Platelet development in cuboid diamonds: insights from micro-FTIR mapping   总被引：1，自引：1，他引：0  

D. Howell  C. J. O’Neill  K. J. Grant  W. L. Griffin  S. Y. O’Reilly  N. J. Pearson  R. A. Stern  T. Stachel 《Contributions to Mineralogy and Petrology》2012,164(6):1011-1025

Fourier transform infrared mapping of diamonds can reveal detailed information on impurities, with a spatial context. We apply this technique, combined with in situ isotopic analysis of carbon, to the study of cuboid diamond growth in a sample that exhibits some mixed-habit growth. While there has been some uncertainty in the literature regarding sectoral differences in nitrogen aggregation and subsequent platelet development, the data from this study appear far more conclusive. We show that despite nitrogen being concentrated in octahedral sectors, there is no detectable difference in the concentration-adjusted rate of nitrogen aggregation within octahedral and cuboid sectors. However, the resultant platelet development is significantly reduced in cuboid sectors compared to contemporaneously formed octahedral sectors. This finding has significant implications for the classification of diamonds using the relationship between their platelet intensity and the absorption caused by B centres. It means that cuboid diamonds naturally fall below the linear relationship that has been termed regular, which would lead to them being incorrectly interpreted as having experienced heating or deformation. The data also support earlier suggestions that large hydrogen concentrations in the diamond-forming fluid may be required for cuboid growth. We further suggest that high nitrogen and hydrogen concentrations are required for mixed-habit diamond growth, which might be the product of specific fluid chemistries that occur in reducing mantle environments.  相似文献   

Thermal treatment as a method to control transfers of invasive biofouling species via vessel sea chests     

Piola RF  Hopkins GA 《Marine pollution bulletin》2012,64(8):1620-1630

This study examined the efficacy of heated seawater for the treatment and remediation of fouled vessel sea chest habitats. In laboratory trials, three temperature regimes (37.5°C for 60 min, 40°C for 30min and 42.5°C for 20 min) were tested on a range of temperate taxa commonly found in sea chests. Field validation trials further assessed the efficacy of heat treatment within a replica sea chest environment. During laboratory trials, 100% mortality was achieved across all three treatments for the majority of taxa; the exceptions being the barnacle Elminius modestus and the oyster Crassostrea gigas. Temperature tolerance limits observed in the laboratory were successfully replicated under simulated sea chest conditions; however, a failure to achieve even heat distribution was an obstacle to achieving uniform mortality. This study provides guidance on the temperature/exposure parameters required for vessels plying temperate latitudes, and demonstrates that heated seawater has potential for controlling biofouling in vessel sea chests.  相似文献   

Spitzer IRAC infrared colours of submillimetre-bright galaxies     

Min S. Yun  Itziar Aretxaga  Matthew L. N. Ashby  Jason Austermann  Giovanni G. Fazio  Mauro Giavalisco  Jia–Sheng Huang  David H. Hughes  Sungeun Kim  James D. Lowenthal  Thushara Perera  Kim Scott  Grant Wilson  Joshua D. Younger 《Monthly notices of the Royal Astronomical Society》2008,389(1):333-340

High-redshift submillimetre-bright galaxies identified by blank field surveys at millimetre and submillimetre wavelengths appear in the region of the Infra Red Array Camera (IRAC) colour–colour diagrams previously identified as the domain of luminous active galactic nuclei (AGNs). Our analysis using a set of empirical and theoretical dusty starburst spectral energy distribution (SED) models shows that power-law continuum sources associated with hot dust heated by young (≲100 Myr old), extreme starbursts at z > 2 also occupy the same general area as AGNs in the IRAC colour–colour plots. A detailed comparison of the IRAC colours and SEDs demonstrates that the two populations are distinct from each other, with submillimetre-bright galaxies having a systematically flatter IRAC spectrum (≳1 mag bluer in the observed [4.5]–[8.0] colour). Only about 20 per cent of the objects overlap in the colour–colour plots, and this low fraction suggests that submillimetre galaxies powered by a dust-obscured AGN are not common. The red infrared colours of the submillimetre galaxies are distinct from those of the ubiquitous foreground IRAC sources, and we propose a set of infrared colour selection criteria for identifying SMG counterparts that can be used even in the absence of radio or Multiband Imaging Photometer for Spitzer (MIPS) 24 μm data.  相似文献   

Stable isotope evidence for nutritional stress,competition, and loss of functional habitat as factors limiting recovery of rare antelope in southern Africa     

D. Codron  J. Codron  J.A. Lee-Thorp  M. Sponheimer  C.C. Grant  J.S. Brink 《Journal of Arid Environments》2009,73(4-5):449-457

A major focus in population ecology is understanding factors that limit rare species. We used stable isotope approaches to diet to determine whether remaining rare antelope populations in Kruger National Park (KNP), South Africa experience i) nutritional stress; ii) competition with sympatric bulk grazers; iii) reduced habitat heterogeneity. Rare species consumed near-pure C₄ grass-based diets throughout the seasonal cycle, in contrast to field observations that reported significant levels of C₃ consumption (browse) by these taxa. This finding, coupled with low faecal %N at the height of the dry season, may indicate nutritional stress, but recent isotopic studies of the same species elsewhere in Africa suggest that field observations overestimated levels of browse consumption. We find little evidence for diet niche overlap between rare antelope with bulk grazing species. This partitioning of resources (interpreted mainly as tall- versus short-grass grazing, respectively), is consistent with reported differences in observed diet, and comparative oral morphology. Last, we find less seasonal diet variations amongst bulk grazers feeding in rare antelope habitats compared with other landscapes. We propose that loss of functional heterogeneity, apparently brought about by high densities of artificial waterholes, limits recovery of diet- and habitat-selective rare antelope populations in KNP.  相似文献   

A New Integrated Weighted Model in SNOW-V10: Verification of Continuous Variables     

Laura X. Huang  George A. Isaac  Grant Sheng 《Pure and Applied Geophysics》2014,171(1-2):277-287

This paper presents the verification results of nowcasts of four continuous variables generated from an integrated weighted model and underlying Numerical Weather Prediction (NWP) models. Real-time monitoring of fast changing weather conditions and the provision of short term forecasts, or nowcasts, in complex terrain within coastal regions is challenging to do with sufficient accuracy. A recently developed weighting, evaluation, bias correction and integration system was used in the Science of Nowcasting Olympic Weather for Vancouver 2010 project to generate integrated weighted forecasts (INTW) out to 6 h. INTW forecasts were generated with in situ observation data and background gridded forecasting data from Canadian high-resolution deterministic NWP system with three nested grids at 15-, 2.5- and 1-km horizontal grid-spacing configurations. In this paper, the four variables of temperature, relative humidity, wind speed and wind gust are treated as continuous variables for verifying the INTW forecasts. Fifteen sites were selected for the comparison of the model performances. The results of the study show that integrating surface observation data with the NWP forecasts produce better statistical scores than using either the NWP forecasts or an objective analysis of observed data alone. Overall, integrated observation and NWP forecasts improved forecast accuracy for the four continuous variables. The mean absolute errors from the INTW forecasts for the entire test period (12 February to 21 March 2010) are smaller than those from NWP forecasts with three configurations. The INTW is the best and most consistent performer among all models regardless of location and variable analyzed.  相似文献   

Evapotranspiration and canopy characteristics of two lodgepole pine stands following mountain pine beetle attack   总被引：1，自引：0，他引：1       下载免费PDF全文

Mathew G. Brown  T. Andrew Black  Zoran Nesic  Vanessa N. Foord  David L. Spittlehouse  Arthur L. Fredeen  Rebecca Bowler  Nicholas J. Grant  Philip J. Burton  J. A. Trofymow  Dominic Lessard  Gesa Meyer 《水文研究》2014,28(8):3326-3340

Over the past decade, British Columbia (BC), has experienced the largest mountain pine beetle (MPB) outbreak on record. This study used the eddy‐covariance (EC) technique to examine the impact of the MPB attack on evapotranspiration (E) and associated canopy characteristics of two lodgepole pine stands with secondary structure (trees, saplings and seedlings surviving the attack) located in central BC. MPB‐06, an 85‐year‐old almost pure stand of pine trees, was first attacked in 2006, and by 2010, ~80% of the trees had been killed. MPB‐03, a 110‐year‐old stand with an overstory consisting of over 90% pine and a developed sub‐canopy, was first attacked in 2003 and by 2007 had > 95% pine canopy mortality. EC measurements began in August 2006 at MPB‐06 and in March 2007 at MPB‐03, and continued for four years. Annual total E ranged from 226 mm to 237 mm at MPB‐06, and from 280 to 297 mm at MPB‐03, showing relatively little year‐to‐year change at both sites over the four years. Increased E from the accelerated growth of the surviving vegetation (secondary structure, shrubs and herbs) compensated for reduction in E due to the death of the overstory. Monthly average daytime canopy conductance, the Priestley–Taylor (α), and the canopy–atmosphere decoupling coefficient (Ω) steadily increased during the growing season reaching approximate maximum values of 5 mm s^?1, 0.75 and 0.12, respectively. Potential evapotranspiration was approximated using a vapour pressure deficit‐dependent α obtained at high soil water content. Calculated water deficits indicated some water‐supply limitation to the surviving trees and understory at both sites. Rates of root zone drainage during the growing season were low relative to precipitation. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Effectiveness of subsurface pressure monitoring for brine leakage detection in an uncertain CO2 sequestration system     

Nicholas A. Azzolina  Mitchell J. Small  David V. Nakles  Grant S. Bromhal 《Stochastic Environmental Research and Risk Assessment (SERRA)》2014,28(4):895-909

This work evaluates the detection sensitivity of deep subsurface pressure monitoring within an uncertain carbon dioxide sequestration system by linking the output of an analytical reduced-order model and first-order uncertainty analysis. A baseline (non-leaky) modeling run was compared against 10 different leakage scenarios, where the cap rock permeability was increased by factors of 2–100 (cap rock permeability from 10^?3 to 10^?1 millidarcy). The uncertainty variance outputs were used to develop percentile estimates and detection sensitivity for pressure throughout the deep subsurface as a function of space (lateral distance from the injection wells and vertical orientation within the reservoir) and time (years since injection), or P(x, z, t). Conditional probabilities were computed for combinations of x, z, and t, which were then used to generate power curves for detecting leakage scenarios. The results suggest that measurements of the absolute change in pressure within the target injection aquifer would not be able to distinguish small leakage rates (i.e., less than 50 × baseline) from baseline conditions, and that only large leakage rates (i.e., >100 × baseline) would be discriminated with sufficient statistical power (>99 %). Combining measurements, for example by taking the ratio of formation pressure in Aquifer 2/Aquifer 1, provides better statistical power for distinguishing smaller leakage rates at earlier times in the injection program. Detection sensitivity for pressure is a function of space and time. Therefore, design of an adequate monitoring network for subsurface pressure should account for this space–time variability to ensure that the monitoring system performs to the necessary design criteria, e.g., specific false-negative and false-positive rates.  相似文献   

Facilitating adaptation of biodiversity to climate change: a conceptual framework applied to the world’s largest Mediterranean-climate woodland     

Suzanne M. Prober  Kevin R. Thiele  Philip W. Rundel  Colin J. Yates  Sandra L. Berry  Margaret Byrne  Les Christidis  Carl R. Gosper  Pauline F. Grierson  Kristina Lemson  Tom Lyons  Craig Macfarlane  Michael H. O’Connor  John K. Scott  Rachel J. Standish  William D. Stock  Eddie J. B. van Etten  Grant W. Wardell-Johnson  Alexander Watson 《Climatic change》2012,110(1-2):227-248

The importance of ecological management for reducing the vulnerability of biodiversity to climate change is increasingly recognized, yet frameworks to facilitate a structured approach to climate adaptation management are lacking. We developed a conceptual framework that can guide identification of climate change impacts and adaptive management options in a given region or biome. The framework focuses on potential points of early climate change impact, and organizes these along two main axes. First, it recognizes that climate change can act at a range of ecological scales. Secondly, it emphasizes that outcomes are dependent on two potentially interacting and countervailing forces: (1) changes to environmental parameters and ecological processes brought about by climate change, and (2) responses of component systems as determined by attributes of resistance and resilience. Through this structure, the framework draws together a broad range of ecological concepts, with a novel emphasis on attributes of resistance and resilience that can temper the response of species, ecosystems and landscapes to climate change. We applied the framework to the world’s largest remaining Mediterranean-climate woodland, the ‘Great Western Woodlands’ of south-western Australia. In this relatively intact region, maintaining inherent resistance and resilience by preventing anthropogenic degradation is of highest priority and lowest risk. Limited, higher risk options such as fire management, protection of refugia and translocation of adaptive genes may be justifiable under more extreme change, hence our capacity to predict the extent of change strongly impinges on such management decisions. These conclusions may contrast with similar analyses in degraded landscapes, where natural integrity is already compromised, and existing investment in restoration may facilitate experimentation with higher risk?options.  相似文献   

Modeling incompatible trace-element abundances in plagioclase in the Skaergaard intrusion using the trapped liquid shift effect     

R.?Grant?CawthornEmail authorView author&#;s OrcID profile  Christian?Tegner 《Contributions to Mineralogy and Petrology》2017,172(11-12):93

Incompatible trace-element abundances in minerals and whole rocks from layered intrusions have been used to model the fractionation processes and evolving liquid compositions. Many such models assume that the analyzed concentration in a mineral represents that of the mineral when it first crystallized. However, overgrowth from residual liquid and subsequent diffusive equilibration can result in significant changes to the bulk mineral compositions (the more incompatible the element the more dramatic the subsequent changes). The proportion of that residual liquid relative to the cumulus minerals is the most important parameter in determining the magnitude of this effect (trapped liquid shift effect). Calculations involving Ba and La contents in plagioclase quantitatively demonstrate this effect. For Ba and La (partition coefficients of 0.4 and 0.04), 50% trapped liquid in a sample can result in two and sevenfold increases, respectively, in concentration between original and final bulk mineral compositions. Different cumulus assemblages also have a major effect on final compositions. We use examples of the concentrations of Ba and La in plagioclase from the Skaergaard intrusion from previous publications to illustrate the importance of this effect. Specifically, the La content of bulk plagioclase steadily decreases upward from the Lower Zone to Upper Zone c, and Ba in plagioclase shows no increase from the Lower Zone to the top of the Middle Zone. Such results are not explicable by fractionation processes, but can be modeled by the trapped liquid shift effect, assuming the well-established evidence for upward decrease in trapped liquid proportion through these zones.  相似文献   

Space- and Time-Dependent Probabilities for Earthquake Fault Systems from Numerical Simulations: Feasibility Study and First Results     

Jordan Van Aalsburg  John B. Rundle  Lisa B. Grant  Paul B. Rundle  Gleb Yakovlev  Donald L. Turcotte  Andrea Donnellan  Kristy F. Tiampo  Jose Fernandez 《Pure and Applied Geophysics》2010,167(8-9):967-977

In weather forecasting, current and past observational data are routinely assimilated into numerical simulations to produce ensemble forecasts of future events in a process termed “model steering”. Here we describe a similar approach that is motivated by analyses of previous forecasts of the Working Group on California Earthquake Probabilities (WGCEP). Our approach is adapted to the problem of earthquake forecasting using topologically realistic numerical simulations for the strike-slip fault system in California. By systematically comparing simulation data to observed paleoseismic data, a series of spatial probability density functions (PDFs) can be computed that describe the probable locations of future large earthquakes. We develop this approach and show examples of PDFs associated with magnitude M > 6.5 and M > 7.0 earthquakes in California.  相似文献