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231.
The evolution of hydrocarbons in sediments was studied from 1978 to 1980 at eight stations in the Ile Grande marshes (Brittany) polluted by the Amoco Cadiz oil spill. Generally, in 1980 (except for one heavily polluted site) the amounts of hydrocarbons were found to be far less important than in 1978 and sometimes biogenic hydrocarbons were found. In the superficial layer of the sediments biodegradation processes were generally important with the preferential degradation of n-alkanes. On the other hand, aromatic hydrocarbons seem not to have been altered after three years. Degradation of percolated hydrocarbons proceeds more slowly than in the surface layer. The number of degrading bacteria decreases when n-alkanes disappear.  相似文献   
232.
Samples of used drilling muds collected during the course of a single well drilling operation exhibited different degrees of acute toxicity to sheepshead minnows and grass shrimp. For moulting grass shrimp, Palaemonetes pugio, the 96-h LC50's were 360 to 14 560 ppm (μl/litre); many of these values were considerably lower than those reported from previous drilling mud assays. However, when some of the muds used in this study were tested on sheepshead minnows, Cyprinodon variegatus, the resulting 96-h LC50's (6300 to 100 000ppm) were well within the range of previously reported values.Although a number of the drilling mud samples had relatively high amounts of chromium due to the addition of sodium chromate, there was a low correlation between chromium concentration and toxicity. In only three drilling muds could chromium content alone account for the observed toxicities. Furthermore, chemical analyses revealed the presence of No. 2 fuel oil like petroleum hydrocarbons in the mud samples. Based on the results of toxicity tests with No. 2 fuel oil and the concentrations of oil present in the muds, the toxicity of the mud samples to grass shrimp appears to be largely attributable to the petroleum hydrocarbon content.  相似文献   
233.
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235.
In subaerial volcaniclastic sequences structures formed by ice blocks can provide information about a volcano's history of lahar generation by glacier melt. At Volcán Hudson in Chile, catastrophic lahars were initiated by eruption-induced melting of glacier ice in August and October 1991. They transported large ice blocks 50 km down the Rio de los Huemules valley to the sea. Large current crescents with lee-side lenses were formed where ice blocks were deposited during waning stages of the flood. When stranded blocks of ice melted, they left cone-shaped and ring-shaped heaps of ice-rafted debris on the sediment surface. Several hundred ice blocks were completely buried within the aggrading lahar sediment, and when these melted circular collapse pits formed in the sediment. Collapse types included subsided coherent blocks of sediment bounded by an outward-dipping ring-fracture, trapdoor structures with horseshoe-shaped fractures, downsag pits with centroclinal dips locally up to 60°, pits with peripheral graben and crevasses, piecemeal (highly fragmented) collapse structures and funnel-shaped pits containing disaggregated sediment. A sequence of progressive collapse is inferred in which initial downsag and subsidence on an outward-dipping ring fracture produces a small diameter pit. This is followed by widening of the pit by progressive development of concentric ring fractures and downsag outside the early formed pit, and by collapse of overhanging pit walls to produce vertical to inward-dipping walls and aprons of collapse debris on the pit floor. The various structures have potential for preservation even in regions prone to high rainfall and flooding, and they can be used to indicate that former lahars contained abundant blocks of ice.  相似文献   
236.
This study describes the lithostratigraphic character of mid-Cenozoic (Oligocene-Pliocene) sequences in different parts of the northeastern Mediterranean area and offers a detailed stratigraphic correlation for this region. The sequences concerned are drawn from the Camardi area (south-central Anatolia), the Adana Basin, the Misis Mountains and the Kyrenia Range (northern Cyprus) and the submerged Florence Rise (west of Cyprus). The stratigraphic relationships identified here indicate the following: (a) Following the middle Eocene (Lutetian) regression there was uplift throughout the entire region; (b) Episodes of fluvial and lacustrine deposition in intramontane settings ensued in most of this region during the late Eocene/early Miocene interval; (c) Following a regionally extensive phase of tectonic compression, major marine transgression commenced in the late Oligocene in northern Cyprus and in the early Miocene in adjacent southern Turkey, with the exception of the Ecemi§ Fault Zone where continental deposition continued; (d) These Oligo-Miocene transgressive sequences comprise a broadly diachronous complex of both shallow and deeper marine facies, including reefal carbonates, littoral clastics, basinal shales and fan-turbidites; (e) Deeper marine Miocene facies persisted longer in the Misis area and in northern Cyprus; (f) A regional regression occurred throughout most of the area during the late Serravallian to Tortonian interval and is marked by the abrupt, locally discordant appearance of extensive shallow marine, deltaic and fluvial deposits; (g) Continued regression in the Messinian led to the formation of significant evaporite deposits in the western and southern parts of the region, but localized uplift of the Misis area is attested by the initial deformation of the Neogene rocks there and the absence of Messinian sediments from this area; (h) In the Pliocene there was extensive emergence of the northern parts of the region interrupted by brief marine incursions. The present-day drainage pattern was established at this time; (i) Marine conditions persisted longer in northern Cyprus, where emergence occurred only in the latest Pliocene.  相似文献   
237.
Conodont associations and recent macrofaunal discoveries, allow us to date the beginning of detrital deposits going with the Variscan uplift in the Pyrenean marine basins during the Lower Carboniferous. Thus, the establishing of synorogenic conditions seems to have progressed from the East to the West; there appears the picture of a kind of north-Pyrenean axis already individualized in the wide Cantabrico-Pyrenean foreland.  相似文献   
238.
The 2685–2752 Ma old granite-greenstone crust in the Rainy Lake area, Ontario, consists of metaigneous and metasedimentary rocks that range in composition from tholeiite to monzogranite and include anorthosite, trachyandesite, monzodiorite and high-silica rhyodacite. Major element, rare earth and other trace element data are the basis for modelling the formation of the crust by melting of large-ionlithophile element enriched and unenriched mantle, by melting of basalt at mantle to crustal levels and by melting of monzodiorite and tonalite at crustal levels.

All metaigneous rocks lie on a 143Nd/144Nd vs. 147Sm/144Nd isochron with an age of 2737 ±42 Ma and an initial 143Nd/144Nd of 0.509178 ±33 (εNd = +1.9). This age is consistent with U-Pb zircon ages, which suggests the Nd isotopic system has been unaffected since the crust-forming events. The positive initial εNd's are further evidence for time-averaged depletion in Sm/Nd relative to CHUR for the Archean mantle. The similarity of the initial Nd isotopic composition for both mantle-derived and crustally-derived rocks suggests rapid recycling of crustal components, which were previously derived from depleted mantle sources.

Initial 143Nd/144Nd ratios on individual rocks range from εNd = +3.3 to εNd = −0.4. Younger granitoids have lower εNd values (+1.5 to −0.1) relative to tholeiites and monzodiorites crystallized from mantle-derived melts (+3.3 to +1.0). Thus, incorporation of slightly older crust (ca. 100–200 Ma) in some of the granitoid source areas is possible. Mantle-derived rocks form an isochron of 2764 ±58 Ma that represents a minimum age for enrichment processes in the mantle sources for the Rainy Lake area. Consideration of data from the Abitibi belt suggests such enrichment processes in the mantle may have preceded crust-forming events in a wide area of the Superior Province, perhaps by as much as 50–70 Ma.  相似文献   

239.
New stratigraphical and micropalaeontological data, supplemented by detailed sedimentological and petrographical observations, have been obtained from an almost completely exposed Oligocene-Miocene succession near Celalli in the Zara-Hafik basin, which forms part of a long-lived zone of subsidence associated with the North Anatolian Fault system. Four laterally extensive lithostratigraphical units have been distinguished and ostracod microfaunas indicate that the lower two units are of Middle Oligocene age, while bivalve/brachiopod faunas from the third unit are also Oligocene. The status of the uppermost unit of redbeds remains equivocal, but microfaunas from the capping marls are of lowermost Miocene age.The basal brown sandstone unit was formed in a shallow marine environment dominated by southwards transport of sand by offshore-directed storm-surges, with associated east-west longshore movement also important. The discordantly succeeding limestone unit records a phase of carbonate bar migration across the basin while the third formation (in which medium-scale facies cyclicity is prominent) was formed in a southwards-prograding coastal plain complex, following a renewal of terrigenous supply to this region. The late Oligocene-Miocene redbed unit resulted from continued terrestrial progradation and is characterised by alluvial deposits formed by small, southwards-flowing streams of high sinuosity, ultimately succeeded by carbonate and evaporitic deposits marking the early Miocene marine transgression.Stratigraphical analysis of sandstone petrography reveals a gradual change in provenance through the Oligocene, from sources of »oceanic« character (rich in ophiolitic rocks) to those of »continental« nature (with silicic metamorphics and sedimentary cover-rocks prominent), and the compositional data thus accord with models suggesting closure of a small oceanic or arc-related basin in this region during the late Palaeogene.
Zusammenfassung Aus einer nahezu vollständig aufgeschlossenen Schichtenfolge des Oligozän und Miozän im Gebiet von Celalli im Zara-Hafik-Becken/Türkei werden neue Daten zur Stratigraphie und Mikropaläontologie vorgestellt. Diese werden ergänzt durch sedimentologische und petrographische Beobachtungen. Das Becken ist Teil einer Zone mit lange anhaltender Subsidenz, die mit dem System des Nordanatolischen Lineaments in Verbindung steht. Es lassen sich vier lateral aushaltende lithostratigraphische Einheiten unterscheiden, von denen die beiden unteren mit Ostracoden-Mikrofaunen in das Mittel-Oligozän eingestuft werden. Nach Muschel- und Brachiopoden-Faunen ist die dritte Einheit ebenfalls oligozänen Alters. Das Alter der obersten Einheit von Rotsedimenten ist nicht genau bekannt, doch besitzen die Mikrofaunen der hangenden Mergel ein tiefstmiozänes Alter.Der basale braune Sandstein wurde in einem flachmarinem Milieu gebildet, das von einem südwärts gerichteten Sandtransport durch ablandige Sturmwellen beherrscht wird. Zusätzlich ist eine ost-west-gerichtete Küsten-Längsdrift von Bedeutung. Die diskordant darüber lagernde Kalkfolge wurd durch eine Phase von durch das Becken wandernden karbonatischen Bänken aufgebaut. Die dritte Einheit (in der eine Fazies-Zyklizität mittlerer Größe vorherrscht) baute sich in dem südwärts vorschreitenden Komplex einer Küstenebene auf, die einer neuerlichen terrigenen Schüttung in diesem Gebiet folgt. Die spätoligozän-miozäne Einheit von Rotsedimenten ist das Ergebnis weiter voranschreitender terrestrischer Sedimente. Sie besteht aus alluvialen Ablagerungen von kleinen nach Süden fließenden Flüssen mit hoher Sinuosität, gefolgt von karbonatischen und evaporitischen Bildungen, die die frühmiozäne Transgression anzeigen.Die stratigraphische Analyse der Sandstein-Petrographie offenbart einen allmählichen Wandel der Provenienz im Oligozän, der von »ozeanischem« Liefergebiet (reich an ophiolithischen Gesteinen) zu »kontinentalem« (mit vorherrschend kieseligen Metamorphiten und sedimentärer Bedeckung) überwechselt. Die Zusammensetzung stimmt mit Modellen überein, die die Schließung eines kleinen ozeanischen oder inselbogen-artigen Beckens während des späten Paläogens nahelegen.

Résumé De nouvelles données stratigraphiques et micropaléontologiques, associées à des observations sédimentologiques et pétrographiques détaillées ont été recueillies dans une série oligocène-miocène exposée de manière presque complète près de Celalli dans le bassin de Zara-Hafik, lequel fait partie d'une zone de subsidence de longue durée associée au système de failles de l'Anatolie du Nord. Quatre unités lithostratigraphiques d'extension latérale notable ont été distinguées. Les deux unités inférieures sont datées de l'Oligocène moyen par une microfaune à Ostracodes, et la troisième de l'Oligocène par une faune à brachiopodes et autres bivalves; l'âge de l'unité supérieure reste incertain, mais les marnes terminales renferment une microfaune éo-miocène.L'unité inférieure, constituée de grès bruns, s'est formée dans un milieu marin peu profond dans lequel le sable était transporté à la fois vers le large (vers le Sud), par des vagues de tempête, et vers l'Ouest parallèlement au rivage. La deuxième unité, discordante et de nature calcaire, témoigne de la migration d'une barre carbonatée à travers le bassin. La troisième unité, caractérisée par une disposition cyclique des faciès à moyenne échelle, a été élaborée dans un complexe de plaine côtière progressant vers le Sud, comme suite à de nouveaux apports terrigènes. La quatrième unité (Oligocène tardif-Miocène), formée de couches rouges, résulte d'une sédimentation continentale continue et consiste en alluvions déposées par de petits cours d'eau très sinueux coulant vers le Sud; ces couches sont surmontées finalement de dépôts carbonates et évaporitiques marquant la transgression éo-miocène.L'analyse pétrographique du grès, opérée en fonction de la stratigraphie, révèle au cours de l'Oligocène un changement graduel de provenance, depuis un domaine nourricier de type »océanique« (riche en ophiolites) jusqu'à un domaine de type »continental« (à dominance de roches métamorphiques et sédimentaires siliceuses). Ces données sont en accord avec un modèle suggérant la fermeture d'un petit bassin océanique ou d'arc insulaire pendant le Paléogène tardif.

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240.
The mid-Tertiary volcanic sequence of the central Sierra Madre Occidental in Chihuahua, Mexico, is about one kilometer thick and is composed predominantly of rhyolitic ignimbrites. Basaltic andesite to dacitic lavas are interbedded with the rhyolites, but they are of minor volumetric importance. Rare earth element (REE) data are used to constrain a crustal anatexis model for the origin of the voluminous ignimbrites and to test a fractional crystallization model. The REE patterns indicate that if the rhyolites were formed by direct crustal anatexis, the residue from partial melting could contain no more than a few percent garnet or about 20% hornblende. This eliminates residues with the mineralogy of amphibolite, eclogite, or garnet granulite, but melting of a garnet-free granulite source is permitted. The crustal anatexis model is difficult to evaluate critically because of a lack of knowledge concerning the mid-Tertiary geothermal gradient and the composition of the crust beneath the Sierra Madre Occidental.In contrast, the fractional crystallization model can be tested rigorously. Rayleigh fractionation calculations are used to closely model REE patterns in the basaltic andesite to rhyolite series. The minerals involved are those occurring as phenocryst phases, and the mineral proportions were generated by leastsquares major element calculations. The results of the calculations are consistent with the hypothesis that the voluminous rhyolites originated by plagioclase-dominated crystal fractionation.  相似文献   
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