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121.
A model of the transition layer of an active region of the Sun is presented based on radio observations. The model is deduced by using the Laplace transform of the brightness temperature and the hydrostatic equilibrium equation. A rational function, well-behaved in the coronal region, has been used to represent the observed brightness temperature. The model indicates the existence of a very steep temperature gradient and suggests the presence of a constant conductive flux from the corona into the chromosphere. Both these conclusions are quantitatively in a very good agreement with those deduced from the UV emission lines observations, thus removing a previous discrepancy between radio and optical based models. It is also shown that the presence of a weak magnetic field does not alter the above conclusions.  相似文献   
122.
In this paper the scaling hypotheses are applied to annual maximum series of rainfall depth for different rainfall duration to derive the depth–duration–frequency (DDF) curve. It is shown that, based on the empirically observed scaling properties of rainfall and some general assumptions about the cumulative distribution function for the annual maximum of the rainfall depth, it is possible to derive a simple DDF relationship. This general framework provides a basis for the generation of maps that can be used to infer DDF curves at any point of a particular area. Data from a dense raingauge network in a mountainous region in north-eastern Italy (the Trentino Province) are used to clarify the methodology for the construction and regionalization of the DDF relationship. The geographical variation of short-duration (i.e., less than 60 xmin) rainfall extremes is also evaluated by using the same framework. It is found that depth–duration ratios, defined as the ratios of the t-min to the 60-min rainfall depths of the same return period, may be considered independent of return period and geographical location for any storm duration less than 60 min.  相似文献   
123.
This letter deals with the problem of imaging 3-D strong scatterers by means of a 2-D slice tomographic reconstruction algorithm. More in detail, the inversion algorithm is based on two steps. In the first step, 2-D slices of the object are reconstructed; then, they are superimposed and interpolated to achieve the 3-D representation of the object. The Kirchhoff approximation is exploited to develop a linear inversion scheme for reconstructing the 2-D slices for scatterers embedded in the free space. Finally, the inversion algorithm is checked against synthetic data for the interesting case of scatterers resembling the human body.  相似文献   
124.
Manganese oxides are important geomaterials, widespread in terrestrial and Martian environments. Characterisation of the oxidation state of Mn is a central issue in science; this task has been addressed up to the present by X‐ray spectroscopy or diffraction techniques. The former, however, requires access to synchrotron facilities, while the latter does not provide crystal‐chemical information at the local scale. In this work, we compare a large set of Raman data from well‐characterised samples, already published by the same authors of this paper or as found in the literature. We show a clear correlation between the oxidation state of Mn and the wavenumber of peculiar bands; octahedrally co‐ordinated Mn2+ is recognised by a band around 530 cm?1, Mn3+ by a band around 580 cm?1 and Mn4+ by a band around 630 cm?1, while tetrahedrally co‐ordinated Mn2+ is recognisable by a band around 650 cm?1. Strongly distorted Mn3+ octahedra are indicated by the appearance of Jahn–Teller modes. Our method allows a reliable, easily accessible tool to characterise the oxidation states of Mn in oxides, also suitable for microscale mapping. It provides a robust analytical basis for the use of these minerals as redox indicators in geology/geochemistry, in exoplanetary research or for monitoring technological processes.  相似文献   
125.
In this study, we performed leaching experiments for timescales of hours-to-months in deionized water on fresh volcanic ash from Mt. Etna (Italy) and Popocatépetl (Mexico) volcanos to monitor Fe release as a function of ash mineral chemistry and size, with the aim of clarifying Fe release mechanisms and eventually evaluating the impact of volcanic ash on marine and lacustrine environments. To define sample mineralogy and Fe speciation, inclusive characterization was obtained by means of XRF, SEM, XRPD, EELS and Mössbauer spectroscopies. For Etna and Popocatépetl samples, glass proportions were quantified at 73 and 40%, Fe2O3 total contents at 11.6–13.2 and 5.8 wt%, and Fe3+/FeTot ratios at 0.33 and 0.23, respectively. Leaching experiments showed that significant amounts of iron, ~?30 to 150 and ~?750 nmol g?1 l?1 for pristine Etna and Popocatépetl samples, respectively, are released within the first 30 min as a function of decreasing particle size (from 1 to 0.125 mm). The Popocatépetl sample showed a very sustained Fe release (up to 10 times Etna samples) all along the first week, with lowest values never below 400 nmol g?1 l?1 and a maximum of 1672 nmol g?1 l?1 recorded after 5 days. This sample, being composed of very small particles (average particle size 0.125 mm) with large surface area, likely accumulated large quantities of Fe-bearing sublimates that quickly dissolved during leaching tests, determining high Fe release and local pH decrease (that contributed to release more Fe from the glass) at short timescale (hours-to-days). The fractional Fe solubility (FeS) was 0.004–0.011 and 0.23% for Etna and Popocatépetl samples, respectively, but no correlation was found between Fe released in solution and either ash Fe content, glass/mineral ratio or mineral assemblage. Results obtained suggest that volcanic ash chemistry, mineralogy and particle size assume a relevant role on Fe release mostly in the medium-to-long timescale, while Fe release in the short timescale is dominated by dissolution of surface sublimates (formed by physicochemical processes occurring within the eruption plume and volcanic cloud) and the effects of such a dissolution on the local pH conditions. For all samples, a moderate to sustained Fe release occurred for leaching times comparable with their residence time within the euphotic zone of marine and lacustrine environments (variable from few minutes to few hours), revealing their possible contribution to increase Fe bioavailability.  相似文献   
126.
We report a FTIR (Fourier transform infrared) study of a set of cordierite samples from different occurrence and with different H2O/CO2 content. The specimens were fully characterized by a combination of techniques including optical microscopy, single-crystal X-ray diffraction, EMPA (electron microprobe analysis), SIMS (secondary ion mass spectrometry), and FTIR spectroscopy. All cordierites are orthorhombic Ccmm. According to the EMPA data, the Si/Al ratio is always close to 5:4; X Mg ranges from 76.31 to 96.63, and additional octahedral constituents occur in very small amounts. Extraframework K and Ca are negligible, while Na reaches the values up to 0.84 apfu. SIMS shows H2O up to 1.52 and CO2 up to 1.11 wt%. Optically transparent single crystals were oriented using the spindle stage and examined by FTIR micro-spectroscopy under polarized light. On the basis of the polarizing behaviour, the observed bands were assigned to water molecules in two different orientations and to CO2 molecules in the structural channels. The IR spectra also show the presence of small amounts of CO in the samples. Refined integrated molar absorption coefficients were calibrated for the quantitative microanalysis of both H2O and CO2 in cordierite based on single-crystal polarized-light FTIR spectroscopy. For H2O the integrated molar coefficients for type I and type II water molecules (ν3 modes) were calculated separately and are [I]ε?=?5,200?±?700?l?mol?1?cm?2 and [II]ε?=?13,000?±?3,000?l?mol?1?cm?2, respectively. For CO2 the integrated coefficient is $ \varepsilon_{{{\text{CO}}_{ 2} }} $ ?=?19,000?±?2,000?l?mol?1?cm?2.  相似文献   
127.
Confidence in the use of macroalgae as an indicator of estuarine eutrophication is limited by the lack of quantitative data on the thresholds of its adverse effects on benthic habitat quality. In the present study, we utilized sediment profile imagery (SPI) to identify thresholds of adverse effects of macroalgal biomass, sediment organic carbon (% OC) and sediment nitrogen (% N) concentrations on the apparent Redox Potential Discontinuity (aRPD), the depth that marks the boundary between oxic near-surface sediment and the underlying suboxic or anoxic sediment. At 16 sites in eight California estuaries, SPI, macroalgal biomass, sediment percent fines, % OC, and % N were analyzed at 20 locations along an intertidal transect. Classification and Regression Tree (CART) analysis was used to identify step thresholds associated with a transition from "reference" or natural background levels of macroalgae, defined as that range in which no effect on aRPD was detected. Ranges of 3–15 g dw macroalgae m?2, 0.4–0.7 % OC and 0.05–0.07 % N were identified as transition zones from reference conditions across these estuaries. Piecewise regression analysis was used to identify exhaustion thresholds, defined as a region along the stress–response curve where severe adverse effects occur; levels of 175 g dw macroalgae m?2, 1.1 % OC and 0.1 % N were identified as thresholds associated with a shallowing of aRPD to near zero depths. As an indicator of ecosystem condition, shallow aRPD has been related to reduced volume and quality for benthic infauna and alteration in community structure. These effects have been linked to reduced availability of forage for fish, birds and other invertebrates, as well as to undesirable changes in biogeochemical cycling.  相似文献   
128.
Rockslides in alpine areas can reach large volumes and, owing to their position along slopes, can either undergo large and rapid evolution originating large rock avalanches or can decelerate and stabilize. As a consequence, in particular when located within large deep-seated deformations, this type of instability requires accurate observation and monitoring. In this paper, the case study of the La Saxe rockslide (ca. 8 × 106 m3), located within a deep-seated deformation, undergoing a major phase of acceleration in the last decade and exposing the valley bottom to a high risk, is discussed. To reach a more complete understanding of the process, in the last 3 years, an intense investigation program has been developed. Boreholes have been drilled, logged, and instrumented (open-pipe piezometers, borehole wire extensometers, inclinometric casings) to assess the landslide volume, the rate of displacement at depth, and the water pressure. Displacement monitoring has been undertaken with optical targets, a GPS network, a ground-based interferometer, and four differential multi-parametric borehole probes. A clear seasonal acceleration is observed related to snow melting periods. Deep displacements are clearly localized at specific depths. The analysis of the piezometric and snowmelt data and the calibration of a 1D block model allows the forecast of the expected displacements. To this purpose, a 1D pseudo-dynamic visco-plastic approach, based on Perzyna’s theory, has been developed. The viscous nucleus has been assumed to be bi-linear: in one case, irreversible deformations develop uniquely for positive yield function values; in a more general case, visco-plastic deformations develop even for negative values. The model has been calibrated and subsequently validated on a long temporal series of monitoring data, and it seems reliable for simulating the in situ data. A 3D simplified approach is suggested by subdividing the landslide mass into distinct interacting blocks.  相似文献   
129.
The Monte Orfano Conglomerate (MOC), exposed in the foothills of the Southern Alps (northern Italy), is one of the few outcrops of sediments documenting the Cenozoic tectonic evolution of the Alpine retrowedge. Calcareous nannofossil biostratigraphy allowed us to constrain the upper part of the MOC, formerly attributed to the Early-Middle Miocene in the type-locality, to the earliest Miocene (Neogene part of the NN1 nannofossil zone). A likely latest Oligocene age is therefore suggested for the bulk of the underlying conglomerates, whose base is not exposed. Deposition of the MOC can be placed within the post-collisional tectonic uplift of the Alps, documented in the Lake Como area by the Como Conglomerate (CC) at the base of the Gonfolite Lombarda Group, and supports the correlation with Upper Oligocene clastic sediments cropping out further to the East, in the Lake Garda and in the Veneto-Friuli areas (“molassa”). The remarkable difference in petrographic composition between the western (CC) and eastern (MOC) clastics deposited in the Alpine retro-foreland basin highlights the synchronous tectonic activity of two structural domains involving different crustal levels. Whilst the bulk of the CC, that straddles the Oligocene/Miocene boundary, records largely the tectonic exhumation of the Alpine axial chain crystalline complexes, the coeval MOC consists of detritus derived from the superficial crustal section (Triassic to Paleogene sedimentary rocks) of the Alpine retrowedge and constrains the onset of the post-collisional deformation phase of the Southern Alps as not younger than the Late Oligocene.  相似文献   
130.
Habitat fragmentation in meadows of Posidonia oceanica, the most important and abundant seagrass in the Mediterranean Sea, was investigated at a region-wide spatial scale using a synthetic ecological index, the Patchiness Index (PI). We tested the hypothesis that human impacts are the major factor responsible for habitat fragmentation in P. oceanica meadows contrasting fragmentation of meadows located in “anthropized” areas with that of meadows located in areas with low anthropization and considered as virtually “natural”. We also related fragmentation of meadow with the morphodynamic state of the submerged beach (i.e. distinctive types of beach produced by the topography, the wave climate and the sediment composition) in order to investigate the influence of one natural component on the seagrass meadow seascape. Results demonstrated that fragmentation in the P. oceanica meadows is strongly influenced by the human component, being lower in natural meadows than in anthropized ones, and that it is little influenced by the morphodynamic state of the coast. The use of landscape approaches to discriminate natural disturbance from human impacts that affect seagrass meadows is thus recommended for the proper management of coastal zones.  相似文献   
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