Characterisation of Soot Emitted by Domestic Heating,Aircraft and Cars Using Diesel or Biodiesel   总被引：1，自引：0，他引：1  

Anne?Smekens  Ricardo?Henrique?Moreton?Godoi  Patrick?Berghmans  René?Van?GriekenEmail author 《Journal of Atmospheric Chemistry》2005,52(1):45-62

The characterisation of aggregates, like soot, firstly requires the determination of the size distribution of the primary particles. The primary particle size of combustion generated aggregates depends upon the combustion environment and the formation conditions, such as temperature, pressure and fuel-to-air ratio, among others. Since the combustion characteristics are different in the different types of burners, the characterisation of primary particles may offer the possibility to distinguish soot from different sources. In this paper, we present the signature of the primary particles and the aggregates of soot emitted by cars using diesel or biodiesel, by domestic heating, and by aircraft exhausts, which can be considered as the major sources as derived from measurements on transmission electron micrographs. The size distributions of all aggregates types with different aerodynamic diameter were log-normal and quasi-monodisperse. The size distribution of the primary particles for soot emitted by different sources showed minor differences. However, a comparison between the diameter of the primary particles and those obtained using a standard method for carbon black revealed discrepancies. The median diameter of the primary particles was combined with the median number of primary particles in an aggregate to calculate the relative particle surface area available for adsorption. In a similar way, the relative specific surface area was determined. The surface area was measured using the Brunauer-Emmett-Teller (B.E.T.) nitrogen adsorption method and the relative surface area available for adsorption was calculated.  相似文献   

Cataclastic rheology of carbonate rocks     

LU Xiancai  SUN Yan  SHU Liangshu  GU Lianxing  GUO Jichun & ZHU Wenbin State Key Laboratory of Mineral Deposits Research  Department of Earth Sciences  Nanjing University  Nanjing  China 《中国科学D辑(英文版)》2005,48(8):1227-1233

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The macroinfauna of the Galician sandy beaches (NW Spain) affected by the Prestige oil-spill     

Junoy J  Castellanos C  Viéitez JM  de la Huz MR  Lastra M 《Marine pollution bulletin》2005,50(5):526-536

Eighteen sandy beaches were sampled along the 1659 km of the Galician coast (NW Spain) six months after the Prestige oil-spill to study the impact of the fuel and the clean-up activities on the macroinfauna community. A transect was extended at each beach, from above the drift line to below the swash line at five sampled levels; at each level six 0.05 m2 replicates were taken to a depth of 30 cm and sieved through a 1mm mesh, and the organisms collected and preserved. Results were compared with previous data obtained using the same procedures. The macroinfauna was numerically dominated by the amphipod Pontocrates arenarius, the isopod genus Eurydice, the polychaete Scolelepis squamata, and the amphipod Talitrus saltator. As a result of the Prestige oil-spill and the clean-up activities, beach populations were reduced, with Eurydice and S. squamata as the most affected taxa.  相似文献   

Surface area, porosity and water adsorption properties of fine volcanic ash particles   总被引：1，自引：1，他引：0  

Pierre Delmelle  Frédéric Villiéras  Manuel Pelletier 《Bulletin of Volcanology》2005,67(2):160-169

Our understanding on how ash particles in volcanic plumes react with coexisting gases and aerosols is still rudimentary, despite the importance of these reactions in influencing the chemistry and dynamics of a plume. In this study, six samples of fine ash (<100 m) from different volcanoes were measured for their specific surface area, a_s, porosity and water adsorption properties with the aim to provide insights into the capacity of silicate ash particles to react with gases, including water vapour. To do so, we performed high-resolution nitrogen and water vapour adsorption/desorption experiments at 77 K and 303 K, respectively. The nitrogen data indicated a_s values in the range 1.1–2.1 m²/g, except in one case where a a_s of 10 m²/g was measured. This high value is attributed to incorporation of hydrothermal phases, such as clay minerals, in the ash surface composition. The data also revealed that the ash samples are essentially non-porous, or have a porosity dominated by macropores with widths >500 Å. All the specimens had similar pore size distributions, with a small peak centered around 50 Å. These findings suggest that fine ash particles have relatively undifferentiated surface textures, irrespective of the chemical composition and eruption type. Adsorption isotherms for water vapour revealed that the capacity of the ash samples for water adsorption is systematically larger than predicted from the nitrogen adsorption a_s values. Enhanced reactivity of the ash surface towards water may result from (i) hydration of bulk ash constituents; (ii) hydration of surface compounds; and/or (iii) hydroxylation of the surface of the ash. The later mechanism may lead to irreversible retention of water. Based on these experiments, we predict that volcanic ash is covered by a complete monolayer of water under ambient atmospheric conditions. In addition, capillary condensation within ash pores should allow for deposition of condensed water on to ash particles before water reaches saturation in the plume. The total mass of water vapour retained by 1 g of fine ash at 0.95 relative water vapour pressure is calculated to be ~10^–2 g. Some volcanic implications of this study are discussed.Editorial responsibility: J. Gilbert  相似文献   

Field assessment of innovative sensor for monitoring of sediment accumulation at inshore coral reefs     

Thomas S  Ridd P 《Marine pollution bulletin》2005,51(1-4):470-480

Sediment accumulation rate is a frequently required parameter in environmental and management studies, in particular near coral reefs where sediment accumulation can potentially cause severe impact. However, opportunities to obtain accurate sediment accumulation measurements are often limited by a lack of adequate instrumentation, in particular for high temporal resolution monitoring. For instance the traditional use of sediment traps, as the most widespread technique, offers poor temporal resolution (commonly of weeks) besides having significant hydrodynamic shortcomings. Therefore, a new optical backscatter sediment accumulation sensor (SAS) was developed to continuously measure in situ short-term sediment accumulation in sensitive riverine and coastal environments, enabling high temporal and vertical resolution (order of 1 h and with a deposited thickness resolution in the order of 20 microm respectively). This allows investigations of various parameters that influence accumulation: tides, current, waves, rain, or anthropogenic activity such as sediment dumping. This paper briefly describes the SAS and presents three field applications on nearshore coral reefs at Ishigaki Island (Japan), Lihir Island (Papua New Guinea), and Magnetic Island (Australia).  相似文献   

Effects of 12 years' operation of a sewage treatment plant on trace metal occurrence within a Mediterranean commercial sponge (Spongia officinalis, Demospongiae)     

Perez T  Longet D  Schembri T  Rebouillon P  Vacelet J 《Marine pollution bulletin》2005,50(3):301-309

The present field study uses Spongia officinalis for assessing trace metals occurrence in time and space within Mediterranean rocky communities. Nine sites were selected in the Marseille area for studying spatial trends in 12 metal concentrations. Long term changes in 8 metal concentrations were assessed at sites that had been sampled before and 12 years after the opening of a treatment plant. Spongia officinalis highly concentrated all the trace metal surveyed excepted Hg and Cd. The overall contamination level registered provided a classification of the study sites which is congruent with that given by other studies on pollutant accumulation in neighbouring sandy-bottoms or benthic assemblages. Among the metals studied, Fe, Pb, Cr are those that best highlighted a pollution gradient. In the present study, only Cd concentration did not vary in space. Except for Ni, all pollutant concentrations clearly decreased between 1984 and 1999. This very impressive decrease in heavy metal concentrations within the Marseille area represents an indisputable evidence of the improvement of the seawater quality resulting from 12 years' operation of the Marseille sewage plant. Moreover, the significant decrease also recorded in the reference population at Port-Cros might reflect an overall improvement in the seawater quality of the NW Mediterranean.  相似文献   

Compression of ephemerides     

Deprit  André  Poplarchek  Walter  Deprit-Bartholomé  Andrée 《Celestial Mechanics and Dynamical Astronomy》1975,11(1):53-58

Approximations in the normL ₁ by Chebyshev polynomials are generated to represent astronomical ephemerides over large intervals of time.  相似文献   

Spin-forbidden resonance multiplets in light elements     

B. Edlén  H. P. Palenius  K. Bockasten  R. Hallin  J. Bromander 《Solar physics》1969,9(2):432-438

We present new laboratory data on the multiplets 2s ^{2 1} S -2s2p ³ P, 2s ²2p ² P - 2s2p ^{2 4} P, and 2s ²2p ^{2 3} P - 2s2p ^{3 5} S in nitrogen, oxygen and fluorine, and discuss theZ-dependence of their wave-numbers. These multiplets are very faint in laboratory light sources, but can become prominent in astrophysical sources of low density. Our results confirm the solar identifications of the nitrogen and oxygen multiplets made by Burtonet al. Predicted positions of the corresponding multiplets in neon are given.  相似文献   

Origin and evolution of the earth-moon system     

Hannes Alfvén  Gustaf Arrhenius 《Earth, Moon, and Planets》1972,5(1-2):210-230

The origin and evolution of the Earth-Moon system is studied by comparing it to the satellite systems of other planets. The normal structure of a system of secondary bodies orbiting around a central body depends essentially on the mass of the central body. The Earth with a mass intermediate between Uranus and Mars should have a normal satellite system that consists of about half a dozen satellites each with a mass of a fraction of a percent of the lunar mass. Hence, the Moon is not likely to have been generated in the environment of the Earth by a normal accretion process as is claimed by some authors.Capture of satellites is quite a common process as shown by the fact that there are six satellites in the solar system which, because they are retrograde, must have been captured. There is little doubt that the Moon is also a captured satellite, but its capture orbit and tidal evolution are still incompletely understood.The Earth and the Moon are likely to have been formed from planetesimals accreting in particle swarms in Kepler orbits (jet streams). This process leads to the formation of a cool lunar interior with an outer layer accreted at increasingly higher temperatures. The primeval Earth should similarly have formed with a cool inner core surrounded in this case by a very strongly heated outer core and with a mantle accreted slowly and with a low average temperature but with intense transient heating at each individual impact site.  相似文献   

Collective resonant phenomena on small bodies in the solar system     

Ch. Froeschlé  C. Froeschlé 《Celestial Mechanics and Dynamical Astronomy》1992,54(1-3):71-89

For both asteroids and meteor streams, and also for comets, resonances play a major role for their orbital evolutions but on different time scales. For asteroids both mean motion resonances and secular resonances not only structure the phase space of regular orbits but are mainly at the origin for the inherent chaos of planet crosser objects.For comets and their chaotic routes temporary trapping into orbital resonances is a well known phenomenon. In addition for slow diffusion through the Kuiper belt resonances are the only candidates for originating a slow chaos.Like for asteroids, resonances with Jupiter play a major role for the orbital evolution of meteor streams. Crossing of separatrix like zones appears to be crucial for the formation of arcs and for the dissolution of streams. In particular the orbital inclination of a meteor stream appears to be a critical parameter for arc formation. Numerical results obtained in an other context show that the competition between the Poynting-Robertson drag and the gravitational interaction of grains near the 2/1 resonance might be very important in the long run for the structure of meteor streams.  相似文献