The effect of chlorite interlayering on <Superscript>40</Superscript>Ar–<Superscript>39</Superscript>Ar biotite dating: an <Superscript>40</Superscript>Ar–<Superscript>39</Superscript>Ar laser-probe and TEM investigations of variably chloritised biotites     

Gianfranco?Di VincenzoEmail author  Cecilia?Viti  Sergio?Rocchi 《Contributions to Mineralogy and Petrology》2003,145(6):643-658

Biotite is one of the most common minerals dated by the ⁴⁰Ar–³⁹Ar method. It frequently shows K contents below the expected stoichiometric value, suggesting the presence of low-K impurities. The most common low-K alteration product of biotite is chlorite. Therefore, it is important to understand the effects of chlorite interlayering on ⁴⁰Ar–³⁹Ar ages in order to correctly interpret ⁴⁰Ar–³⁹Ar data. This study examines the outcome of ⁴⁰Ar–³⁹Ar dating analyses on variably chloritised biotites from Ordovician intrusive rocks. The infrared (IR) laser-probe technique and different gas extraction methods were adopted. Incremental laser-heating data on bulk samples yielded hump-shaped age profiles with meaningless young and old age steps. Both the extent of anomalous old age steps and the degree of discordance of the age spectra were much more pronounced in the more chloritised biotite samples. In contrast, in situ data on rock chips and total-fusion ages on single biotite flakes yielded ages concordant with, or younger than, the inferred emplacement ages. Transmission electron microscopy (TEM) was used to texturally characterise biotite samples at the nanometre scale. It was also used to document the complex decomposition-transformation process affecting interlayered biotite–chlorite during in-vacuo IR-laser heating to temperatures ranging from ~600 to >1,000 °C. TEM results suggest that hump-shaped age profiles result from an interplay between ³⁹Ar_K redistribution by recoil during sample irradiation and differential release of argon isotopes hosted in three main reservoirs. These reservoirs are (from least to most retentive): extended defects, chlorite and biotite. The final descending age segment is attributed to the progressive release of argon with increasing temperature from large biotite domains for which ³⁹Ar_K recoil loss was less important. ⁴⁰Ar–³⁹Ar data support previous findings, which suggest that ⁴⁰Ar–³⁹Ar ages when recoil effects are minimised, provide minimum estimates that approach the true biotite age, when the pristine domains are analysed. The most effective approach for obtaining meaningful ⁴⁰Ar–³⁹Ar ages was using individual total-fusion analyses on carefully selected, single flakes previously split along the basal cleavage by wet-grinding and corresponding to a sample mass of a few micrograms.Editorial responsibility: I Parsons  相似文献   

A structural and geophysical approach to the study of fractured aquifers in the Scansano-Magliano in Toscana Ridge, southern Tuscany, Italy   总被引：1，自引：0，他引：1  

Roberto Francese  Francesco Mazzarini  Andrea Bistacchi  Gianfranco Morelli  Giorgio Pasquarè  Nicola Praticelli  Henry Robain  Nigel Wardell  Annalisa Zaja 《Hydrogeology Journal》2009,17(5):1233-1246

Fresh water availability has recently become a serious concern in the Italian Apennines, as various activities rely on a predictable supply. Along the ridge between Scansano and Magliano in Toscana, in southern Tuscany, the situation is further complicated by contamination of the nearby alluvial aquifers. Aquifers locally consist of thin fractured reservoirs, generally within low-permeability formations, and it can be difficult to plan the exploitation of resources based on conventional techniques. An integrated study based on geological data investigated the link between tectonics and groundwater circulation, to better define the hydrological model. After the regional identification of fault and fracture patterns, a major structure was investigated in detail to accurately map its spatial position and to understand the geometry and properties of the associated aquifer and assess its exploitation potential. The subsurface around the fault zone was clearly imaged using ground probing radar, two-dimensional and three-dimensional resistivity tomography, and three-dimensional shallow seismic surveys. The vertical and horizontal contacts between the different geological units of the Ligurian and Tuscan series were resolved with a high degree of spatial accuracy. Three-dimensional high-resolution geophysical imaging proved to be a very effective means of characterising small-scale fractured reservoirs.  相似文献   

Direct evidence of Middle Oligocene extension in the Calabria–Peloritani terrane from co-seismic faulting: the pseudotachylyte-bearing shear zones of Palmi (southern Calabria, Italy)     

Antonietta Grande  Gianfranco Di Vincenzo  Giacomo Prosser  Alfredo Caggianelli 《地学学报》2009,21(4):293-303

The Variscan crystalline basement of the Calabria–Peloritani terrane (CPT) in southern Italy was partly reworked by ductile and brittle shear zones throughout the Alpine tectonic evolution (from thickening to exhumation). Although evidence of extensional tectonics in the CPT has already been found and roughly constrained to the Oligocene onward, no attempt has ever been made to directly date brittle fault movements. Structural (meso- and micro-scale), kinematic and petrographic analyses and ⁴⁰Ar–³⁹Ar laser experiments reveal that the pseudotachylyte-bearing shear zones of the Palmi area in southern Calabria formed in response to extensional shearing ∼33.5 Ma ago and overprinted compressional tectonic structures. Results provide the first direct evidence of Middle Oligocene co-seismic faulting in the area and confirm the role of extensional tectonics in promoting the Oligocene exhumation of the Calabria basement.  相似文献   

Nonlinear regional economic dynamics: continuous-time specification,estimation and stability analysis     

Gianfranco Piras  Kieran P. Donaghy  Giuseppe Arbia 《Journal of Geographical Systems》2007,9(4):311-344

This paper presents an innovative approach to the study of regional economic dynamics within a nonlinear continuous-time econometric framework—a generalized specification of the Lotka–Volterra system of equations. This specification, which accounts for interdependent behavior of three industrial sectors and spillover effects of activities in neighboring regions, is employed in an analysis of five Italian regions between 1980 and 2003. For these regions, we report estimation results, characterize the varying systems dynamics, analyze the models’ local and global stability properties, and determine via sensitivity analyses which structural features appear to exert the greatest influence on these properties.

Kieran P. DonaghyEmail:

  相似文献   

The thin layer of Warm Ionized Gas: towards a 3-D reconstruction of the spatial distribution of HII regions     

Roberta Paladini  Rod Davies  Gianfranco DeZotti 《Astrophysics and Space Science》2004,289(3-4):363-366

HII regions are known to contribute to the so-called thin layer of the diffuse Warm Ionized Gas. In order to constrain thiscontribution, we reconstruct the 3-D distribution of the sources.A detailed spatial analysis of the largest up-to-date sample of HIIregions is presented.  相似文献   

Grains accretion processes in a proto-planetary nebula     

A. Coradini  G. Magni  C. Federico 《Astrophysics and Space Science》1977,48(1):79-87

Some mechanisms which are expected to produce the growth of dust grains in the protosolar nebula are studied during the isothermal and the adiabatic phase of the gravitational collapse. Owing to the low sticking efficiency in the grain-grain collisions and also to the impossibility of gas capture by solid particles in the physical environment considered, the main result is the production in about 10⁶ yr of a set of particles similar in mass. The obtained mass limit (10⁻⁸–10⁻⁹ g) depends on the physical properties of the grains, and seems to be independent of the turbulence model used for the gas motion.  相似文献   

Ar-Ar laser dating of tektites from the Cheb Basin (Czech Republic): Evidence for coevality with moldavites and influence of the dating standard on the age of the Ries impact     

Gianfranco Di Vincenzo  Roman Skála 《Geochimica et cosmochimica acta》2009,73(2):493-2158

Moldavites (Central European tektites) are genetically related to the impact event that produced the ∼24-km diameter Ries crater in Germany, representing one of the youngest large impact structures on Earth. Although several geochronological studies have been completed, there is still no agreement among ⁴⁰Ar-³⁹Ar ages on both moldavites and glasses from Ries suevites. Even recently published data yielded within-sample mean ages with a nominal spread of more than 0.6 Ma (14.24-14.88 Ma). This age spread, which significantly exceeds current internal errors, must be in part ascribed to geological and/or analytical causes.This study reports the results of a detailed geochronological investigation of moldavites from the Cheb area (Czech Republic), which have never been dated before, and, for comparison, of two samples from type localities, one in southern Bohemia and the other in western Moravia. We used ⁴⁰Ar-³⁹Ar laser step-heating and total fusion techniques in conjunction with microscale petrographic and chemical characterization. In addition, with the purpose of ascertaining the influence of the dating standards on the age of the Ries impact and making data from this study and literature consistent with the now widely used Fish Canyon sanidine (FCs) standard, we performed a direct calibration of multi-grain splits of the Fish Canyon biotite (FCT-3) with FCs. The intercalibration factors (), determined for eight stack positions in one of the three performed irradiations, were indistinguishable within errors and gave an arithmetic mean and a standard deviation of 1.0086 ± 0.0031 (±2σ), in agreement with previous works suggesting that biotite from the Fish Canyon Tuff is somewhat older (∼0.8%) than the coexisting sanidine.Laser total fusion analysis of milligram to sub-milligram splits of five tektite samples from the Cheb area yielded mostly concordant intrasample ⁴⁰Ar-³⁹Ar ages, and within-sample weighted mean ages of 14.66 ± 0.08-14.75 ± 0.12 Ma (±2σ internal errors, ages relative to FCs) that overlap within errors. These ages match those obtained for samples from western Moravia (14.66 ± 0.08 Ma) and southern Bohemia (14.68 ± 0.11 Ma), supporting the genetic link between Cheb Basin tektites and moldavites, and, consequently, between Cheb Basin tektites and the Ries impact. In contrast to samples from the Cheb area and Moravia, ⁴⁰Ar-³⁹Ar ages from total fusion experiments on the Bohemian specimen ranged widely from ∼14.6 to ∼17.0 Ma. Older apparent ages, however, were systematically obtained from fragments characterized by visible surface alteration. Laser step-heating experiments, although displaying slightly disturbed age profiles, were in line with total fusion analyses and yielded well-defined plateau ages of 14.64 ± 0.11-14.71 ± 0.11 Ma (±2σ internal errors, ages relative to FCs).A thorough comparison of our and previous ⁴⁰Ar-³⁹Ar ages on both moldavites and Ries suevite glasses, recalculated relative to the ⁴⁰Ar^∗/⁴⁰K ratio recently determined for FCs using intercalibration factors available in or derivable from the literature, reveals some inconsistencies which may be ascribed to either geological or analytical causes. Based on our data, decay constants in current use in geochronology, and ages calculated relative to FCs, we infer that the age of moldavites is 14.68 ± 0.11 Ma (±2σ, neglecting uncertainties in the ⁴⁰K decay constants).  相似文献   

Dark matter annihilation in substructures revised     

Lidia Pieri  Gianfranco Bertone  Enzo Branchini 《Monthly notices of the Royal Astronomical Society》2008,384(4):1627-1637

  相似文献   

Correction to: Numerical investigation of small- and medium-diameter drain wells to stabilise deep landslides     

Aloi  Ferdinando  Pirone  Marianna  Urciuoli  Gianfranco 《Acta Geotechnica》2019,14(3):921-921

Acta Geotechnica - In the original publication, the first name of the authors was exchanged with the last name inadvertently. The name of the authors should be as below.  相似文献   

U?Pb and 40Ar?39Ar geochronology of Palaeozoic units in the northern Apennines: determining protolith age and alpine evolution using the Calamita Schist and Ortano Porphyroid     

Giovanni Musumeci  Francesco Mazzarini  Massimo Tiepolo  Gianfranco Di Vincenzo 《Geological Journal》2011,46(4):288-310

In the northern Apennines, the Palaeozoic basement involved in the Late Oligocene–Middle Miocene nappe stack contains metamorphic units for which hypothetical ages have been assigned on the basis of lithological correlations with the Palaeozoic formations of the Variscan chain in Sardinia. This uncertainty concerning the age poses limitations to reconstructing the Palaeozoic stratigraphy, defining the Alpine and pre‐Alpine histories and correlations with other domains of the Variscan chain. We present the U Pb age of detrital zircon and the ⁴⁰Ar ³⁹Ar age of metamorphic muscovite for the Calamita Schist and Ortano Porphyroid, two metamorphic units of undetermined Palaeozoic age cropping out in the eastern Elba Island. The radioisotopic data allows us to: (i) define the Early Carboniferous and Middle Ordovician ages for the Calamita Schist and Ortano Porphyroid, respectively, as well as their derivation (flysch deposit and magmatic rocks); (ii) pose some constraints concerning their alpine tectonic and metamorphic histories. These new data generate a more precise reconstruction of the Palaeozoic sequence in the northern Apennines, and they document that the Palaeozoic basement involved in the alpine deformation underwent internal stacking with an inversion of the original sequence. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献