Relative importance of acid coating on ice nuclei in the deposition and contact modes for wintertime Arctic clouds and radiation     

Eric Girard  Niloofar Sokhandan Asl 《Meteorology and Atmospheric Physics》2014,123(1-2):81-92

Aerosols emitted from volcanic activities and polluted mid-latitudes regions are efficiently transported over the Arctic during winter by the large-scale atmospheric circulation. These aerosols are highly acidic. The acid coating on ice nuclei, which are present among these aerosols, alters their ability to nucleate ice crystals. In this research, the effect of acid coating on deposition and contact ice nuclei on the Arctic cloud and radiation is evaluated for January 2007 using a regional climate model. Results show that the suppression of contact freezing by acid coating on ice nuclei leads to small changes of the cloud microstructure and has no significant effect on the cloud radiative forcing (CRF) at the top of the atmosphere when compared with the effect of the alteration of deposition ice nucleation by acid coating on deposition ice nuclei. There is a negative feedback by which the suppression of contact freezing leads to an increase of the ice crystal nucleation rate by deposition ice nucleation. As a result, the suppression of contact freezing leads to an increase of the cloud ice crystal concentration. Changes in the cloud liquid and ice water contents remain small and the CRF is not significantly modified. The alteration of deposition ice nucleation by acid coating on ice nuclei is dominant over the alteration of contact freezing.  相似文献   

Ground penetrating radar imaging and time-domain modelling of the infiltration of diesel fuel in a sandbox experiment     

Maksim Bano  Olivier Loeffler  Jean-François Girard 《Comptes Rendus Geoscience》2009,341(10-11):846-858

Ground penetrating radar (GPR) is a non-destructive method which, over the past 10 years, has been successfully used not only to estimate the water content of soil, but also to detect and monitor the infiltration of pollutants on sites contaminated by light non-aqueous phase liquids (LNAPL). We represented a model water table aquifer (72 cm depth) by injecting water into a sandbox that also contains several buried objects. The GPR measurements were carried out with shielded antennae of 900 and 1200 MHz, respectively, for common mid point (CMP) and constant offset (CO) profiles. We extended the work reported by Loeffler and Bano by injecting 100 L of diesel fuel (LNAPL) from the top of the sandbox. We used the same acquisition procedure and the same profile configuration as before fuel injection. The GPR data acquired on the polluted sand did not show any clear reflections from the plume pollution; nevertheless, travel times are very strongly affected by the presence of the fuel and the main changes are on the velocity anomalies. We can notice that the reflection from the bottom of the sandbox, which is recorded at a constant time when no fuel is present, is deformed by the pollution. The area close to the fuel injection point is characterized by a higher velocity than the area situated further away. The area farther away from the injection point shows a low velocity anomaly which indicates an increase in travel time. It seems that pore water has been replaced by fuel as a result of a lateral flow. We also use finite-difference time-domain (FDTD) numerical GPR modelling in combination with dielectric property mixing models to estimate the volume and the physical characteristics of the contaminated sand.  相似文献   

Interpretation of magnetic resonance soundings in rocks with high electrical conductivity   总被引：1，自引：0，他引：1  

A. Legchenko  M. Ezersky  J.-F. Girard  J.-M. Baltassat  M. Boucher  C. Camerlynck  A. Al-Zoubi   《Journal of Applied Geophysics》2008,66(3-4):118

Magnetic resonance sounding (MRS) is an electromagnetic method designed for groundwater investigations. MRS can be applied not only for studying fresh-water aquifers, but also in areas where intrusion of saline water is rendering the subsurface electrically conductive. In the presence of rocks with a high electrical-conductivity attenuation and a phase shift of the MRS signal may influence the efficiency of the MRS method. We investigated the performance of MRS for allowing us to propose a procedure for interpreting MRS data under these conditions. For numerical modeling, we considered a subsurface with a resistivity between 0.5 and 10 Ω m. The results show that the depth of investigation with MRS depends upon the electrical conductivity of groundwater and surrounding rocks, on the depth of the saline water layer, and on the amount of fresh water above the saline water. For interpreting MRS measurements, the electrical conductivity of the subsurface is routinely measured with an electrical or electromagnetic method. However, due to the equivalence problem, the result obtained with these methods may be not unique. Hence, we investigated the influence of the uncertainty in conductivity distribution provided by transient electromagnetic measurements (TEM) on MRS results. It was found that the uncertainty in TEM results has an insignificant effect on MRS.  相似文献   

Direct migration of ambient seismic data     

Aaron J. Girard  Jeffrey Shragge 《Geophysical Prospecting》2020,68(1):270-292

Utilising ambient seismic energy naturally propagating in the Earth as an alternative approach to active body-wave seismic investigations has been a topic of interest for a number of decades. However, because ambient surface-wave arrivals typically are of much greater amplitude than ambient body-wave energy, significant data signal processing and long recording times are required to mitigate this and other coherent noise sources, and to correlate sufficient reflected body-wave energy to converge to a stable image. Even for these scenarios, identifying and validating imaged body-wave reflection events remain challenging. In active-source investigations, extended imaging condition gathers are used to examine velocity (in)accuracy. Herein, we develop an ambient direct migration approach that uses a novel ambient (deconvolution) extended imaging condition. We simulate synthetic ambient-wavefield seismic data for two different models and use a field data set from Lalor Lake in Manitoba, Canada, to conduct a series of numerical experiments to demonstrate the velocity sensitivity and long-term stationarity of ambient-wavefield seismic data in the migration image domain. Tests with varying global velocity perturbations show a characteristic reflector moveout in deconvolution extended imaging condition gathers that can serve as a diagnostic of reflected ambient body-wave energy. We illustrate that this imaging formalism, under idealised circumstances, gives comparable results to conventional seismic methods, which extends the use of extended imaging condition gather-based image validation to ambient-wavefield seismic data scenarios. We assert that this may be a valuable tool for the validation of ambient migration techniques that to date have yielded largely inconclusive results.  相似文献   

Oxygen and carbon isotope composition of structural carbonate in weathering apatites from laterites, southern Brazil and western Senegal     

Jean-Pierre Girard  Ren Flicoteaux  Anne-Vronique Walter  Samuel M. Savin  Daniel Nahon 《Applied Geochemistry》1993,8(6)

The oxygen (δ¹⁸O_c) and carbon (δ¹³C_c) isotope compositions of the structural carbonate group (CO₃) in apatites from lateritic profiles were investigated. The weathering profiles, located in southern Brazil and in western Senegal, are developed on three different types of apatite-rich parent rock: carbonatite, metamorphosed marine phosphorite and sedimentary marine phosphorite. The parent rock apatites are of magmatic, hydrothermal, metamorphic and sedimentary origins. The in situ formation of apatite of weathering origin in the profiles is well documented petrographically and geochemically.The overall range of measured δ¹⁸O_c and δ¹³C_c values of apatites of weathering origin (22 to 27 SMOW for δ¹⁸O_c and −15 to −10 PDB for δ¹³C_c) is much smaller than the range of measured and/or published isotope compositions of parent rock apatites (4–35 for δ¹⁸O_c and −11 to +1 for δ¹³C_c). In any profile, the apatites of weathering origin can exhibit lower, similar or higher δ¹⁸O_c values than parent rock apatites. In contrast, their δ¹³C_c values are systematically and significantly lower than those of the parent rock apatites. Apatites formed as a result of weathering in laterites can therefore be readily distinguished from apatites of other origin on the basis of their isotope composition.Assuming that apatite CO₃ fractionates O in a way similar to calcite CO₃, the structural carbonate group of the apatites of weathering origin appears to form in approximate isotopic equilibrium with the weathering solutions. The very low δ¹³C_c values exhibited by these apatites indicate that the dominant sources of dissolved CO₂ in the soil water are organic. The isotope composition of structural carbonate in apatite of weathering origin in lateritic profiles may provide useful information for paleoenvironmental studies.  相似文献   

Pigmenting agents in Martian soils: inferences from spectral, Mossbauer, and magnetic properties of nanophase and other iron oxides in Hawaiian palagonitic soil PN-9     

Morris RV  Golden DC  Bell JF rd  Lauer HV  Adams JB 《Geochimica et cosmochimica acta》1993,57(19):4597-4609

We have examined a Hawaiian palagonitic tephra sample (PN-9) that has spectroscopic similarities to Martian bright regions using a number of analytical techniques, including Mossbauer and reflectance spectroscopy, X-ray diffraction, instrumental neutron activation analysis, electron probe microanalysis, transmission electron microscopy, and dithionite-citrate-bicarbonate extraction. Chemically, PN-9 has a Hawaiitic composition with alkali (and presumably silica) loss resulting from leaching by meteoric water during palagonitization; no Ce anomaly is present in the REE pattern. Mineralogically, our results show that nanophase ferric oxide (np-Ox) particles (either nanophase hematite (np-Hm) or a mixture of ferrihydrite and np-Hm) are responsible for the distinctive ferric doublet and visible-wavelength ferric absorption edge observed in Mossbauer and reflectivity spectra, respectively, for this and other spectrally similar palagonitic samples. The np-Ox particles appear to be imbedded in a hydrated aluminosilicate matrix material; no evidence was found for phyllosilicates. Other iron-bearing phases observed are titanomagnetite, which accounts for the magnetic nature of the sample; olivine; pyroxene; and glass. By analogy, np-Ox is likely the primary pigmenting agent of the bright soils and dust of Mars.  相似文献   

Stability functions correct at the free convection limit and consistent for for both the surface and Ekman layers     

Yves Delage  Claude Girard 《Boundary-Layer Meteorology》1992,58(1-2):19-31

For the thermal stability function _h used to calculate heat and moisture fluxes in the surface layer, we choose a formulation which has the theoretically correct free convection limit % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaeikaiabgk% HiTGqaciaa-PhacaqGVaGaamitaiaabMcadaahaaWcbeqaaiabgkHi% TiaaigdacaGGVaGaaG4maaaaaaa!3DFE!\[{\rm{(}} - z{\rm{/}}L{\rm{)}}^{ - 1/3} \]. We then use the experimental result that z/L Ri to deduce a formulation with an exponent -1/6 for the momentum stability function _m. This formulation also resolves the matching problem at the interface between the surface and Ekman layers. The proposed functions are found to remain reasonably close to another formulation that is well supported by observations and has exponents -1/2 for _h and -1/4 for _m. The intent of the proposals is mainly to clarify and simplify the parameterization of the convective boundary layer in present day atmospheric models, without significantly altering the results.  相似文献   

High-pressure and high-temperature deformation experiments on polycrystalline wadsleyite using the rotational Drickamer apparatus     

Robert Farla  George Amulele  Jennifer Girard  Nobuyoshi Miyajima  Shun-ichiro Karato 《Physics and Chemistry of Minerals》2015,42(7):541-558

  相似文献   

敦煌三危山地区白垩纪OIB型基性岩墙的特征及地质意义   总被引：4，自引：3，他引：1  

冯志硕  张志诚  李建锋  郭召杰 《岩石学报》2010,26(2):607-616

本文首次报道甘肃敦煌三危山地区早白垩世玄武质岩浆活动的记录。在三危山附近,基性岩墙侵入于敦煌群TTG和表壳岩大理岩和片岩中。全岩的K-Ar年龄为136.00±11.56Ma到99.11±6.35Ma,形成时代属于早白垩世。基性岩墙SiO₂含量变化范围较小,集中在47.95%~50.65%之间,以富TiO₂ (2.07%~2.35%,平均为2.21%)、MgO(6.03 %~6.51%,平均为6.32%)、贫K₂O(<1.29%),Na₂O>K₂O, Mg^#值中等且比较稳定(48.9~53.1,平均为51.7)为特征。基性岩相容元素含量相对较低,Ni含量变化相对较小,分布在112.7×10^-6~182.7×10^-6之间。而V含量变化较大,介于184×10^-6~267×10^-6之间,表明岩浆早期可能发生了一定的以橄榄石和单斜辉石为主的分离结晶作用。基性岩富集LREE((La/Yb)_N ＝3.97~4.66)和LILE,无Eu负异常,较高的Fe/Mn比值等,具有与洋岛玄武岩(OIB)相似的特征。微量元素比值等特征表明其来源与富集地幔关系密切,玄武质岩浆的形成可能与岩石圈的减薄和软流圈的上涌有关。  相似文献   

华北地台南缘张士英岩体的锆石SHRIMP U-Pb测年、Hf同位素组成及其地质意义   总被引：6，自引：3，他引：3  

向君峰  赵海杰  李永峰  程彦博  高亚龙  侯可军  董春艳  李向前 《岩石学报》2010,26(3):871-887

张士英岩体位于华北地台南缘,岩石类型包括钾长花岗岩、似斑状花岗岩和石英斑岩脉,其中只在钾长花岗岩中发育有暗色岩石包体,在包体和寄主岩中发育反映岩浆混合作用的岩石结构。钾长花岗岩、似斑状花岗岩和石英斑岩脉的SHRIMP锆石U-Pb年龄分别为107.3±2.4Ma、106.7±2.5Ma和101±3Ma。锆石Hf同位素分析结果显示,钾长花岗岩的锆石εHf(t)为-15.96～-20.80,单阶段模式年龄(tDM1)为1396～1643Ma,两阶段模式年龄(tDM2)为1880～2018Ma;似斑状花岗岩的锆石εHf(t)为-18.97～-22.18,tDM1为1512～1640Ma,tDM2为1925～2080Ma;除了一粒年龄为2.6Ga的锆石具有εHf(t)为-0.71、tDM1为2943Ma和tDM2为3036Ma的组成,石英斑岩的锆石εHf(t)为-23.41～-27.95,tDM1为1678～1896Ma,tDM2为2144～2330Ma。这些数据暗示,除了存在少量太古宙地壳物质的贡献外,张士英岩体的物质来源可能主要为1.9～2.3Ga期间形成的新生地壳,但也不排除古老地壳与富集地幔源混合的可能。综合分析前人研究成果表明,在太平洋板块俯冲方向发生转变的过程中,先存断裂带发生拉张。张士英岩体与中国东部同期岩浆活动一起可能形成于这种受断裂带控制的伸展环境。  相似文献