; N = 10) corresponding to 0.7 × 10^?6 mol/L of Ag(I), the limit of detection (10 blanks), and the enrichment factor were obtained as 1.7%, 2.9 × 10^?8 mol/L, and 43.0, respectively. The proposed procedure was then applied successfully for determination of silver ions in different water samples.  相似文献   

Simultaneous estimation of shape factor and depth of subsurface cavities from residual gravity anomalies using feed-forward back-propagation neural networks   总被引：1，自引：0，他引：1  

Alireza Hajian  Hossein Zomorrodian  Peter Styles 《Acta Geophysica》2012,60(4):1043-1075

We develop a new method of using feed-forward back-propagation (FFBP) neural networks to simultaneously estimate shape factor and depth of gravity anomalies. The advantages compared to neural network methods are the following: no pre-assumptions are made on source shape, the FFBP neural network estimates both depth and shape factor of source bodies and, once trained, works well for any new data in the training space, without repeating the initial calculations.  相似文献   

Hydraulic parameters in channels with wall vegetation and gravel bed     

Hossein AFZALIMEHR  Razieh MOGHBEL 《国际泥沙研究》2010,25(1):81-90

In this experimental study,field observations and laboratory experiments have been carried out to assess the impacts of the vegetated channel walls and aspect ratio on flow velocity profiles,shear stress distribution and roughness coefficient of channel.Results show that the presence of vegetation cover on channel wall causes deviation of the Reynolds stress distribution from the linear one under uniform flow condition.It is also noticed that the Reynolds stress distribution is influenced by the aspect rati...  相似文献   

Study on elastic response of structures to near-fault ground motions through record decomposition   总被引：4，自引：0，他引：4  

S. Farid Ghahari  Hossein JahankhahM. Ali Ghannad 《Soil Dynamics and Earthquake Engineering》2010

Accelerograms recorded near active faults have some important characteristics that make them different from those recorded in far-fault regions. High-frequency components in acceleration records and long-period velocity pulses are among notable specifications of such ground motions. In this paper, a moving average filtering with appropriate cut-off frequency has been used to decompose the near-fault ground motions into two components having different frequency contents: first, Pulse-Type Record (PTR) that possesses long-period pulses; second, the relatively high-frequency BackGround Record (BGR), which does not include large velocity pulses. Comparing the results with those extracted through wavelet analysis shows that moving average filter is an appropriate and efficient tool for near-fault records decomposition. The method is applied to decompose a suite of 91 selected near-fault records and the elastic response of structures is examined through their response to the decomposed parts. The results emphasizes that in contrast with ordinary far-fault earthquake records, response spectra of near-fault ground motions typically have two distinct local peaks, which are representatives of the high- and low-frequency components, i.e., BGR and PTR, respectively. Moreover, a threshold period is identified below which the response of structures is dominated by BGR while PTR controls the response of structures with periods longer than this period.  相似文献   

Application of various methods for 2D inverse modeling of residual gravity anomalies     

Maysam Abedi  Ahmad Afshar  Vahid E. Ardestani  Gholam H. Norouzi  Caro Lucas 《Acta Geophysica》2010,58(2):317-336

This paper presents a neural network approach to determine 2D inverse modeling of a buried structure from gravity anomaly profile. The results of the applied neural network method are compared with the results of two other methods, least-squares minimization and the simple method. Sphere, horizontal cylinder and vertical cylinder and their gravity effects are considered as the synthetic models and the synthetic data, respectively. The synthetic data are also corrupted with noise to evaluate the capability of the methods. Then the Dehloran bitumen map in Iran is chosen as a real data application. Anomaly value of the cross-section, which is taken from the gravity anomaly map of Dehloran bitumen, is very close to those obtained from these methods.  相似文献   

Genesis of Tertiary Magnetite–Apatite Deposits,Southeast of Zanjan,Iran     

Hossein Azizi  Behzad Mehrabi  Afshin Akbarpour 《Resource Geology》2009,59(4):330-341

Magnetite–apatite deposits in the Alborz volcano–plutonic belt, southeast Zanjan, in Iran, have blade, lenzoid, and vein forms, which extend in an E‐W direction. There are many magnetite–apatite veins and veinlets in this region, and some of them are economically important, such as Zaker, Morvarid, Sorkheh–Dizaj, and Aliabad. The sizes of the vein orebodies vary between 2 and 16 m in width, 10–100 m in length, and 5–40 m in depth. Microscopic examination of thin sections and polishes indicate that they are composed of magnetite and apatite, with minor amounts of goethite, hematite, actinolite, quartz, muscovite–illite, talc, dolomite, and calcite. The geochemistry and mineralogy of the granitic host rock reveals that it is calc‐alkaline and I‐type. Field observations, mineral paragenesis, the composition of the orebodies, and the composition of the fluid inclusions in the apatite minerals with low salinity (less than 20 wt.% NaCl equivalent) indicate that these magnetite veins were hydrothermally generated at about 200–430°C and are not related to silica–iron oxide immiscibility, as are the major Precambrian magnetite deposits in central Iran.  相似文献   

Earthquake relocation in the Central Alborz region of Iran using a non-linear probabilistic method     

Vahid Maleki  Z. Hossein Shomali  Mohammad Reza Hatami  Mehrdad Pakzad  Anthony Lomax 《Journal of Seismology》2013,17(2):615-628

In this study, we calculate accurate absolute locations for nearly 3,000 shallow earthquakes (≤20 km depth) that occurred from 1996 to 2010 in the Central Alborz region of northern Iran using a non-linear probabilistic relocation algorithm on a local scale. We aim to produce a consistent dataset with a realistic assessment of location errors using probabilistic hypocenter probability density functions. Our results indicate significant improvement in hypocenter locations and far less scattering than in the routine earthquake catalog. According to our results, 816 earthquakes have horizontal uncertainties in the 0.5–3.0 km range, and 981 earthquakes are relocated with focal-depth errors less than 3.0 km, even with a suboptimal network geometry. Earthquake relocated are tightly clustered in the eastern Tehran region and are mainly associated with active faults in the study area (the Mosha and Garmsar faults). Strong historical earthquakes have occurred along the Mosha and Garmsar faults, and the relocated earthquakes along these faults show clear north-dipping structures and align along east–west lineations, consistent with the predominant trend of faults within the study region. After event relocation, all seismicity lies in the upper 20 km of the crust, and no deep seismicity (>20 km depth) has been observed. In many circumstances, the seismicity at depth does not correlate with surface faulting, suggesting that the faulting at depth does not directly offset overlying sediments.  相似文献   

PM10 Source Apportionment in Ahvaz,Iran, Using Positive Matrix Factorization     

Mohammad Hossein Sowlat  Kazem Naddafi  Masud Yunesian  Peter L. Jackson  Saeedeh Lotfi  Abbas Shahsavani 《洁净——土壤、空气、水》2013,41(12):1143-1151

Source apportionment of particulate matter <10 µm in diameter (PM₁₀), having considerable impacts on human health and the environment, is of high priority in air quality management. The present study, therefore, aimed at identifying the potential sources of PM₁₀ in an arid area of Ahvaz located in southwest of Iran. For this purpose, we collected 24‐h PM₁₀ samples by a high volume air sampler. The samples were then analyzed for their elemental (Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Se, Si, Sn, Sr, Li, Ti, V, Zn, Mo, and Sb) and ionic (NH, Cl^?, NO, and SO) components using inductively coupled plasma optical emission spectrometry and ion chromatography instruments, respectively. Eight factors were identified by positive matrix factorization: crustal dust (41.5%), road dust (5.5%), motor vehicles (11.5%), marine aerosol (8.0%), secondary aerosol (9.5%), metallurgical plants (6.0%), petrochemical industries and fossil fuel combustion (13.0%), and vegetative burning (5.0%). Result of this study suggested that the natural sources contribute most to PM₁₀ particles in the area, followed closely by the anthropogenic sources.  相似文献   

Middle Jurassic palynomorphs of the Dalichai Formation, central Alborz Ranges, northeastern Iran: Paleoecological inferences     

DEHBOZORGI Afsaneh  SAJJADI Freshteh  HASHEMI Hossein 《中国科学:地球科学(英文版)》2013,56(12):2107-2115

Palynological data are used to draw paleoecological inferences for the Dalichai Formation,northeast of Semnan,northeastern Iran.All samples examined yield well-preserved,diverse palynofloras consisting predominantly of miospores;dinoflagellate cysts,foraminiferal test linings,and fungal spores occur as minor constituents.Fifty-four species of spores(37 genera),18species of pollen(9 genera),and 16 species of dinoflagellate cysts(13 genera)are recognized.Co-occurrence of such miospore species with known vertical ranges as Klukisporites variegatus,Sellaspora asperata,Murospora florida,and Concavissimisporites verrucosus suggests a Middle Jurassic(Bajocian-Callovian)age for the host strata,thus corroborating the available paleozoological evidence.Such spore species as Klukisporites,Cyathidites,and Dictyophyllidites known to have been produced by Pterophyta dominate the palynofloras.Thus the contemporaneous coastal vegetation was characterized by predominance of Pterophyta whereas representatives of Ginkgophyta,Pteridospermophyta,Lycophyta,Coniferophyta,and Bryophyta were rarely represented.This reconstruction implies that a moist,warm climate prevailed in northeastern Iran during the Middle Jurassic(Bajocian-Callovian).This is confirmed by occurrence of fungal spores accompanied by such warm water dinoflagellate cysts as Mendicodinium groenlandicum,Pareodinia ceratophora,and Gonyaulacysta jurassica.Abundance of Amorphous Organic Matter(AOM)signifies a shallow,low-energy,dysoxic-anoxic depositional site for the host strata.Furthermore,the ratio of AOM to marine palynomorphs as well as abundance of blade-shaped to eqiudimensional opaque palynomacerals could indicate low sedimentation rate in a shallow,low-oxygenated marine environment.Additionally,occurrence of chorate dinoflagellate cysts(e.g.,Adnatosphaeridium caulleryi)and acritarchs bearing relatively long processes(e.g.,Micrhystridium)possibly suggests deepening upward in the study section.  相似文献   

Foraminiferal Biostratigraphy of the Mobarak Formation (Lower Carboniferous) in Kiyasar Area,SE Sari,Northern Iran     

Mostafa FALAHATGAR  Hossein MOSADDEGH  Mahnaz Parvanehnejad SHIRAZI 《《地质学报》英文版》2012,86(6):1413-1425

The Mobarak Formation is near the town of Kiyasar in the south-east of Sari city, northern Iran. This formation conformably overlies the Geirud Formation (Upper Devonian). The lower part of the Mobarak Formation consisting of shales and thin- to medium-bedded limestone toward the top of these sequences changes into alternations of dark limestone and interbedded gray to black shales. Weathered yellow thick-bedded shales are observed at the top of the section. This formation is covered unconformably by sandstones attributed to the Dorud Formation (Lower Permian). The thickness of the formation in this region is 250 m. Four rock units have been recognized in this section. Foraminiferal biostratigraphy shows that the age of the Mobarak Formation in the Kiaysar region ranges from Lower Tournaisian to Early Middle Visean. The foraminifer Zones FAZ1 and FAZ2 are correlated with the Lower Tournaisian and Upper Tournaisian, whereas Zones FAZ3 and FAZ4 correlate with the Visean. Affinities exist between specimens recorded in the Kiyasar section with species known from other regions in eastern and Central Alborz, but there are important differences in their appearance.  相似文献