A MEG study of the olivine and spinel forms of Mg2SiO4     

Mark D. Jackson  Roy G. Gordon 《Physics and Chemistry of Minerals》1988,15(6):514-520

In this paper we present a theoretical investigation of the structures and relative stability of the olivine and spinel phases of Mg₂SiO₄. We use both a purely ionic model, based on the Modified Electron Gas (MEG) model of intermolecular forces, and a bond polarization model, developed for low pressure silica phases, to investigate the role of covalency in these compounds. The standard MEG ionic model gives adequate structural results for the two phases but incorrectly predicts the spinel phase to be more stable at zero pressure. This is mainly because the ionic modeling of Mg₂SiO₄ only accounts for 95 percent of the lattice energy. The remainder can be attributed to covalency and many-body effects. An extension of the MEG ionic model using “many-body” pair potentials corrects the phase stability error, but predicts structures which are in poorer agreement with experiment than the standard ionic approach. In addition, calculations using these many-body pair potentials can only account for 10 percent of the missing lattice energy. This model predicts an olivine-spinel phase transition of 8 GPa, below the experimental value of 20 GPa. Therefore, in order to understand more fully the stability of these structures we must consider polarization. A two-shell bond polarization model enhances the stability of both structures, with the olivine structure being stabilized more. This model predicts a phase transition at about 80 GPa, well above the observed value. Also, the olivine and spinel structures calculated with this approach are in poorer agreement with experiment than the ionic model. Therefore, based on our investigations, to properly model covalency in Mg₂SiO₄, a treatment more sophisticated than the two-shell model is needed.  相似文献   

Detergent Formula Effect on Transport of Nutrients to Ground Water from Septic Systems     

Bashar J. Alhajjar  John M. Harkin  Gordon Chesters 《Ground water》1989,27(2):209-219

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The problem of “naturally”-occurring drought     

B G Hunt  H B Gordon 《Climate Dynamics》1988,3(1):19-33

Naturally-occurring drought is defined here to be drought arising from the nonlinear interactions which are an inherent part of the dynamics of the climatic system. As such it has no specific excitation mechanism, in contrast to forced drought where sea surface temperature anomalies are frequently cited as an important precursor. The essential difference between these two types of drought is that the former is very local and isolated spatially, whereas the latter is widespread and coherent. Observations for Australia are used to illustrate these points. Results are given for a 10-year general circulation model integration which clearly simulated naturally occurring drought and highlighted its unique characteristics. Multi-annual time series for specific geographical regions in the model show that no differences in monthly mean values of relative humidity or zonal and meridional fluxes of moisture were apparent for years with or without drought. More detailed analysis indicated that rather small differences exist in atmospheric temperatures and absolute humidities between drought and nondrought years which are important factors in determining the onset of precipitation in the model.Overall the analysis emphasises the subtlety of the processes involved. These processes, however, were able to produce completely different precipitation histories from one year to the next at a given point. The smallness of the changes involved in the atmospheric processes indicates that the nonlinearities were able to modulate conditions at a given point within an existing synoptic system only slightly, rather than initiate a new climatic regime in drought years. The problem of naturally-occurring drought, of course, is that it is intrinsically unpredictable.  相似文献   

What has seismic missed?     

Gordon Kaufman 《Natural Resources Research》1994,3(4):304-314

The relative efficiencies of alternative geometric patterns of both discrete borehole and continuous grid line search have been extensively discussed in the mathematical geology literature. However, an equally important problem has received virtually no attention: How to use a sample of properties of geologic anomalies detected by grid line search of a region to estimate systematically both the number and size distribution of geologic anomalies missed by the search. We show how estimation methods developed in the sample survey design literature can be adapted to this problem, and we apply these methods to data describing 94 anomalies identified by a seismic reconnaissance survey.  相似文献   

Simulation of pebble abrasion on coastal benches by transgressive waves     

Gordon E. Bigelow 《地球表面变化过程与地形》1984,9(4):383-390

Tumbler simulations of abrasion processes affecting rocks on basaltic marine benches have clarified the effects of mass and volume of rock fragments on their rate of wear. Several experiments indicate that rate of basalt wear increases with mass in the interval 1 g to 8 g, but is not related to volume of fragments abraded in seawater. Relatively small quantities of rock flour suspended in the immersant seawater substantially reduced the rate of basalt wear. Basalt and calcareous beachrock responded differently in systems with both rock types tumbling together. Examination of the cuttings from these low-energy encounters suggests that abrasion on elevated benches along exposed seacoasts reduces virtually all clastic material to particles of silt size or smaller, producing essentially no sand.  相似文献   

Structure and viscosity of rhyolitic composition melts     

Michael F. Hochella  Gordon E. Brown 《Geochimica et cosmochimica acta》1984,48(12):2631-2640

The average local structure of a rhyolitic composition glass has been determined at 25°C using X-ray radial distribution analysis (RDA) and quasi-crystalline modelling and is best described as similar to that in a stuffed framework composed principally of six-membered rings of Si and Al tetrahedra (basically a stuffed tridymite-like model). Using this model it is possible to calculate a density (2.41 g/cm³) which compares well with the measured density (2.40 g/cm³); a structural model based on four-membered rings (an albite-like model) results in a substantially higher calculated density (2.60 g/cm³). We suggest that the rhyolite glass structural model is appropriate for rhyolitic melts, based on evidence from the recent literature. New viscosity data for an anhydrous rhyolite composition measured between 1200°C and 1500°C are presented and interpreted in terms of our proposed structural model and previous melt structure models for the major normative components of rhyolite. A mechanism for diffusion and viscous flow in framework silicate melts (including rhyolite composition) is proposed on the basis of recent molecular orbital calculations and molecular dynamics simulations of silicate and fluoride melts.  相似文献   

Preface     

Gordon McBean  Erik Rasmussen 《Dynamics of Atmospheres and Oceans》1987,10(4)

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Dependence of Effective Porosity on Fracture Continuity in Fractured Media     

Matthew J. Gordon 《Ground water》1986,24(4):446-452

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Production and pelagic dissolution of biogenic silica in the Southern Ocean     

David M. Nelson  Louis I. Gordon 《Geochimica et cosmochimica acta》1982,46(4):491-501

Vertical distributions of particulate silica, and of production and dissolution rates of biogenic silica, were determined on two N-S transects across the Pacific sector of the Antarctic Circumpolar Current during the austral spring of 1978. Particulate silica profiles showed elevated levels in surface water and near the bottom, with low (35–110 nmol Si · 1^?1) and vertically uniform values through the intervening water column. Both the particulate silica content of the upper 200 m and the production rate of biogenic silica in the photic zone increased from north to south, reaching their highest values near the edge of the receding pack ice. A significant, but variable, fraction (18–58%) of the biogenic silica produced in the surface layer was redissolving in the upper 90–98 m. Net production of biogenic silica in the surface layer (production minus dissolution) was proceeding at a mean rate of ca. 2 mmol Si · m^?2 · day^?1. This is ca. 4 times greater than the most recent estimate of the mean accumulation rate of siliceous sediments beneath the ACC. We estimate, based on mass balance, that the mean dissolution rate of biogenic silica in subsurface water column in the Southern Ocean is 1.2–2.9 mmol Si · m^?2 · day^?1.  相似文献   

Tectonic systems and the deposition of iron-formation   总被引：8，自引：0，他引：8  

Gordon A. Gross 《Precambrian Research》1983,20(2-4)

The iron-formation group of chemically precipitated cherty iron-rich sediments ranges in age from Early Precambrian to Recent and is composed of a variety of lithological facies. Iron-formations are classified as Lake Superior and Algoma types to emphasize the contrasting conditions in the spectrum of sedimentary-tectonic environments in which they formed. Thick stratigraphic units of Lake Superior type iron-formation, which form the most extensive iron ranges of the world, are part of sedimentary-tectonic systems that developed along the margins of cratons or continental platforms and were deposited over extended periods of time under relatively stable tectonic conditions. The Algoma type iron-formations were deposited with volcanic rocks and greywacke in various tectonic-volcanic systems, formed under more dynamic tectonic conditions, but are otherwise comparable to present day spreading ridges on the ocean floor. The thick sequences of Lake Superior type iron-formation deposited between 2.7 and 2.0 Ga form part of major sedimentary-tectonic systems that extended along the margins of continents. Direct biogenic factors and the composition of the atmosphere probably had only limited influence on the precipitation of these chemical sediments.  相似文献