Organic matter and metamorphic history of CO chondrites     

Lydie Bonal  Michèle Bourot-Denise  Gilles Montagnac 《Geochimica et cosmochimica acta》2007,71(6):1605-1623

The metamorphic grades of a series of eight CO3 chondrites (ALHA77307, Colony, Kainsaz, Felix, Lancé, Ornans, Warrenton and Isna) have been quantified. The method used was based on the structural grade of the organic matter trapped in the matrix, which is irreversibly transformed by thermal metamorphism. The maturation of the organic matter is independent with respect to the mineralogical context and aqueous alteration. This metamorphic tracer is thus valid whatever the chemical class of chondrites. Moreover, it is sensitive to the peak metamorphic temperature.The structural grade of the organic matter was used along with other metamorphic tracers such as petrography of opaque minerals, Fa and Fs silicate composition in type I chondrules, presolar grains and noble gas (P3 component) abundance. The deduced metamorphic hierarchy and the attributed petrographic types are the following: ALHA77307 (3.03) < Colony (3.1) < Kainsaz (3.6) < Felix (3.6 (1)) < Ornans (3.6 (2)) < Lancé (3.6 (3)) < Warrenton (3.7 (1)) < Isna (3.7 (2)).For most metamorphosed objects, the peak metamorphic temperature can be estimated using a geothermometer calibrated with terrestrial metasediments [Beyssac O., Goffe B., Chopin C., and Rouzaud J. N. (2002) Raman spectrum of carbonaceous material in metasediments: a new geothermometer. J. Metamorph. Geol., 20, 859-871]. A value of 330 °C was obtained for Allende (CV chondrite), Warrenton and Isna, consistent with temperatures estimated from Fe diffusion [Weinbruch S., Armstrong J., and Palme H. (1994). Constraints on the thermal history of the Allende parent body as derive from olivine-spinel thermometry and Fe/Mg interdiffusion in olivine. Geochim. Cosmochim. Acta58(2), 1019-1030.], from the Ni content in sulfide-metal assemblages [Zanda B., Bourot-Denise M., and Hewins R. (1995) Condensate sulfide and its metamorphic transformations in primitive chondrites. Meteorit. Planet. Sci.30, A605.] and from the d₀₀₂ interlayer spacing in poorly graphitized carbon [Rietmeijer, F., and MacKinnon, I. (1985) Poorly graphitized carbon as a new cosmothermometer for primitive extraterrestrial materials. Nature, 315, 733-736]. The trapped noble gas and C content appear to be sensitive but not precise metamorphic tracers, indicating that the “Ornans paradox” does not exist. Major problems with the current petrologic types derived from Induced ThermoLuminescence are pointed out.  相似文献   

Late Pleistocene (MIS 3–4) climate inferred from micromammal communities and δO of rodents from Les Pradelles,France     

Aurélien Royer  Christophe Lécuyer  Sophie Montuire  Gilles Escarguel  François Fourel  Alan Mann  Bruno Maureille 《Quaternary Research》2013

The middle Paleolithic stratigraphic sequence of Les Pradelles (Charente, France) spans from the end of Marine Isotope Stage (MIS) 4 until the middle of MIS 3. Micromammal remains are present in all the stratigraphic levels, offering a rare opportunity to address the questions of both environmental and climatic fluctuations throughout this period. Climate modes were studied through the taphonomy, biodiversity and oxygen isotope compositions of phosphate (δ¹⁸O_p) from 66 samples of rodent tooth enamel. The δ¹⁸O_p values from the lower sedimentary levels provide summer mean air temperatures of 19 ± 2°C (level 2/1) and of 16 ± 2°C (levels 2A, 2B and 4A). Within the middle of sequence (level 4B), a paleobiodiversity change can be identified with an increase of Dicrostonyx torquatus, which is associated with the largest amplitude in δ¹⁸O_p values and the highest maximal δ¹⁸O_p values. At the top of the sequence (level 5-2), a biodiversity change is observed with the increase of Microtus arvalis, but without any change in δ¹⁸O_p values. The association of cold rodent species with unexpected high and large amplitudes in the δ¹⁸O_p values of their teeth, possibly indicative of aridity, suggests their deposition during a Heinrich event.  相似文献   

Sea-Spray-Generation Dependence on Wind and Wave Combinations: A Laboratory Study     

Bruch  William  Piazzola  Jacques  Branger  Hubert  van Eijk  Alexander M. J.  Luneau  Christopher  Bourras  Denis  Tedeschi  Gilles 《Boundary-Layer Meteorology》2021,180(3):477-505

Boundary-Layer Meteorology - We investigate the effects of wind–wave interactions on the surface sea-spray-generation flux. To this end, the Marine Aerosol Tunnel Experiment (MATE2019) was...  相似文献   

The effects of surface weathering on the geochemical analysis of archaeological lithic samples using non‐destructive polarized energy dispersive XRF     

Gilles Gauthier  Adrian L. Burke 《Geoarchaeology》2011,26(2):269-291

The purpose of this paper is to show the effects of lithic artifact surface weathering on whole rock non‐destructive polarized energy dispersive X‐ray fluorescence (P‐ED‐XRF) major and trace element determinations. Chemical results for a weathered and subsequently mechanically ground subset of New Hampshire Ossipee archaeological flakes, cataloged as hornfels, show that both groups of elements are variably affected by weathering. A graphic approach is developed and proposed to highlight the role and importance of immobile elements. A case is made and an analytical method is proposed for the routine use of P‐ED‐XRF spectrometers to determine the chemical makeup of lithic artifacts and therefore provide a data set compatible with existing geochemical databases and literature. The use of specific variation diagrams is adopted to portray the weathering trend. Internationally approved geochemical rock type diagrams are used to correct the rock type previously assigned to Ossipee artifacts and in turn narrow down potential quarry sources. © 2011 Wiley Periodicals, Inc.  相似文献   

Coupes équilibrees crustales : méthodologie et application aux Alpes occidentales     

Gilles Menard  François Thouvenot 《Geodinamica Acta》2013,26(1):35-45

Résumé

La construction de coupes équilibrées à l’échelle de la croûte ainsi que leur remise à l’état avant déformation suivent les règles générales de construction des coupes équilibrées (conservation des longueurs et des surfaces entre l’état avant déformation et l’état actuel), mais présentent des caractères qui leur sont propres (nécessité de connaître les mouvements verticaux importants qui accompagnent les déformations à cette échelle ainsi que le mode de déformation de la croûte).

Un exemple de construction de telles coupes est proposé pour les Alpes occidentales. Ces coupes, équilibrées pour le chevauchement crustal des massifs cristallins externes (Burdigalien-Actuel), traduisent un raccourcissement crustal variant de 10 km environ au niveau du Vercors à 55 km environ au niveau des Préalpes. Elles permettent d’intégrer dans un modèle unique un certain nombre de phénomènes comme le raccourcissement crustal, le raccourcissement dans la couverture, la subsidence du bassin molassique, la surrection des massifs cristallins externes, le rétrodéversement des structures en arrière de ces massifs.  相似文献   

Example of Neogene tectonic indentation in the Eastern Betic Cordilleras: the Arc of Aguilas (Southeastern Spain)     

Gilles Coppier  Philippe Griveaud  François-Dominique de Larouziere  Christian Montenat  Philippe Ott d’Estevou 《Geodinamica Acta》2013,26(1):37-51

Abstract

Neogene deformations have deeply disturbed the initial architecture of the pile of nappes within the Eastern Betic zone. The Arc of Aguilas, displaying a southeast-facing concavity, is a spectacular example of such a post-nappe structuration. Miocene deposits involved in the torsion of the Arc provide a chronology of the deformation. The Arc of Aguilas is one element within a system of rigid-plastic indentation including the following units, from the inner (SE) to the outer (NW) zones : — A rigid block, little deformed, located in the present day abyssal plain, play the part of the indenter.

— A structural pad corresponding to the Aguilas Arc itself. It was severely folded during Miocene times.

— A large peripheral zone mainly subjected to faulting during the Neogene (essentially strike-slip faults). These faults control the evolution of different types of sedimentary basins during the Late Neogene (Tortonian to Pliocene).

Two large shear zones: N020 sinistral (Palomares and Terreros faults), N100 dextral (Las Moreras faults) guided the deformation of the Aguilas Arc within a compressive stressfield of which major tensor axis oscillated between NW-SE and N-S.  相似文献   

Influence of plankton concentration on gametogenesis and spawning of the black lip pearl oyster Pinctada margaritifera in Ahe atoll lagoon (Tuamotu archipelago, French polynesia)     

Fournier J  Levesque E  Pouvreau S  Pennec ML  Moullac GL 《Marine pollution bulletin》2012,65(10-12):463-470

Pearl culture industry represents one of the dominant business sector of French Polynesia. However, it still entirely relies on unpredictable spat collection success. Our aim was to assess the influence of natural plankton concentration fluctuations on maturation and spawning of the black lip pearl oyster Pinctada margaritifera, during a 4months survey conducted in Ahe atoll lagoon. Plankton concentration was assessed by chlorophyll a extraction and by microscope counts while gonadic index, gonado-visceral dry weights and histology were used to measure pearl oysters reproduction activity. We found that (i) plankton concentration fluctuations were mainly related to wind regime, (ii) gametogenesis rate was mainly related to plankton concentration, (iii) spawning occurred when maximal gonad storage was reached, (iv) plankton concentration was the main spawning synchronizing factor. These results contribute explaining P. margaritifera spat collection variability in French Polynesian atoll lagoon.  相似文献   

Unraveling the patterns of late Holocene debris-flow activity on a cone in the Swiss Alps: Chronology, environment and implications for the future     

Markus Stoffel  Delphine Conus  Michael A. Grichting  Igor Livre  Gilles Maître 《Global and Planetary Change》2008,60(3-4):222-234

Debris-flow activity on the forested cone of the Ritigraben torrent (Valais, Swiss Alps) was assessed from growth disturbances in century-old trees, providing an unusually complete record of past events and deposition of material. The study of 2246 tree-ring sequences sampled from 1102 Larix decidua Mill., Picea abies (L.) Karst. and Pinus cembra ssp. sibirica trees allowed reconstruction of 123 events since AD 1566. Geomorphic mapping permitted identification of 769 features related to past debris-flow activity on the intermediate cone. The features inventoried in the study area covering 32 ha included 291 lobes, 465 levées and 13 well-developed debris-flow channels. Based on tree-ring records of disturbed trees growing in or next to the deposits, almost 86% of the lobes identified on the present-day surface could be dated. A majority of the dated material was deposited over the last century. Signs of pre-20th century events are often recognizable in the tree-ring record of survivor trees, but the material that caused the growth anomaly in trees has been completely overridden or eroded by more recent debris-flow activity.Tree-ring records suggest that cool summers with frequent snowfalls at higher elevations regularly prevented the release of debris flows between the 1570s and 1860s; the warming trend combined with greater precipitation totals in summer and autumn between 1864 and 1895 provided conditions that were increasingly favorable for releasing events from the source zone. Enhanced debris-flow activity continued well into the 20th century and reconstructions show a clustering of events in the period 1916–1935 when warm–wet conditions prevailed during summer in the Swiss Alps. In contrast, very low activity is observed for the last 10-yr period (1996–2005) with only one debris-flow event recorded on August 27, 2002. Since sediment availability is not a limiting factor, this temporal absence of debris-flow activity is due to an absence of triggering events, which not only shifted from June and July to August and September over the 20th century, but also seemed to be initiated primarily by persistent precipitation rather than summer thunderstorms. From the reconstructions, based on RCM simulations, there are indications that debris-flow frequencies might continue to decrease in the future, as precipitation events are projected to occur less frequently in summer but become more common in spring or autumn.  相似文献   

High-pressure yield strength of rocksalt structures using quartz Raman piezometry     

Bruno Reynard  Razvan Caracas  Hervé Cardon  Gilles Montagnac  Sébastien Merkel 《Comptes Rendus Geoscience》2019,351(2-3):71-79

The Raman frequencies of quartz are used to evaluate deviatoric stresses in rocksalt-structure media in diamond-anvil cell experiments to pressures up to 20 GPa. The piezospectroscopic effect in quartz is modeled by first-principles calculations. Non-hydrostatic stresses measured in halogen salts give yield strength estimates of 3 GPa in the B1 structure (NaCl), and 4.5 GPa for the B2 structure (KCl and KBr). Raman measurements in MgO show that the yield strength is reached at around 6 ± 1 GPa. Measurements on quartz alone indicate similar yield strength. The estimated yield strength in MgO is thus likely a lower bound, in consistency with former radial X-ray diffraction measurements that gave a yield strength of 8 ± 1 GPa, and lower-pressure large-volume press experiments indicating a yield strength of 6 GPa at 5 GPa. Former values of the yield strength below 2 GPa determined by pressure gradient measurements were underestimated due to unverified assumptions in boundary conditions. The yield strength increases with increasing coordination of ionic solids, likely contributing to increase viscosity at phase transitions near the upper–lower mantle boundary.  相似文献   

Thermodynamic properties of chlorite CCa-2. Heat capacities, heat contents and entropies     

H. Gailhanou  J. Rogez  A.C.G. van Genderen  C. Gilles  N. Michau  P. Blanc 《Geochimica et cosmochimica acta》2009,73(16):4738-4749

The heat capacities of the international reference clay mineral chlorite CCa-2 from Flagstaff Hill, California, were measured by low temperature adiabatic calorimetry and differential scanning calorimetry, from 5 to 520 K (at 1 bar). The studied chlorite is a Fe-bearing trioctahedral chlorite with an intermediary composition between ideal clinochlore (Si₃Al)(Mg₅Al)O₁₀(OH)₈ and chamosite (Si₃Al)(Fe₅Al)O₁₀(OH)₈. Only few TiO₂ impurities were detected in the natural chlorite sample CCa-2. Its structural formula, obtained after subtracting the remaining TiO₂ impurities, is (Si_2.633Al_1.367)(Al_1.116Mg_2.952Mn_0.012Ca_0.011)O₁₀(OH)₈. From the heat capacity results, the entropy, standard entropy of formation and heat content of the chlorite were deduced. At 298.15 K, the heat capacity of the chlorite is 547.02 (±0.27) J mol⁻¹ K⁻¹ and the molar entropy is 469.4 (±2.9) J mol⁻¹ K⁻¹. The standard molar entropy of formation of the clay mineral from the elements is −2169.4 (±4.0) J mol⁻¹ K⁻¹.  相似文献