全文获取类型
收费全文 | 124篇 |
免费 | 7篇 |
专业分类
测绘学 | 2篇 |
大气科学 | 2篇 |
地球物理 | 26篇 |
地质学 | 69篇 |
海洋学 | 10篇 |
天文学 | 18篇 |
自然地理 | 4篇 |
出版年
2023年 | 1篇 |
2021年 | 3篇 |
2020年 | 1篇 |
2019年 | 5篇 |
2018年 | 5篇 |
2017年 | 1篇 |
2016年 | 7篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 9篇 |
2012年 | 5篇 |
2011年 | 6篇 |
2010年 | 4篇 |
2009年 | 10篇 |
2008年 | 6篇 |
2007年 | 5篇 |
2006年 | 2篇 |
2005年 | 5篇 |
2004年 | 5篇 |
2003年 | 2篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1973年 | 3篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1964年 | 1篇 |
排序方式: 共有131条查询结果,搜索用时 15 毫秒
111.
Giancarlo Capitani Nobuyoshi Miyajima Roberto Sulpizio Maria D’Addabbo Lucia Galimberti Massimo Guidi Giovanni B. Andreozzi 《Environmental Earth Sciences》2018,77(13):521
In this study, we performed leaching experiments for timescales of hours-to-months in deionized water on fresh volcanic ash from Mt. Etna (Italy) and Popocatépetl (Mexico) volcanos to monitor Fe release as a function of ash mineral chemistry and size, with the aim of clarifying Fe release mechanisms and eventually evaluating the impact of volcanic ash on marine and lacustrine environments. To define sample mineralogy and Fe speciation, inclusive characterization was obtained by means of XRF, SEM, XRPD, EELS and Mössbauer spectroscopies. For Etna and Popocatépetl samples, glass proportions were quantified at 73 and 40%, Fe2O3 total contents at 11.6–13.2 and 5.8 wt%, and Fe3+/FeTot ratios at 0.33 and 0.23, respectively. Leaching experiments showed that significant amounts of iron, ~?30 to 150 and ~?750 nmol g?1 l?1 for pristine Etna and Popocatépetl samples, respectively, are released within the first 30 min as a function of decreasing particle size (from 1 to 0.125 mm). The Popocatépetl sample showed a very sustained Fe release (up to 10 times Etna samples) all along the first week, with lowest values never below 400 nmol g?1 l?1 and a maximum of 1672 nmol g?1 l?1 recorded after 5 days. This sample, being composed of very small particles (average particle size 0.125 mm) with large surface area, likely accumulated large quantities of Fe-bearing sublimates that quickly dissolved during leaching tests, determining high Fe release and local pH decrease (that contributed to release more Fe from the glass) at short timescale (hours-to-days). The fractional Fe solubility (FeS) was 0.004–0.011 and 0.23% for Etna and Popocatépetl samples, respectively, but no correlation was found between Fe released in solution and either ash Fe content, glass/mineral ratio or mineral assemblage. Results obtained suggest that volcanic ash chemistry, mineralogy and particle size assume a relevant role on Fe release mostly in the medium-to-long timescale, while Fe release in the short timescale is dominated by dissolution of surface sublimates (formed by physicochemical processes occurring within the eruption plume and volcanic cloud) and the effects of such a dissolution on the local pH conditions. For all samples, a moderate to sustained Fe release occurred for leaching times comparable with their residence time within the euphotic zone of marine and lacustrine environments (variable from few minutes to few hours), revealing their possible contribution to increase Fe bioavailability. 相似文献
112.
Simone Bernardini Fabio Bellatreccia Giancarlo Della Ventura Armida Sodo 《Geostandards and Geoanalytical Research》2021,45(1):223-244
Manganese oxides are important geomaterials, widespread in terrestrial and Martian environments. Characterisation of the oxidation state of Mn is a central issue in science; this task has been addressed up to the present by X‐ray spectroscopy or diffraction techniques. The former, however, requires access to synchrotron facilities, while the latter does not provide crystal‐chemical information at the local scale. In this work, we compare a large set of Raman data from well‐characterised samples, already published by the same authors of this paper or as found in the literature. We show a clear correlation between the oxidation state of Mn and the wavenumber of peculiar bands; octahedrally co‐ordinated Mn2+ is recognised by a band around 530 cm?1, Mn3+ by a band around 580 cm?1 and Mn4+ by a band around 630 cm?1, while tetrahedrally co‐ordinated Mn2+ is recognisable by a band around 650 cm?1. Strongly distorted Mn3+ octahedra are indicated by the appearance of Jahn–Teller modes. Our method allows a reliable, easily accessible tool to characterise the oxidation states of Mn in oxides, also suitable for microscale mapping. It provides a robust analytical basis for the use of these minerals as redox indicators in geology/geochemistry, in exoplanetary research or for monitoring technological processes. 相似文献
113.
A short intra‐Messinian continental period has been recognised in some North Italian gypsum areas, mostly under the form of palaeokarst deposits. This emersion appears to have occurred only locally, and is explained as caused by the intra‐Messinian tectonic phase and a major sea level lowering. Evidences of this palaeokarst are mostly small, although at some places the palaeontological content of its fillings is of great importance. The discovery near Zola Predosa (Bologna) of a new intra‐Messinian extensive karst system and of its infilling sheds new light on the importance of this karst episode. 相似文献
114.
The volumetric compaction due to wetting processes is a phenomenon observed quite often in unsaturated soils. Under certain circumstances, saturation events can result into a sudden and unexpected collapse of the system. These phenomena are usually referred to as wetting‐induced collapses, without providing any detailed theoretical justification for this terminology. In order to predict in a general fashion the occurrence of coupled instabilities induced by saturation processes, a generalization of the theoretical approaches usually employed for saturated geomaterials is here provided. More specifically, this paper addresses the problem of hydro‐mechanical instability in unsaturated soils from an energy standpoint. For this purpose, an extension of the definition of the second‐order work is here suggested for the case of unsaturated porous media. On the basis of some examples of numerical simulations of laboratory tests, coupled hydro‐mechanical instabilities are then interpreted in the light of this second‐order energy measure. Finally, the implications of the theoretical results here presented are commented from a constitutive modelling perspective. Two possible alternative approaches to formulate incremental coupled constitutive relations are indeed discussed, showing how the onset of hydro‐mechanical instabilities can be predicted using an extended form of Hill's stability criterion. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
115.
The Monte Orfano Conglomerate revisited: stratigraphic constraints on Cenozoic tectonic uplift of the Southern Alps (Lombardy, northern Italy) 总被引:1,自引:0,他引:1
Dario Sciunnach Giancarlo Scardia Fabrizio Tremolada Isabella Premoli Silva 《International Journal of Earth Sciences》2010,99(6):1335-1355
The Monte Orfano Conglomerate (MOC), exposed in the foothills of the Southern Alps (northern Italy), is one of the few outcrops
of sediments documenting the Cenozoic tectonic evolution of the Alpine retrowedge. Calcareous nannofossil biostratigraphy
allowed us to constrain the upper part of the MOC, formerly attributed to the Early-Middle Miocene in the type-locality, to
the earliest Miocene (Neogene part of the NN1 nannofossil zone). A likely latest Oligocene age is therefore suggested for
the bulk of the underlying conglomerates, whose base is not exposed. Deposition of the MOC can be placed within the post-collisional
tectonic uplift of the Alps, documented in the Lake Como area by the Como Conglomerate (CC) at the base of the Gonfolite Lombarda
Group, and supports the correlation with Upper Oligocene clastic sediments cropping out further to the East, in the Lake Garda
and in the Veneto-Friuli areas (“molassa”). The remarkable difference in petrographic composition between the western (CC) and eastern (MOC) clastics deposited in
the Alpine retro-foreland basin highlights the synchronous tectonic activity of two structural domains involving different
crustal levels. Whilst the bulk of the CC, that straddles the Oligocene/Miocene boundary, records largely the tectonic exhumation
of the Alpine axial chain crystalline complexes, the coeval MOC consists of detritus derived from the superficial crustal
section (Triassic to Paleogene sedimentary rocks) of the Alpine retrowedge and constrains the onset of the post-collisional
deformation phase of the Southern Alps as not younger than the Late Oligocene. 相似文献
116.
An approximate step-by-step procedure is presented for the finite element analysis of transient unconfined flow problems. At each step the free surface is modelled by means of segments coinciding with sides of the elements. This leads to an approximate but extremely simple solution scheme which can be readily incorporated into standard codes for confined analysis. The solutions of some significant problems are presented and compared with other non-approximate solutions. They show that the technique, in spite of its approximation, is capable of giving meaningful results from an engineering viewpoint. 相似文献
117.
Fossi MC Marsili L Lauriano G Fortuna C Canese S Ancora S Leonzio C Romeo T Merino R Abad E Jiménez B 《Marine environmental research》2004,58(2-5):269-274
Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily - Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups. 相似文献
118.
The paper mainly concerns the mechanical response of 2D dry dense sand specimens under shock loading. The problem is numerically analysed by means of a SEM dynamic code, within which an already conceived non‐local viscoplastic constitutive model characterized by a non‐associated flow rule and by an anisotropic strain hardening has been implemented. In particular the strain localization and time dependency of the material mechanical response are taken into consideration. Both rapid/static loading and dynamic histories are numerically simulated. In the first case, the time dependency of the material mechanical response can be captured by neglecting inertial effects, while in the second one the two factors are superimposed and the propagation of the stress waves within the specimen is discussed. The interest of these analyses derives from the fact that the diffusion phenomenon takes place within a specimen already localized. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
119.
Daniele Penna Marco Borga Daniele Norbiato Giancarlo Dalla Fontana 《Journal of Hydrology》2009,364(3-4):311-327
120.
Vibrios in association with sedimentary crustaceans in three beaches of the northern Adriatic Sea (Italy) 总被引:3,自引:0,他引:3
Covazzi Harriague A Brino MD Zampini M Albertelli G Pruzzo C Misic C 《Marine pollution bulletin》2008,56(3):574-579
In the marine environment, vibrios adhere to a number of substrates including chitin-rich organisms such as crustaceans. Their wide diffusion in coastal waters and pathogenic potential require knowledge of the lifestyle and environmental reservoirs of these bacteria. To test the presence of culturable vibrios in coastal areas and their association with benthic crustaceans, vibrios were isolated from water, sediments and crustaceans (copepods and anphipods) at three stations placed in front of heavily used tourist beaches of the Adriatic Sea. We observed significant correlations between vibrios and temperature. Benthic and planktonic copepods harboured vibrios in summer, while benthic amphipods harboured these bacteria in spring and autumn. Vibrio alginolyticus and Vibrio parahaemolyticus strains gave positive results using primers for Vibrio cholerae toxR and toxS. Sedimentary crustaceans may extend Vibrio persistence in seawater and may represent an additional aquatic reservoir of these bacteria. 相似文献