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71.
Variation in13C/12C and18O/16O ratios in the shell carbonate of several species of land snails was studied along a climatic gradient in semi-arid to arid areas in the southern Levant.13C was found to be enriched in snails from communities having plants with a C4 photosynthetic pathway. Depleted δ13C values were found in areas with high mean annual rainfall, apparently due to higher input of metabolic CO2 as a result of greater snail activity. Shell carbonate δ18O values show a weak relation to the δ18O values of rainwater. The shell δ18O values are enriched by 2–8‰ relative to isotopic equilibrium with environmental waters. Enrichment is suggested to result from metabolic effects on body water (with lower activity producing greater enrichment) but evaporation could also be a factor. Consistent differences in both13C and18O were found among species and may relate to the time when shell deposition occurs. As with most paleoenvironmental indicators, the application of shell isotopes is complicated by the multiplicity of controls of isotopic composition.  相似文献   
72.
Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ18O = +5.7 to +6.6 (‰ SMOW) andδ34S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ18O = +6.3 ± 0.2 are slightly enriched in18O with respect to unfractionated basalts of<53%SiO2 with meanδ18O = +6.0 ± 0.1. This18O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ18O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ18OSiO2 trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO2; therefore, the meanδ34S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of18O and34S in Mariana Arc parental magmas relative to ocean floor basalts withδ18O ca. + 5.7‰ andδ34S = ca.0.3‰ is attributed to the recycling of18O- and34S-rich crustal components (sediment withδ18O = ca. + 25‰ and seawater sulfate withδ34S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments.  相似文献   
73.
Catastrophic floods from glacial Lake Missoula entered the Pasco Basin in south-central Washington and backflooded its marginal valleys. Badger Coulee, one such valley, contains beds of fine-grained slackwater sediment deposited by these floods. The slackwater sediment contains two ash layers of the Mount St. Helens set S tephra, about 13,000 yr old. The ash was deposited on a ground surface developed atop slackwater sediment deposited during preash flooding. Evidence of the former ground surface includes the reworked ash, inferred trace fossils, stream and debris-flow deposits, slopewash and/or eolian sediment, and colluvium at the ash horizon. These features and the ash were buried by slackwater sediment deposited during postash flooding. Nonflood, subaerial deposits are not present atop other beds. Instead, beds commonly are reversely graded across “contacts,” suggesting that multiple beds were continuously deposited. The exposed beds thus record at least two late-Wisconsin floods, one preash, the other postash. The pre- and postash floods may be correlative with earlier-reported floods thought to have occurred 17,500-14,000 and 14,000–13,000 yr B.P., respectively.  相似文献   
74.
Mineralogical and petrographic studies of a wide variety of refractory objects from the Murchison C2 chondrite have revealed for the first time melilite-rich and feldspathoid-bearing inclusions in this meteorite, but none of these is identical to any inclusion yet found in Allende. Blue spinel-hibonite spherules have textures indicating that they were once molten, and thus their SiO2-poor bulk composition requires that they were exposed to higher temperatures (>1550°C) than those deduced so far from any Allende inclusion. Melilite-rich inclusions are similar to Allende compact Type A's, but are more Al-, Ti-rich. One inclusion (MUCH-1) consists of a delicate radial aggregate of hibonite crystals surrounded by alteration products, and probably originated by direct condensation of hibonite from the solar nebular vapor. The sinuous, nodular and layered structures of another group of inclusions, spinel-pyroxene aggregates, suggest that these also originated by direct condensation from the solar nebular gas. Each type of inclusion is characterized by a different suite of alteration products and/or rim layers from all the other types, indicating modification of the inclusions in a wide range of different physico-chemical environments after their primary crystallization. All of these inclusions contain some iron-free rim phases. These could not have formed by reaction of the inclusions with fluids in the Murchison parent body because the latter would presumably have been very rich in oxidized iron. Other rim phases and alteration products could have formed at relatively low temperatures in the parent body, but some inclusions were not in the locations in which they were discovered when this took place. Some of these inclusions are too fragile to have been transported from one region to another in the parent body, indicating that low temperature alteration of these may have occurred in the solar nebula.  相似文献   
75.
The judicious choice of dipolar dephasing times or carbon magnetization holding times has been shown to improve resolution in solid state nuclear magnetic resonance (NMR) spectra of complex materials. Signals from protonated and alkylated aromatic carbons are reduced to enhance resolution of aromatic oxygenated groups. Rapidly rotating methyl groups can be resolved from other aliphatic carbon types. These techniques were used to investigate the structure of a brown coal, xylite fractions of a brown coal, a bituminous coal, an oil shale and a solvent-refined coal. The results allow estimates of the fraction of aromatic carbon that is protonated in coal to be made, and demonstrate that methyl groups in coal rotate rapidly at room temperature.  相似文献   
76.
In two of the perennially ice-covered lakes in the McMurdo Dry Valleys, lakes Hoare and Bonney in the Taylor Valley, bottom water has 14C ages of 2.7 ka and 10 ka (respectively), rendering 14C ages of bottom sediments highly problematic. Consequently, we tested the effectiveness of thermoluminescence (TL) zeroing in polymineral fine silt material from several depositional environments around and on the lake (stream suspensions, ice-surface sand dune, and silty sand from near the top of the more-than-3m-thick ice). We also conducted TL and infrared-stimulated-luminescence (IRSL) dating tests on material from three box cores recovered from the bottom of Lake Hoare, in a transect away from the abutting Canada Glacier. We observed effective zeroing of light-sensitive TL in suspended silt from one input stream and less effective zeroing from another stream. We observed effective zeroing of light-sensitive TL also in silt from a glacier-proximal eolian ice-surface dune and from sand from within the upper 5 cm of ice. In contrast, in box-core 1, the bottom sediment yielded minimum TL apparent ages of 1500-2600 yrs, with no discernable stratigraphic depth trend. IRSL dating applied to the same box-core samples produced significantly lower age estimates, ranging from ~600 ± 200 yrs to 1440 ± 270 yrs top-to-bottom, an improvement over the depth-constant ~2200 yrs TL ages. In two other cores closer to the Canada Glacier, IRSL ages from ~600 ± 200 yrs (top) to ~ 2900± 300 yrs (at depth) were measured. Not only are the IRSL ages a significant improvement over the TL results, but the near-core-top IRSL ages are also a dramatic improvement over the 14C results (~2.7 ka). IRSL dating has a demonstrated potential to supplant 14C dating for such antarctic lacustrine deposits.  相似文献   
77.
Fluctuations in US Freezing Rain Days   总被引:1,自引:0,他引:1  
Freezing rain occurrences during a 50-year period, 1949/1950–1998/1999, derived from carefully examined records of 161 first-order stations distributed across the United States, were assessed for temporal fluctuations and trends. Classification of station fluctuations based on five 10-year periods revealed five unique distribution types in areas east of the Rockies. One of these five distributions, for stations located in the western Great Plains, experienced its greatest 10-year value at the end of the 50-year period. The other four regional distributions experienced their highest 10-year value in either of the first two 10-year periods. Nationally, the 10-year period when the greatest number of stations experienced their maximum value was 1949/1950–1958/1959, while the period when the greatest number of stations experienced their minimum value fell near the end of the 50-year record (1979/1980–1988/1989). The 50-year linear trends defined one region, the western Great Plains, with increasing values, while three areas of decreasing trend were identified; the Great Lakes, the eastern Ohio River valley, and southern New England. These analyses also indicate the need to examine and consider such time–space changes in the frequency of climate variables at various spatial scales when assessing weather risks and developing climate change scenarios.  相似文献   
78.
Stratospheric warming effects on the tropical mesospheric temperature field   总被引:1,自引:0,他引:1  
Temperature observations at 20–90 km height and 5–15°N during the winter of 1992–1993, 1993–1994 and 2003–2004, from the Wind Imaging Interferometer (WINDII) and Microwave Limb Sounder (MLS) experiments on the Upper Atmosphere Research Satellite (UARS) satellite and the Sounding the Atmosphere using Broadband Emission Radiometry (SABER) experiment on the Thermosphere, Ionosphere, Mesosphere Energetics and Dynamics (TIMED) satellite are analyzed together with MF radar winds and UK Meteorological Office (UKMO) assimilated fields. Mesospheric cooling is observed at the time of stratospheric warming at the tropics correlative with stratospheric warming events at middle and high latitudes. Planetary waves m=1 with periods of 4–5, 6–8, 10 and 12–18 days are found to dominate the period. Westward 7- and 16-day waves at the tropics appear enhanced by stationary planetary waves during sudden stratospheric warming events.  相似文献   
79.
80.
During the initial stages of the November 1996 jökulhlaup at Skeiðarárjökull, Iceland, floodwaters burst onto the glacier surface via a series of fractures. This supraglacial drainage led to the formation of a number of distinct ice surface depressions, one of which is investigated in detail. The morphology and structural characteristics of this feature are described, as well as the sedimentology of an associated assemblage of debris-filled fractures. This work suggests that debris-charged subglacial floodwaters travelled up to the glacier surface, where supraglacial flow occurred initially via an extensive network of fractures, orientated parallel to the glacier margin. Supraglacial discharge became progressively more focused into a series of discrete outlets, leading to the mechanical erosion of a number of depressions on the glacier surface. The associated transfer of subglacially derived floodwaters to high levels within the glacier resulted in the rapid entrainment of large volumes of sediment which may influence the patterns, processes and products of ice-marginal sedimentation in the future.  相似文献   
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